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Synthesis and biological activity of optically active phenylbutenoid dimers.
Chu, Jeonghyun; Suh, Dong Hoon; Lee, Gehyung; Han, Ah-Reum; Chae, Song Wha; Lee, Hwa Jeong; Seo, Eun-Kyoung; Lim, Hee-Jong.
J Nat Prod ; 74(8): 1817-21, 2011 Aug 26.
Article in English | MEDLINE | ID: mdl-21770432

ABSTRACT

The total synthesis of optically active phenylbutenoid dimers 1, 3, and ent-3 is described. The key step to access optically active cyclohexene rings was achieved by Diels-Alder reaction of chiral acryloyloxazolinone 9 and phenylbetadiene 10.


Subject(s)
Benzene Derivatives/chemical synthesis , Benzene Derivatives/pharmacology , Butyrates/chemical synthesis , Butyrates/pharmacology , Cyclohexenes/chemical synthesis , Cyclohexenes/pharmacology , Benzene Derivatives/chemistry , Butyrates/chemistry , Cyclohexenes/chemistry , Female , Humans , Molecular Structure , Stereoisomerism
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