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Chem Commun (Camb) ; (6): 696-7, 2003 Mar 21.
Article in English | MEDLINE | ID: mdl-12703778

ABSTRACT

Catalytic hydrophosphination of propargyl alcohols by ruthenium complexes RuCl(cod)(C5Me5) and RuCl(PPh3)2(C5Me5) leads to the formation of functionalized vinylphosphines, with linkage of the phosphorus atom to the terminal alkyne carbon, via a ruthenium vinylidene intermediate.

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