ABSTRACT
External control over the pore size of flexible metal-organic frameworks (MOFs) has recently emerged as an intriguing concept, with possible applications to gas storage and separation. In this work we present a new pressure cell capable for the first time of monitoring through in situ X-ray powder diffraction an adsorbent powder under combined uniaxial applied mechanical stress (up to 1â GPa) and gas pressure (up to 20â bar). The combined stress-pressure clamp (CSPC) cell was successfully exploited to follow the evolution of the CO2 breathing behaviour of the prototypical complex breathing MIL-53(Al) system under mechanical compression obtaining structural evidence that this MOF can be maintained in its closed pore state upon compression, precluding its re-opening at high gas pressure (>7â bar). This novel setup shows potential for the in-operando exploration of flexible systems, in equilibrium and flow configurations.
ABSTRACT
The spatial structure of the vertical component of the electric field emitted by base stations in the Brussels region (Belgium) is measured, and studied using the variogram. A relationship between the variogram shape and base station antenna density in each measurement area is found; the variogram range and sill level are shown to depend on cellular base stations' antenna density, following exponential laws. Bioelectromagnetics. 37:557-562, 2016. © 2016 Wiley Periodicals, Inc.
