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Carbohydr Res ; 499: 108228, 2021 Jan.
Article in English | MEDLINE | ID: mdl-33429168

ABSTRACT

In this note, an hydrozirconation/bromination/Michaelis-Arbuzov sequence was developped to introduce a trimethylene phosphonate unit on ketopyranosides. Performed on polyfunctional substrates bearing orthogonal protecting groups, this new approach provided a straightforward entry towards a large diversity of glycophosphomimetics having a quaternary anomeric position.


Subject(s)
Organophosphorus Compounds/chemical synthesis , Carbohydrates/chemistry , Glycosylation , Halogenation , Ketones/chemistry , Molecular Structure , Organophosphorus Compounds/chemistry
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