ABSTRACT
This study investigates the possibility of using municipal solid waste incineration fly ash as a supplementary cementitious material to replace part of the clinker in cement. Life cycle assessment has shown that the partial replacement of clinker with blast furnace slag (CEM III) reduces cement's global warming potential by ~30%, while replacing clinker with fly ash reduces it by up to 55%. When using CEM III as the control binder in cement in which 55 wt% of the clinker was replaced with hydrothermally treated fly ash, the flexural strength decreased by ~60% and the compressive strength by ~65%. When the fly ash was mixed with calcined and vitrified demolition materials, flexural strength decreased by ~30% and compressive strength by ~50%. The hardening of the hydraulic binders fixed the heavy metals in the municipal solid waste incineration fly ash.
ABSTRACT
The current shortage of pediatric multivisceral donors accounts for the long time and mortality on the waiting list of pediatric patients. The use of donors after cardiac death, especially after the outbreak of normothermic regional perfusion, has increased in recent years for all solid organs except the intestine, mainly because of its higher susceptibility to ischemia-reperfusion injury. We present the first literature case of multivisceral donors after cardiac death transplantation in a 13-month-old recipient from a 2.5-month-old donor. Once exitus was certified, an extracorporeal membrane oxygenation circuit was established, cannulating the aorta and infrarenal vena cava, while the supra-aortic branches were clamped. The abdominal organs completely recovered from ischemia through normothermic regional perfusion (extracorporeal membrane oxygenation initially and beating heart later). After perfusion with the preservation solution, the multivisceral graft was uneventfully implanted. Two months later, the patient was discharged without any complications. This case demonstrates the possibility of reducing the time spent on the waiting list for these patients.
Subject(s)
Organ Preservation , Tissue and Organ Procurement , Humans , Child , Infant , Organ Preservation/adverse effects , Tissue Donors , Death , Tissue and Organ Harvesting , PerfusionABSTRACT
The organisational life cycle assessment (O-LCA) and the social organisational life cycle assessment (SO-LCA) of the University of the Basque Country UPV/EHU were conducted. The data presented in this paper support the calculation of the environmental and social footprint of the University of the Basque Country UPV/EHU for year 2016 [1], and may be used as a reference for future calculations of the environmental and social footprint of higher education institutions and other organisations. This dataset provides detailed information on the UPV/EHU and the boundaries considered; on the compilation and quantification of the life cycle inventory (LCI) -which included a transport survey conducted in summer 2018-; and on the modelling process followed for the calculation of the environmental and social footprints, based on the ecoinvent 3.3 database [2] and PSILCA-based Soca v1 add-on [3, 4], and carried out with the openLCA free software [5]. The dataset also includes the life cycle impact assessment (LCIA) results provided by the CML (baseline, 2015) [6] and ReCiPe (endpoint (H), 2008) [7] LCIA methods and post-processed social impacts provided by the Social Impacts Weighting Method [3], disaggregated by subprocesses and impact locations. Data is provided for the reference year (2016), and some aggregated data is also provided for alternative scenarios that were explored in order to check pathways to reduce social and environmental impacts of the academic activity of the UPV/EHU [1].
ABSTRACT
Municipal solid waste incinerator (MSWI) fly ash is a residue of municipal solid waste incineration whose recycling is currently a worldwide problem. Therefore, considerable efforts are being made to establish effective recovery techniques so MSWI can be used as a substitute for natural resources in construction, as in masonry blocks, roads and so on, or in the manufacture of new materials. MSWI fly ashes contain elements such as Ca, Si and Al, which make it possible for them to be used as raw material to manufacture cements. This paper presents the results obtained from the physicochemical characterization of two MSWI fly ashes from two Spanish cities. The research aims to explore the feasibility of using MSWI fly ash as raw material for sintering belite cements. The results show that MSWI fly ashes have a suitable composition. However, appropriate pre-treatment will be required to eliminate chloride and possible traces of heavy metals and to improve pozzolanic activity. Furthermore, the addition of vitreous silica in the proper proportions is required. The phases generated after calcination of the blend at 800 °C are not those corresponding to pure belite cements. Nevertheless, the possibility of using these ashes as supplementary cementitious material in the manufacture of eco-cements should be contemplated.
