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1.
Angew Chem Int Ed Engl ; 39(22): 4145-4148, 2000 Nov 17.
Article in English | MEDLINE | ID: mdl-11093234
2.
Acta Crystallogr C ; 56 (Pt 4): 427-9, 2000 Apr.
Article in English | MEDLINE | ID: mdl-10815196
3.
Angew Chem Int Ed Engl ; 38(20): 3053-3055, 1999 Oct 18.
Article in English | MEDLINE | ID: mdl-10540419

ABSTRACT

Thermally unstable crystals of the title compound-the first bismuth phosphide complex to be structurally characterized (see picture)-are obtained by the reaction of [Bi(NMe(2))(3)] with [tBuPHLi] (1:3) in THF/hexane. Berry pseudorotation of the pseudo-trigonal-bipyramidal [{(tBuP)(3)}(2)Bi](-) ion is prevented for steric reasons.

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