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1.
ACS Omega ; 9(25): 27710-27721, 2024 Jun 25.
Article in English | MEDLINE | ID: mdl-38947784

ABSTRACT

In this report, we introduce a novel idea to prepare a redox additive in a gel polymer electrolyte system of PVA-ZnSO4-H2SO4 based on zinc-carbon battery recycling. Here, zinc cans from spent zinc-carbon batteries are dissolved completely in 1 M H2SO4 to obtain a redox additive in an aqueous electrolyte of ZnSO4-H2SO4. Moreover, carbon nanoparticles and graphene nanosheets were synthesized from carbon rod and carbon powder from spent zinc-carbon batteries by only one step of washing and electrochemical exfoliation, respectively, which have good electrochemical capability. The three-electrode system using a ZnSO4-H2SO4 electrolyte with carbon nanoparticles and graphene nanosheets as working electrodes shows high electrochemical adaptability, which points out its promising application in supercapacitor devices. Thus, the symmetrical solid-state supercapacitor devices based on the sandwich structure of graphene nanosheets/PVA-ZnSO4-H2SO4/graphene nanosheets illustrated the highest energy density of 39.17 W h kg-1 at a power density of 1700 W kg-1. While symmetrical devices based on carbon nanoparticles/PVA-ZnSO4-H2SO4/carbon nanoparticles exhibited a maximum energy density of 35.65 W h kg-1 at a power density of 1700 W kg-1. Moreover, these devices illustrate strong durability after 5000 cycles, with approximately 90.2% and 73.1% remaining, respectively. These results provide a promising strategy for almost completely recycling zinc-carbon batteries, one of the most popular dry batteries.

2.
Heliyon ; 10(11): e32209, 2024 Jun 15.
Article in English | MEDLINE | ID: mdl-38912489

ABSTRACT

Alzheimer's disease (AD) is a brain illness that causes cognitive impairment in the elderly, especially females, as a result of genetics, hormones, and life experiences. It becomes more severe with age and is associated with cardiovascular disease, hypertension, and diabetes. Beta-amyloid plaques and hyper phosphorylated Tau protein buildup are common clinical findings. Misfiling of amyloid precursor protein (APP) and Amyloid beta peptide (Aß) proteins contributes to Alzheimer's disease. Enzyme Acetylcholinesterase enzyme interacts with amyloid-beta, enhancing its accumulation in insoluble plaques, leading to successful treatment for Alzheimer's disease primarily based on lowering this enzyme. Treatments include using the Rivastigmine for mild, moderate, or severe Alzheimer's disease, which inhibits acetylcholinesterase, but may cause side effects; Solanine derivatives, nightshade toxin, it is cholinesterase inhibitory, may mitigate Alzheimer's illness is progressing. In this research utilized a molecular docking program, which is a computer's computational ability to determine the optimal position for a specific compound to bind to a protein or target, forming a target-ligand complex and displaying biological activity and aiding in the development of effective anti-AD treatments and understanding AD pathological mechanisms. The study examined complexes of 3LII (Acetylcholinesterase receptor) in the A and B chain with Solanine and Rivastigmine derivatives, using an in-silico approach. PyRx default sorter was used to improve docking accuracy. Four compounds were selected based on their higher binding affinities in chain A and B. The results showed that Solanine derivatives (alpha-Solanine, Beta1-Solanine and Beta2-Solanine) have higher binding strength (-9.0,-9.3 and -8.6) than Rivastigmine (-7.2) in chain A, and also the binding strength was high for the Solanine derivatives (alpha-Solanine, Beta1-Solanine, and Beta2-Solanine) (-9.0,-8.8 and -8.9) is higher than Rivastigmine (-6.0) in the chain B. Solanine derivatives showed higher binding strength with acetylcholinesterase, potentially for to reduce the progression of the disease.

4.
ACS Omega ; 9(21): 22543-22556, 2024 May 28.
Article in English | MEDLINE | ID: mdl-38826542

ABSTRACT

In this paper, carbon materials, including graphene nanosheets and carbon nanoparticles, were prepared from spent zinc-carbon batteries by the following two simple methods: electrochemical exfoliation and ultrasonication. Here, graphene nanosheets were synthesized by electrochemical exfoliation in 0.5 M H2SO4 by using a direct current power supply with two carbon rods from spent zinc-carbon batteries. Carbon nanoparticles were prepared by fast ultrasonication in a low-cost, green solution of DI water and ethanol. Graphene nanosheets in this study have high quality, large scale, and good electrochemical ability, while carbon nanoparticles have a unique nanosize and a good specific surface area. These carbon materials were applied for electrochemical measurements for supercapacitor studies and showed excellent stability at different temperatures. Moreover, electric double-layer capacitor devices based on graphene nanosheets and carbon nanoparticles were also used in electrochemical studies with strong stability and good electrochemical capability.

5.
Micromachines (Basel) ; 15(6)2024 May 29.
Article in English | MEDLINE | ID: mdl-38930684

ABSTRACT

The development of nanocomposite photocatalysts with high photocatalytic activity, cost-effectiveness, a simple preparation process, and scalability for practical applications is of great interest. In this study, nanocomposites of TiO2 Degussa P25 nanoparticles/activated carbon (TiO2/AC) were prepared at various mass ratios of (4:1), (3:2), (2:3), and (1:4) by a facile process involving manual mechanical pounding, ultrasonic-assisted mixing in an ethanol solution, paper filtration, and mild thermal annealing. The characterization methods included XRD, SEM-EDS, Raman, FTIR, XPS, and UV-Vis spectroscopies. The effects of TiO2/AC mass ratios on the structural, morphological, and photocatalytic properties were systematically studied in comparison with bare TiO2 and bare AC. TiO2 nanoparticles exhibited dominant anatase and minor rutile phases and a crystallite size of approximately 21 nm, while AC had XRD peaks of graphite and carbon and a crystallite size of 49 nm. The composites exhibited tight decoration of TiO2 nanoparticles on micron-/submicron AC particles, and uniform TiO2/AC composites were obtained, as evidenced by the uniform distribution of Ti, O, and C in an EDS mapping. Moreover, Raman spectra show the typical vibration modes of anatase TiO2 (e.g., E1g(1), B1g(1), Eg(3)) and carbon materials with D and G bands. The TiO2/AC with (4:1), (3:2), and (2:3) possessed higher reaction rate constants (k) in photocatalytic degradation of methylene blue (MB) than that of either TiO2 or AC. Among the investigated materials, TiO2/AC = 4:1 achieved the highest photocatalytic activity with a high k of 55.2 × 10-3 min-1 and an MB removal efficiency of 96.6% after 30 min of treatment under UV-Vis irradiation (120 mW/cm2). The enhanced photocatalytic activity for TiO2/AC is due to the synergistic effect of the high adsorption capability of AC and the high photocatalytic activity of TiO2. Furthermore, TiO2/AC promotes the separation of photoexcited electron/hole (e-/h+) pairs to reduce their recombination rate and thus enhance photocatalytic activity. The optimal TiO2/AC composite with a mass ratio of 4/1 is suggested for treating industrial or household wastewater with organic pollutants.

6.
Microb Genom ; 10(5)2024 May.
Article in English | MEDLINE | ID: mdl-38739115

ABSTRACT

Aeromonas spp. are commonly found in the aquatic environment and have been responsible for motile Aeromonas septicemia (MAS) in striped catfish, resulting in significant economic loss. These organisms also cause a range of opportunistic infections in humans with compromised immune systems. Here, we conducted a genomic investigation of 87 Aeromonas isolates derived from diseased catfish, healthy catfish and environmental water in catfish farms affected by MAS outbreaks in eight provinces in Mekong Delta (years: 2012-2022), together with 25 isolates from humans with bloodstream infections (years: 2010-2020). Genomics-based typing method precisely delineated Aeromonas species while traditional methods such as aerA PCR and MALDI-TOF were unable identify A. dhakensis. A. dhakensis was found to be more prevalent than A. hydrophila in both diseased catfish and human infections. A. dhakensis sequence type (ST) 656 followed by A. hydrophila ST251 were the predominant virulent species-lineages in diseased catfish (43.7 and 20.7 %, respectively), while diverse STs were found in humans with bloodstream infections. There was evidence of widespread transmission of ST656 and ST251 on striped catfish in the Mekong Delta region. ST656 and ST251 isolates carried a significantly higher number of acquired antimicrobial resistance (AMR) genes and virulence factors in comparison to other STs. They, however, exhibited several distinctions in key virulence factors (i.e. lack of type IV pili and enterotoxin ast in A. dhakensis), AMR genes (i.e. presence of imiH carbapenemase in A. dhakensis), and accessory gene content. To uncover potential conserved proteins of Aeromonas spp. for vaccine development, pangenome analysis has unveiled 2202 core genes between ST656 and ST251, of which 78 proteins were in either outer membrane or extracellular proteins. Our study represents one of the first genomic investigations of the species distribution, genetic landscape, and epidemiology of Aeromonas in diseased catfish and human infections in Vietnam. The emergence of antimicrobial resistant and virulent A. dhakensis strains underscores the needs of enhanced genomic surveillance and strengthening vaccine research and development in preventing Aeromonas diseases in catfish and humans, and the search for potential vaccine candidates could focus on Aeromonas core genes encoded for membrane and secreted proteins.


Subject(s)
Aeromonas , Catfishes , Fish Diseases , Gram-Negative Bacterial Infections , Sepsis , Animals , Catfishes/microbiology , Vietnam/epidemiology , Aeromonas/genetics , Aeromonas/isolation & purification , Aeromonas/classification , Aeromonas/pathogenicity , Gram-Negative Bacterial Infections/microbiology , Gram-Negative Bacterial Infections/veterinary , Gram-Negative Bacterial Infections/epidemiology , Humans , Sepsis/microbiology , Sepsis/veterinary , Sepsis/epidemiology , Fish Diseases/microbiology , Phylogeny , Genomics , Genome, Bacterial , Virulence Factors/genetics , Anti-Bacterial Agents/pharmacology
7.
J Environ Manage ; 359: 121058, 2024 May.
Article in English | MEDLINE | ID: mdl-38714036

ABSTRACT

Water pollution remains a pressing environmental issue, with diverse pollutants such as heavy metals, pharmaceuticals, dyes, and aromatic hydrocarbon compounds posing a significant threat to clean water access. Historically, biomass-derived activated carbons (ACs) have served as effective adsorbents for water treatment, owing to their inherent porosity and expansive surface area. Nanocomposites have emerged as a means to enhance the absorption properties of ACs, surpassing conventional AC performance. Biomass-based activated carbon nanocomposites (ACNCs) hold promise due to their high surface area and cost-effectiveness. This review explores recent advancements in biomass-based ACNCs, emphasizing their remarkable adsorption efficiencies and paving the way for future research in developing efficient and affordable ACNCs. Leveraging real-time communication for ACNC applications presents a viable approach to addressing cost concerns.


Subject(s)
Charcoal , Fruit , Nanocomposites , Vegetables , Water Purification , Nanocomposites/chemistry , Charcoal/chemistry , Water Purification/methods , Fruit/chemistry , Adsorption , Vegetables/chemistry , Water Pollutants, Chemical/chemistry , Biomass
8.
Int J Biol Macromol ; 268(Pt 2): 131760, 2024 May.
Article in English | MEDLINE | ID: mdl-38663693

ABSTRACT

In the adsorption process for wastewater treatment, the adsorbent plays an important role. A composite adsorptive material composed of graphitic carbon nitride and agar-derived porous carbon (CNPC) was fabricated from simple precursors (melamine, thiourea, and agar) and through a facile procedure with different melamine and thiourea ratios. Characterization of CNPC proved a successful formation of a porous structure consisting of mesopores and macropores, wherein CNPC holds distinctive electrochemical (lowered resistance and higher specific capacity) and photochemical properties (lowered bandgap to 2.33 eV) thanks to the combination of graphitic carbon nitride (CN) and agar-derived porous carbon (PC). Inheriting the immanent nature, CNPC was subjected to the adsorption of methylene blue (MB) dye in an aqueous solution. The highest adsorption capacity was 133 mg/g for CNPC-4 which was prepared using a melamine to thiourea ratio of 4:4 - equivalent to the removal rate of 53.2 % and following the pseudo-I-order reaction rate. The effect of pH points out that pH 7 and 9 were susceptible to maximum removal and pretreatment is not required while the optimal ratio of 7.5 mg of MB and 30 mg of material was also determined to yield the highest performance. Furthermore, the reusability of the material for three consecutive cycles was evaluated based on two methods pyrolysis at 200 °C and photocatalytic degradation by irradiation under visible light. In general, the photocatalytic regeneration pathway is more ample and efficient than pyrolysis in terms of energy efficiency (saving energy over 10 times) and adsorption capacity stability. As a whole, the construction of accessible regenerative and stable adsorbent could be a venturing step into the sustainable development spearhead for industries.


Subject(s)
Agar , Graphite , Methylene Blue , Water Pollutants, Chemical , Adsorption , Graphite/chemistry , Porosity , Water Pollutants, Chemical/chemistry , Water Pollutants, Chemical/isolation & purification , Methylene Blue/chemistry , Agar/chemistry , Water Purification/methods , Triazines/chemistry , Environmental Restoration and Remediation/methods , Carbon/chemistry , Wastewater/chemistry , Hydrogen-Ion Concentration , Nitrogen Compounds/chemistry , Kinetics , Thiourea/chemistry
9.
Nanotechnology ; 35(26)2024 Apr 09.
Article in English | MEDLINE | ID: mdl-38527359

ABSTRACT

A novel, rapid, and facile method for one-step sonoelectrochemical synthesis of zinc oxide nanoparticles (UEZ) was introduced in this study. The optimum operating parameters have been selected at a voltage of 7.5 V, KCl concentration of 0.5 M, and the reaction time of 60 min. The as-prepared UEZ were characterized by XRD, SEM, and HRTEM. It was found that the UEZ has a hexagonal wurtzite structure with high crystalline quality, good purity, a size range of 30-100 nm, and good photocatalytic degradation of methylene blue. This work provides a facile route for large-scale synthesizing ZnO nanoparticles via anodization.

10.
Environ Monit Assess ; 196(4): 395, 2024 Mar 25.
Article in English | MEDLINE | ID: mdl-38528293

ABSTRACT

This study assessed the accumulation levels and ecological risks associated with seven heavy metals (As, Pb, Cd, Hg, Cu, Cr, Zn) in the surface sediments of the Bong Mieu River in Quang Nam Province, Vietnam. The sampling encompassed 10 locations (S1-S10), considering areas both impacted and less impacted by gold mining activities. The findings revealed elevated levels of heavy metal pollution and associated ecological risks attributable to gold mining. Heavy metal content varied within specific ranges: As (70.6-341.2 mg/kg), Pb (216.3-504.1 mg/kg), Hg (0.138-0.252 mg/kg), Cd (0.91-1.51mg/kg), Cu (18.3-45.5 mg/kg), Cr (10.5-19.1 mg/kg), and Zn (49.3-84.1 mg/kg). Among these elements, Hg, Cu, Cr, Zn, and Cd adhered to the acceptable limits of VNTR 43:2017/MONRE (VNTR 43:2017/MONRE: National Technical Regulation/Ministry of Natural Resources and Environment of Vietnam). However, As and Pb content at all locations exceeded these limits significantly, with As being 4.1-20 times higher and Pb 2.3-5.5 times higher. The pollution of Pb and As was attributed to waste discharge from gold mining activities, which carry substantial amounts of these metals in various forms. The Igeo indicated heavy pollution of As and Pb in the sediments. Ecological risk factors were ranked as follows: E r i (As) > E r i (Pb) > E r i (Hg) > E r i (Cd) > E r i (Cu) > E r i (Cr) > E r i (Zn). The potential ecological risk (RI) due to combined heavy metal impact varied across locations, with S2 > S8 > S9 > S6 > S7 > S10 > S1 > S3 > S4 > S5, exhibiting low to moderate risk (RI values ranging from 73.4 to 252.8). The study area demonstrated high contamination levels for As and Pb, coupled with low to moderate potential ecological risks.


Subject(s)
Mercury , Metals, Heavy , Water Pollutants, Chemical , Rivers , Vietnam , Cadmium , Lead , Risk Assessment , Environmental Monitoring , Water Pollutants, Chemical/analysis , Geologic Sediments , Metals, Heavy/analysis , Gold , China
11.
Int J Epidemiol ; 53(1)2024 Feb 01.
Article in English | MEDLINE | ID: mdl-37843876

ABSTRACT

BACKGROUND: Despite an increasing proportion of smokers who use non-cigarette products, the harmfulness of these is inconsistent. This study aimed to evaluate the impact of waterpipe tobacco (WTP) smoking on all-cause mortality. METHODS: A prospective cohort study followed up on 35 646 participants from 2007 to 2019 in Northern Viet Nam. Data for each type of cigarette and WTP smoking were collected based on demographic lifestyle and semi-quantitative food frequency questionnaires. Smokers were categorized as current smokers and former smokers who were lifetime ever smokers but stopped smoking >6 months before the interview. Data on all-cause mortality (2449 deaths) were obtained from medical records at the state health facilities. The hazard ratios (HRs) and 95% CIs for mortality were estimated using a Cox proportional-hazards model. RESULTS: Compared with non-smokers, ever smokers had a higher all-cause mortality risk (HR = 1.29, 95% CI = 1.16-1.43). Current WTP (HR = 1.37, 95% CI = 1.19-1.57), current cigarette (HR = 1.40, 95% CI = 1.22-1.60) and former WTP smokers (HR = 1.39, 95% CI = 1.10-1.76) showed an elevated risk of dying. The mortality risk was significantly elevated in dual smokers using WTP and cigarettes (HR = 1.55, 95% CI = 1.35-1.79) and exclusive WTP smokers (HR = 1.38, 95% CI = 1.21-1.57). Elevated risk was observed for the main targeted attractions of cancer, diabetes and heart diseases. Smoking cessation of >10 years decreased the risk of all-cause mortality (HR = 0.61, 95% CI = 0.44-0.85) and cancer (HR = 0.24, 95% CI = 0.11-0.52). CONCLUSIONS: WTP smoking increases the risk of all-cause mortality. A unique programme to control exposure to WTP should be a high priority in Viet Nam and other countries.


Subject(s)
Neoplasms , Smoking Cessation , Tobacco, Waterpipe , Humans , Prospective Studies , Smoking/adverse effects , Smoking/epidemiology
12.
Heliyon ; 9(11): e21041, 2023 Nov.
Article in English | MEDLINE | ID: mdl-37928005

ABSTRACT

The main aim of this study is to figure out how well cryptand-2.2.1 (C 2.2.1) and cryptand-2.1.1 (C 2.1.1) macrocyclic compounds (MCs) work as novel extractants for scandium (Sc) by using an artificial neural network (ANN) models in MATLAB software. Moreover, C2.2.1 and C2.1.1 have never been evaluated to recover Sc. The independent variables impacting the extraction process (concentration of MC, concentration of Sc, pH, and time), and a nonlinear autoregressive network with exogenous input (NARX) and feed-forward neural network (FFNN) models were used to estimate their optimum values. The greatest obstacle in the selective recovery process of the REEs is the similarity in their physicochemical properties, specifically their ionic radius. The recovery of Sc from the aqueous solution was experimentally evaluated, then the non-linear relationship between those parameters was predictively modeled using (NARX) and (FFNN). To confirm the extraction and stripping efficiency, an atomic absorption spectrophotometer (AAS) was employed. The results of the extraction investigations show that, for the best conditions of 0.008 mol/L MC concentration, 10 min of contact time, pH 2 of the aqueous solution, and 75 mg/L Sc initial concentration, respectively, the C 2.1.1 and C 2.2.1 extractants may reach 99 % of Sc extraction efficiency. Sc was recovered from a multi-element solution of scandium (Sc), yttrium (Y), and lanthanum (La) under these circumstances. Whereas, at a concentration of 0.3 mol/L of hydrochloric acid, the extraction of Sc was 99 %, as opposed to Y 10 % and La 7 %. The Levenberg-Marquardt training algorithm had the best training performance with an mean-squared-error, MSE, of 5.232x10-6 and 6.1387x10-5 for C 2.2.1 and C 2.1.1 respectively. The optimized FFNN architecture of 4-10-1 was constructed for modeling recovery of Sc. The extraction process was well modeled by the FFNN with an R2 of 0.999 for the two MC, indicating that the observed Sc recovery efficiency consistent with the predicted one.

13.
Heliyon ; 9(11): e21345, 2023 Nov.
Article in English | MEDLINE | ID: mdl-37954383

ABSTRACT

The lateritic ore drying in the Cuban nickel producing industry is realized within flighted rotary dryers. In this investigation, performance indicators in regards to transfer of momentum, heat and mass were evaluated. The dryers operate in a concurrent configuration with combustion gas, at a productivity between 40 t h-1 and 50 t h-1. The distribution function of the residence time (RTD) was best fitted to a model of a multi-branch tanks-in-series system, theoretical residence time was 51 ± 2 min and experimental mean residence time 61 min, at a rate of 45 t h-1 and hydraulic efficiency 1.23, due to the presence of dead-zoon. Mass and energy balance was made following a "black box" model, as results, the specific fuel consumption was 27.25 ± 0.25 kg fuel t-1 of wet ore, specific energy consumption 79.66 ± 0.95 kg fuel t-1 of H2O evaporated, energy efficiency 97.28 ± 0.01 %, thermal efficiency 66.88 ± 0.71 % and drying efficiency 98.77 ± 0.12 %. Mathematical modelling was made using a system of differential equations, the rate of drying in falling rate period was estimated by Arrhenius equation, then, temperature profile and ore moisture content along the dryer was simulated. The model provided a successful predictive performance; for an inlet gas temperature between 850 °C and 900 °C, the ore moisture was reduced form 33.0 % (wet basis) to a range depending on the dryer productivity, from 3.0 % to 7.1 %. Designing a computerized system that implements these algorithms can benefit on efficiency and productivity of the production plant.

14.
Case Rep Crit Care ; 2023: 7888990, 2023.
Article in English | MEDLINE | ID: mdl-37799271

ABSTRACT

Pseudoaneurysm rupture in patients with pancreatitis is a rare but fatal etiology of upper gastrointestinal bleeding. We report a rare case of upper gastrointestinal bleeding in a patient who presented simultaneously with two pseudoaneurysms, a potential cause of severe gastrointestinal bleeding. Angiography was successfully performed with coil embolization of the target arteries and both pseudoaneurysmal sacs. The patient was discharged 9 days after admission without further events within a 3-month follow-up period.

15.
Mar Pollut Bull ; 196: 115636, 2023 Nov.
Article in English | MEDLINE | ID: mdl-37813060

ABSTRACT

The goal of this study was to identify the presence of microplastics on the beach near a refinery in the central coast of Vietnam. In this study, 11 sampling sites were selected within a length of 300 m of the beach. The results showed that microplastics were presented in all collected samples with an average concentration of 1582 ± 660 MPs/kg. Fibers were the predominant shape of microplastics found in the samples, which accounted for 57.11 %, while the rest were classified as fragments. The average size of microplastics varied greatly around 83.1 ± 74.3 µm with the vast majority having a size smaller than 50 µm (41.84 %). A total of 11 polymers of microplastics were detected from collected samples, Polyethylene Terephthalate was the main polymer with 46.43 %. The pollution load index of microplastics was 3.15 showing that refinery activities could expose microplastic to the environment.


Subject(s)
Microplastics , Water Pollutants, Chemical , Plastics , Vietnam , Water Pollutants, Chemical/analysis , Environmental Monitoring , Polymers , Risk Assessment
16.
Heliyon ; 9(9): e19746, 2023 Sep.
Article in English | MEDLINE | ID: mdl-37809844

ABSTRACT

All-solid-state lithium batteries (ASSLBs) using solid polymer electrolytes (SPEs) are believed to be future next-generation batteries aiming to replace high-risk traditional batteries using liquid electrolytes, which have a wide application range in portable electronic devices, portable power supplies, and especially in electric vehicles. Moreover, the appearance of SPEs can overcome the electrolyte leakage and flammability problems in conventional lithium-ion batteries. Nevertheless, ASSLBs still face some limitations due to the low ionic conductivity of solid-state electrolytes (SSEs) at room temperature and the poor contact electrode/electrolyte interface, which can be solved by suitable strategies. Currently, the research strategies of metal-organic frameworks that can be incorporated into solid polymer electrolytes offer a remarkable method for producing uniform solid polymer electrolytes that have good electrode/electrolyte contact interfaces and high ionic conductivity. Herein, the updates of current studies about metal-organic framework-incorporated composite solid polymer electrolytes are discussed in this mini-review.

17.
Micromachines (Basel) ; 14(10)2023 Sep 29.
Article in English | MEDLINE | ID: mdl-37893316

ABSTRACT

In this study, samarium (Sm-10at%)-doped BiFeO3 (SmBFO) thin films were grown on platinum-coated glass substrates using pulsed laser deposition (PLD) to unveil the correlation between the microstructures and nanomechanical properties of the films. The PLD-derived SmBFO thin films were prepared under various oxygen partial pressures (PO2) of 10, 30, and 50 mTorr at a substrate temperature of 600 °C. The scanning electron microscopy analyses revealed a surface morphology consisting of densely packed grains, although the size distribution varied with the PO2. X-ray diffraction results indicate that all SmBFO thin films are textured and preferentially oriented along the (110) crystallographic orientation. The crystallite sizes of the obtained SmBFO thin films calculated from the Scherrer and (Williamson-Hall) equations increased from 20 (33) nm to 25 (52) nm with increasing PO2. In addition, the nanomechanical properties (the hardness and Young's modulus) of the SmBFO thin films were measured by using nanoindentation. The relationship between the hardness and crystalline size of SmBFO thin films appears to closely follow the Hall-Petch equation. In addition, the PO2 dependence of the film microstructure, the crystallite size, the hardness, and Young's modulus of SmBFO thin films are discussed.

18.
Chem Commun (Camb) ; 59(80): 12035-12038, 2023 Oct 05.
Article in English | MEDLINE | ID: mdl-37729393

ABSTRACT

New phosphorescent "carbene-metal-carboranyl" (CMC) Cu(I) and Au(I) complexes based on the diamidocarbene (DAC) ligand show up to 68% photoluminescence quantum yield and microsecond range lifetimes. CMC organic light emitting diodes (OLEDs) emit sky-blue and warm white electroluminescence.

19.
RSC Adv ; 13(40): 28262-28287, 2023 Sep 18.
Article in English | MEDLINE | ID: mdl-37753405

ABSTRACT

Hydrogen is the most environmentally friendly and cleanest fuel that has the potential to supply most of the world's energy in the future, replacing the present fossil fuel-based energy infrastructure. Hydrogen is expected to solve the problem of energy shortages in the near future, especially in complex geographical areas (hills, arid plateaus, etc.) and harsh climates (desert, ice, etc.). Thus, in this report, we present a current status of achievable hydrogen fuel based on various scopes, including production methods, storage and transportation techniques, the global market, and the future outlook. Its objectives include analyzing the effectiveness of various hydrogen generation processes and their effects on the economy, society, and environment. These techniques are contrasted in terms of their effects on the environment, manufacturing costs, energy use, and energy efficiency. In addition, hydrogen energy market trends over the next decade are also discussed. According to numerous encouraging recent advancements in the field, this review offers an overview of hydrogen as the ideal renewable energy for the future society, its production methods, the most recent storage technologies, and transportation strategies, which suggest a potential breakthrough towards a hydrogen economy. All these changes show that this is really a profound revolution in the development process of human society and has been assessed as having the same significance as the previous industrial revolution.

20.
Heliyon ; 9(7): e17794, 2023 Jul.
Article in English | MEDLINE | ID: mdl-37456018

ABSTRACT

Several conventional methods are employed to remove numerous pollutants from oily wastewater discharged from oil-field activities. The purpose of this study is to use a new design of an electrocoagulation reactor (ECR) to treat oily wastewater effluents from the Al-Muthanna petroleum plant to minimize a Total Dissolved Solids (TDS) to levels suitable for employment. In a continuous ECR, a One-Sided-Finned cathode tube (1SF) made of aluminum was inserted between a pair of aluminum-cylindrical anodes. The effects of the electrolysis period (4-60 min), current density (0.63-5.0 mA/cm2), and flow rate (50-150 ml/min) on Final TDS value were investigated. The increment of flow rate causes the final TDS value to be increased, while the extending of the electrolysis process and the raise in current density reduces it. The final TDS was 1842.54 mg/l (reduce by 307.46 mg/l) at optimum values of 1-h electrolysis, 5 mA/cm2 current density, and 50 ml/min flow rate, with an inner anode consumption of 0.13 g and an outer anode consumption of 0.43 g. Regression models with a p-value of 0.001 and F-value of 27.01 noted that the selected model components were important, and the estimated model is considered prominent. Furthermore, the regression coefficient (R2 = 97.99%) for the final TDS response revealed that the model fit the data well. This study confirmed the ability of the new electrocoagulation reactor to treat petroleum wastewater under significant conditions which overcomes the drawbacks of the conventional designs of electrocoagulation reactors.

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