Influence of TiO2 Nanoparticles on the Physical, Mechanical, and Structural Characteristics of Cementitious Composites with Recycled Aggregates.

The aim of this study is to analyze the effect of the addition of TiO2 nanoparticles (NTs) on the physical and mechanical properties, as well as the microstructural changes, of cementitious composites containing partially substituted natural aggregates (NAs) with aggregates derived from the following four recycled materials: glass (RGA), brick (RGB), blast-furnace slag (GBA), and recycled textolite waste with WEEE (waste from electrical and electronic equipment) as the primary source (RTA), in line with sustainable construction practices. The research methodology included the following phases: selection and characterization of raw materials, formulation design, experimental preparation and testing of specimens using standardized methods specific to cementitious composite mortars (including determination of apparent density in the hardened state, mechanical strength in compression, flexure, and abrasion, and water absorption by capillarity), and structural analysis using specialized techniques (scanning electron microscopy (SEM) images and energy dispersive X-ray spectroscopy (EDS)). The analysis and interpretation of the results focused primarily on identifying the effects of NT addition on the composites. Results show a decrease in density resulting from replacing NAs with recycled aggregates, particularly in the case of RGB and RTA. Conversely, the introduction of TiO2 nanoparticles resulted in a slight increase in density, ranging from 0.2% for RTA to 7.4% for samples containing NAs. Additionally, the introduction of TiO2 contributes to improved compressive strength, especially in samples containing RTA, while flexural strength benefits from a 3-4% TiO2 addition in all composites. The compressive strength ranged from 35.19 to 70.13 N/mm2, while the flexural strength ranged from 8.4 to 10.47 N/mm2. The abrasion loss varied between 2.4% and 5.71%, and the water absorption coefficient varied between 0.03 and 0.37 kg/m2m0.5, the variations being influenced by both the nature of the aggregates and the amount of NTs added. Scanning electron microscopy (SEM) images and energy dispersive X-ray spectroscopy (EDS) analysis showed that TiO2 nanoparticles are uniformly distributed in the cementitious composites, mainly forming CSH gel. TiO2 nanoparticles act as nucleating agents during early hydration, as confirmed by EDS spectra after curing.

The Influence of Different Aggregates on the Physico-Mechanical Performance of Alkali-Activated Geopolymer Composites Produced Using Romanian Fly Ash.

In light of the urgent need to develop environmentally friendly materials that, at some point, will allow the reduction of concrete and, consequently, cement consumption-while at the same time allowing the reuse of waste and industrial by-products-alkali-activated fly ash (AAFA) geopolymer composite emerges as a material of great interest. The aim of this study was to investigate the physico-mechanical performance of composites based on AAFA binders and the effect of different types of aggregates on these properties. The experimental results indicate variations in flexural and compressive strength, which are influenced both by the nature and particle size distribution of aggregates and the binder-to-aggregate ratio. The analysis of the samples highlighted changes in porosity, both in distribution and pore size, depending on the nature of the aggregates. This supports the evolution of physico-mechanical performance indicators.

Thermophysical Characteristics of Clay for Efficient Rammed Earth Wall Construction.

This case study focuses on twelve compacted clay soil samples to understand their fundamental physical and thermal properties. For each sample, the density, thermal conductivity, thermal diffusivity, specific heat, and drying shrinkage were assessed. The identification and characterisation of the materials were also carried out by positioning them into the ternary diagram based on the percentage of sand, silt, and clay. These properties are definitive for the performance characteristics of materials used in rammed earth wall construction. The aim is to provide information for better knowledge and prediction regarding the dynamic heat flow in rammed earth walls. Experimental results show a relatively wide range of values for each property, reflecting the diverse properties of the sampled clays. The thermophysical characteristics of the 12 types of earth analysed showed correlations with reports in the literature in terms of density (1490-2150 kg/m3), porosity (23.22-39.99%), specific heat capacity (701-999 J/kgK), and thermal conductivity (0.523-1.209 W/mK), which indicates them as materials suitable for use in the construction of rammed earth walls. Using test data, a dynamic assessment of heat flow through simulated rammed earth walls was performed. For a better understanding of the results obtained, they were compared with results obtained for simulations where the building element would be made of concrete, i.e., a mineral wool core composite. Thus, heat flux at the wall surface and mass flux, respectively, during the 16 years of operation showed similar evolution for all 12 types of clay material analysed, with small variations explained by differences in thermophysical characteristics specific to each type of S1-S12 earth. In the case of walls made from clay material, there is a stabilisation in the evolution of the water content phenomenon by the 5th year of simulation. This contrasts with walls made of concrete, where the characteristic water content appears to evolve continuously over the 16-year period. Therefore, it can be said that in the case of the construction elements of existing buildings, which have already gone through a sufficient period for the maturation of the materials in their construction elements, the rammed earth wall quickly develops a moisture buffer function. In the case of simulating a mineral wool core composite wall, it cannot perform as a temperature or humidity buffer, exhibiting an enthalpy exchange with indoor air that is only 4% of that of the rammed earth walls; consequently, it does not play a significant role in regulating indoor comfort conditions. Overall, there is confirmation of the temperature and moisture buffering capabilities of rammed earth walls during both warm and cold periods of the year, which is consistent with other reports in the literature. The findings of this research provide a better insight into clay as a material for rammed earth walls for more efficient design and construction, offering potential improvements regarding indoor comfort, energy efficiency, and sustainability. The data also provides useful information in the fields of architecture and civil engineering regarding the use of clay as an eco-friendly building material. The results emphasise the importance of thoroughly understanding the thermophysical properties of clay to ensure the efficiency of rammed earth construction.

Influence of the Extraction Solution on the Removal of Heavy Metals from Polluted Soils.

Soil pollution with heavy metals is a problem for the whole geosystem. The aim of the research is to identify new solutions for extracting heavy metals from polluted soils so that they can be further exploited. To this end, investigations of the physicochemical characteristics of the soil sample under study were carried out. Following the analyses, the soil was characterised as lute-coarse sand (UG) with a strongly acidic pH (4.67), a hygroscopicity coefficient (CH = 4.8% g/g), and a good supply of nutrients: nitrogen (Nt): 0.107%; mobile phosphorus (PAL): 6 mg kg-1 and mobile potassium (KAL): 26 mg kg-1, but is low in humus (2.12%). The metal content of the soil was determined by atomic absorption spectrometry (AAS), and the analyses showed high concentrations of metals (Pb: 27,660 mg kg-1; Cu: 5590 mg kg-1; Zn: 2199 mg kg-1; Cd: 11.68 mg kg-1; Cr: 146 mg kg-1). The removal of metals (Pb, Cu, Zn, Cd, and Cr) from polluted soil by different extraction agents (water, humus, malic acid, chitosan, and gluconic acid) was investigated. Metal extraction experiments were carried out in a continuous orbital rotation-oscillation stirrer at a solid/liquid/ (S/L ratio; g:mL) of 1:4, at two concentrations of extraction solution (1% and 3%), and at different stirring times (2, 4, 6, and 8 h). The yield of the extraction process is very low for all proposed extraction solutions. The maximum values of extraction efficiency are: 0.5% (Pb); 3.28% (Zn); and 5.72% (Cu). Higher values were obtained in the case of Cr (11.97%) in the variant of using humus 3% as an extraction solution at a stirring time of 6 h. In the investigated experimental conditions, the best removal efficiencies were obtained in the case of cadmium (26.71%) when using a 3% malic acid solution. In conclusion, it is considered that, from case to case, the type of extraction solution as well as the nature of the metal influence the mechanism of the depollution process, i.e., the capacity of the fine soil granules to free themselves from the pollutant metal that has adhered to them, and further research is considered necessary in the future.

Research on Thermal Insulation Performance and Impact on Indoor Air Quality of Cellulose-Based Thermal Insulation Materials.

Worldwide, the need for thermal insulation materials used to increase the energy performance of buildings and ensure indoor thermal comfort is constantly growing. There are several traditional, well-known and frequently used thermal insulation materials on the building materials market, but there is a growing trend towards innovative materials based on agro-industrial waste. This paper analyses the performance of 10 such innovative thermal insulation materials obtained by recycling cellulosic and/or animal waste, using standardised testing methods. More precisely, thermal insulation materials based on the following raw materials were analysed: cellulose acetate, cigarette filter manufacturing waste; cellulose acetate, cigarette filter manufacturing waste and cigarette paper waste; cellulose acetate, waste from cigarette filter manufacturing, waste cigarette paper and waste aluminised paper; cellulose from waste paper (two types made by two independent manufacturers); wood fibres; cellulose from cardboard waste; cellulose from waste cardboard, poor processing, inhomogeneous product; rice husk waste and composite based on sheep wool, recycled PET fibres and cellulosic fibres for the textile industry. The analysis followed the performance in terms of thermal insulating quality, evidenced by the thermal conductivity coefficient (used as a measurable indicator) determined for both dry and conditioned material at 50% RH, in several density variants, simulating the subsidence under its own weight or under various possible stresses arising in use. The results showed in most cases that an increase in material density has beneficial effects by reducing the coefficient of thermal conductivity, but exceptions were also reported. In conjunction with this parameter, the analysis of the 10 types of materials also looked at their moisture sorption/desorption capacity (using as a measurable indicator the amount of water stored by the material), concluding that, although they have a capacity to regulate the humidity of the indoor air, under low RH conditions the water loss is not complete, leaving a residual quantity of material that could favour the development of mould. Therefore, the impact on indoor air quality was also analysed by assessing the risk of mould growth (using as a measurable indicator the class and performance category of the material in terms of nutrient content conducive to the growth of microorganisms) under high humidity conditions but also the resistance to the action of two commonly encountered moulds, Aspergillus niger and Penicillium notatum. The results showed a relative resistance to the action of microbiological factors, indicating however the need for intensified biocidal treatment.

Study on the Possibilities of Developing Cementitious or Geopolymer Composite Materials with Specific Performances by Exploiting the Photocatalytic Properties of TiO2 Nanoparticles.

Starting from the context of the principles of Sustainable Development and Circular Economy concepts, the paper presents a synthesis of research in the field of the development of materials of interest, such as cementitious composites or alkali-activated geopolymers. Based on the reviewed literature, the influence of compositional or technological factors on the physical-mechanical performance, self-healing capacity and biocidal capacity obtained was analyzed. The inclusion of TiO2 nanoparticles in the matrix increase the performances of cementitious composites, producing a self-cleaning capacity and an anti-microbial biocidal mechanism. As an alternative, the self-cleaning capacity can be achieved through geopolymerization, which provides a similar biocidal mechanism. The results of the research carried out indicate the real and growing interest for the development of these materials but also the existence of some elements still controversial or insufficiently analyzed, therefore concluding the need for further research in these areas. The scientific contribution of this study consists of bringing together two apparently distinct research directions in order to identify convergent points, to create a favorable framework for the development of an area of research little addressed so far, namely, the development of innovative building materials by combining improved performance with the possibility of reducing environmental impact, awareness and implementation of the concept of a Circular Economy.

Influence of Fe2O3, MgO and Molarity of NaOH Solution on the Mechanical Properties of Fly Ash-Based Geopolymers.

The use of waste from industrial activities is of particular importance for environmental protection. Fly ash has a high potential in the production of construction materials. In the present study, the use of fly ash in the production of geopolymer paste and the effect of Fe2O3, MgO and molarity of NaOH solution on the mechanical strength of geopolymer paste are presented. Samples resulting from the heat treatment of the geopolymer paste were subjected to mechanical tests and SEM, EDS and XRD analyses. Samples were obtained using 6 molar and 8 molar NaOH solution with and without the addition of Fe2O3 and MgO. Samples obtained using a 6 molar NaOH solution where Fe2O3 and MgO were added had higher mechanical strengths compared to the other samples.

Extraction of Metals from Polluted Soils by Bioleaching in Relation to Environmental Risk Assessment.

Environmental pollution has particular implications for the whole geosystem and increases the global risk to human and ecological health. In this regard, investigations were carried out on soil samples to perform the quality status assessment by determining: pH, texture, structure and metal concentration, as well as carrying out an assessment of anthropogenic activity by determining pollution indices: Cf (contamination factor), Cd (degree of contamination), PLI (pollution load index), Er (ecological risk index) and PERI (potential ecological risk index). Analyses on soil samples showed high concentrations of metals (Cu: 113-2996 mg kg-1; Pb: 665-5466 mg kg-1; Cr: 40-187 mg kg-1; Ni: 221-1708 mg kg-1). The metal extraction experiments were carried out by bioleaching using Thiobacillusferrooxidans, microorganisms at different amounts of bioleaching solution (20 mL and 40 mL 9K medium) and a stirring time of up to 12 h. The results on the degree of contamination, pollution loading index PLI (2.03-57.23) and potential ecological risk index PERI (165-2298) indicate that the soils in the studied area have a very high degree of pollution. The decontamination procedure by bioleaching showed a decrease, but at the end of the test (12 h), the followed indices indicate high values, suggesting that bioleaching should continue. The depollution yield after 12 h of treatment is, however, encouraging: Cu 29-76%, Pb: 10-32%, Cr: 39-72% and Ni 44-68%. The use of yield-time correlation equations allows the identification of the optimal exposure time on the bioleaching extraction process to obtain optimal results. The aim of the research is to determine the soil quality, soil environmental risk, extraction of metals from polluted soils by bioleaching and to identify influencing factors in achieving high remediation yields.

Thermal Insulation Mattresses Based on Textile Waste and Recycled Plastic Waste Fibres, Integrating Natural Fibres of Vegetable or Animal Origin.

The current context provides, worldwide, the need to identify solutions for the thermal efficiency of constructions, through sustainable and innovative methods and products. A viable solution is to produce thermal insulating products by carding-folding technology, using natural fibres and recycled polyethylene terephthalate (rPET) and polyester (rPES) waste, converted to fibres. This paper presents experimental results obtained after testing several thermal insulation composite products produced using a mix of sheep wool, cellulose, rPET and rPES fibres. The results of the research demonstrate the thermal insulation properties but, at the same time, identify the benefits of using such materials on the quality of the air in the interior space (the ability to adjust humidity and reduce the concentration of harmful substances). At the same time, the advantages of using sheep wool composite mattresses concerning their resistance to insect attack is demonstrated when compared with ordinary thermal insulation materials. Finally, sensitivity elements of these composites are observed in terms of sensitivity to mould, and to contact with water or soil, drawing future research directions in the development of this type of materials.

Influence of TiO2 Nanoparticles on the Resistance of Cementitious Composite Materials to the Action of Fungal Species.

The development of mold films on the cement surfaces of buildings is a health and safety problem for the population, aesthetic but also in terms of their durability. The use of specific performance of cementitious composites containing TiO2 nanoparticles, photoactivated by UV radiation, can be a viable solution to mitigate to eliminate these problems. The experimental studies presented aim to analyze the capacity to inhibit the development of mold type Aspergillus and Penicillium on the surface of composite materials with nano-TiO2 content and the identification of the optimal range of nanomaterial addition. The identification and analysis of the inhibition halo (zone with a biological load of maximum 1-10 colonies of microorganisms) confirmed the biocidal capacity of the cementitious composites, but also indicated the possibility that an excess of TiO2 nanoparticles in the mixture could induce a development of cell resistance, which would be unfavorable both in terms of behavior and in terms of cost.

Improving Indoor Air Quality by Using Sheep Wool Thermal Insulation.

Currently, the need to ensure adequate quality of air inside the living space but also the thermal efficiency of buildings is pressing. This paper presents the capacity of sheep wool heat-insulating mattresses to simultaneously provide these needs, cumulatively analyzing efficiency indicators for thermal insulation and indicators of improving air quality. Thus, the values obtained for the coefficient of thermal conductivity, and its resistance to heat transfer, demonstrate the suitability of their use for thermal insulation. The results of the permeability to water vapor characteristics on the sorption/desorption of water, air, demonstrate the ability to control the humidity of the indoor air and the results on the reduction of the concentration of formaldehyde, demonstrating their contribution to the growth of the quality of the air, and to reduce the risk of disease in the population.

Influence of TiO2 Nanoparticles on the Resistance of Cementitious Composite Materials to the Action of Bacteria.

The formation of biofilms on cementitious building surfaces can cause visible discoloration and premature deterioration, and it can also represent a potential health threat to building occupants. The use of embedded biofilm-resistant photoactivated TiO2 nanoparticles at low concentrations in the cementitious composite matrix is an effective method to increase material durability and reduce maintenance costs. Zone of inhibition studies of TiO2-infused cementitious samples showed efficacy toward both Gram-negative and Gram-positive bacteria.