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Enantioselective synthesis of cyclopropylcarboxamides using s-BuLi-sparteine-mediated metallation.
Lauru, Stephanie; Simpkins, Nigel S; Gethin, David; Wilson, Claire.
Chem Commun (Camb) ; (42): 5390-2, 2008 Nov 14.
Article in English | MEDLINE | ID: mdl-18985220

ABSTRACT

Enantioselective synthesis of cyclopropylcarboxamides is possible by asymmetric metallation of prochiral starting cyclopropanes using s-BuLi-sparteine.


Subject(s)
Amides/chemistry , Cyclopropanes/chemistry , Lithium/chemistry , Sparteine/chemistry , Catalysis , Crystallography, X-Ray , Models, Molecular , Molecular Structure , Stereoisomerism
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