Interference micro/nanolenses of salts for local modulation of Raman scattering.

Micro/nanolenses play a crucial role in optics and spectroscopy, but the effect of interference patterns within each lens has been largely unexplored. Herein, we investigate modulation of Raman scattering by the interference within a single micro/nanolens of a hygroscopic salt. Lenses having two different diameter (d) ranges, d > 2 µm and d ∼1 µm, are placed on a silicon substrate, followed by collection of a Raman intensity map of the silicon peak. Lenses with d > 2 µm show dark and bright circular fringes in the Raman map, resembling the Newton's rings formed by optical interference. In the smaller lenses (d ∼1 µm), the map yields only a single peak at the center, representing either an intensity maximum or minimum. In both diameter ranges, whether the Raman intensity is enhanced or suppressed is determined by interference conditions, such as wavelength of the excitation laser or thickness of the SiO2 layer. The interference in salt micro/nanolenses finds applications in local modulation of Raman scattering of a nanoscale object, as demonstrated in individual single-walled carbon nanotubes decorated with the salt lenses.

Potential of Carbon Nanotube Chemiresistor Array in Detecting Gas-Phase Mixtures of Toxic Chemical Compounds.

Toxic industrial chemicals (TICs), when accidentally released into the workplace or environment, often form a gaseous mixture that complicates detection and mitigation measures. However, most of the existing gas sensors are unsuitable for detecting such mixtures. In this study, we demonstrated the detection and identification of gaseous mixtures of TICs using a chemiresistor array of single-walled carbon nanotubes (SWCNTs). The array consists of three SWCNT chemiresistors coated with different molecular/ionic species, achieving a limit of detection (LOD) of 2.2 ppb for ammonia (NH3), 820 ppb for sulfur dioxide (SO2), and 2.4 ppm for ethylene oxide (EtO). By fitting the concentration-dependent sensor responses to an adsorption isotherm, we extracted parameters that characterize each analyte-coating combination, including the proportionality and equilibrium constants for adsorption. Principal component analysis confirmed that the sensor array detected and identified mixtures of two TIC gases: NH3/SO2, NH3/EtO, and SO2/EtO. Exposing the sensor array to three TIC mixtures with various EtO/SO2 ratios at a fixed NH3 concentration showed an excellent correlation between the sensor response and the mixture composition. Additionally, we proposed concentration ranges within which the sensor array can effectively detect the gaseous mixtures. Being highly sensitive and capable of analyzing both individual and mixed TICs, our gas sensor array has great potential for monitoring the safety and environmental effects of industrial chemical processes.