1.
Chem Commun (Camb)
; (6): 696-7, 2003 Mar 21.
Article
in English
| MEDLINE
| ID: mdl-12703778
ABSTRACT
Catalytic hydrophosphination of propargyl alcohols by ruthenium complexes RuCl(cod)(C5Me5) and RuCl(PPh3)2(C5Me5) leads to the formation of functionalized vinylphosphines, with linkage of the phosphorus atom to the terminal alkyne carbon, via a ruthenium vinylidene intermediate.