Trace element partitioning in basaltic systems as a function of oxygen fugacity.

Along with temperature, pressure and melt chemistry, magmatic oxygen fugacity (fO2) has an important influence on liquid and solid differentiation trends and melt structure. To explore the effect of redox conditions on mineral stability and mineral-melt partitioning in basaltic systems we performed equilibrium, one-atmosphere experiments on a picrite at 1200-1110 °C with fO2 ranging from NNO-4 log units to air. Clinopyroxene crystallizes from 1180 °C to near-solidus, along with plagioclase, olivine and spinel. Olivine Mg# increases with increasing fO2, eventually reacting to pigeonite. Spinel is absent under strongly reducing conditions. Mineral-melt partition coefficients (D) of redox-sensitive elements (Cr, Eu, V, Fe) vary systematically with fO2 and, in some cases, temperature (e.g. DCr in clinopyroxene). Clinopyroxene sector zoning is common; sectors along a- and b-axes have higher AlIV, AlVI, Cr and Ti and lower Mg than c-axis sectors. In terms of coupled substitutions, clinopyroxene CaTs (MgSi = AlVIAlIV) prevails under oxidized conditions (≥ NNO), where Fe3+ balances the charge, but is limited under reduced conditions. Overall, AlIV is maximised under high temperature, oxidizing conditions and in slowly grown (a-b) sectors. High AlIV facilitates incorporation of REE (REEAlIV = CaSi), but DREE (except DEu) show no systematic dependence on fO2 across the experimental suite. In sector zoned clinopyroxenes enrichment in REE3+ in Al-rich sectors is quantitatively consistent with the greater availability of suitably-charged M2 lattice sites and the electrostatic energy penalty required to insert REE3+ onto unsuitably-charged M2 sites. By combining our experimental results with published data, we explore the potential for trace element oxybarometry. We show that olivine-melt DV, clinopyroxene-melt DV/DSc and plagioclase-melt DEu/DSr all have potential as oxybarometers and we present expressions for these as a function of fO2 relative to NNO. The crystal chemical sensitivity of heterovalent cation incorporation into clinopyroxene and the melt compositional sensitivity of the Eu2+-Eu3+ redox potential limit the use of clinopyroxene-melt and plagioclase-melt, however, olivine-melt DV affords considerable precision and accuracy as an oxybarometer that is independent of temperature, and crystal and melt composition. Variation of DV and DV/DSc with fO2 for olivine and clinopyroxene contains information on redox speciation of V in coexisting melt. By comparing the redox speciation constraints from partitioning to data from Fe-free synthetic systems and XANES spectroscopy of quenched glasses, we show that homogenous equilibria involving Fe and V species modify V speciation on quench, leading to a net overall reduction in the average vanadium valence. Mineral-melt partitioning of polyvalent species can be a useful probe of redox speciation in Fe-bearing systems that is unaffected by quench effects. Supplementary Information: The online version contains supplementary material available at 10.1007/s00410-023-02069-x.

Microwave plasmonic mixer in a transparent fibre-wireless link.

To cope with the high bandwidth requirements of wireless applications1, carrier frequencies are shifting towards the millimetre-wave and terahertz bands2-5. Conversely, data is normally transported to remote wireless antennas by optical fibres. Therefore, full transparency and flexibility to switch between optical and wireless domains would be desirable6,7. Here, we demonstrate for the first time a direct wireless-to-optical receiver in a transparent optical link. We successfully transmit 20 and 10 Gbit/s over wireless distances of 1 and 5 m at a carrier frequency of 60 GHz, respectively. Key to the breakthrough was a plasmonic mixer directly mapping the wireless information onto optical signals. The plasmonic scheme with its subwavelength feature and pronounced field confinement provides a built-in field enhancement of up to 90'000 over the incident field in an ultra-compact and CMOS compatible structure. The plasmonic mixer is not limited by electronic speed and thus compatible with future terahertz technologies.

Correlation between electrical direct current resistivity and plasmonic properties of CMOS compatible titanium nitride thin films.

Damping distances of surface plasmon polariton modes sustained by different thin titanium nitride (TiN) films are measured at the telecom wavelength of 1.55 µm. The damping distances are correlated to the electrical direct current resistivity of the films sustaining the surface plasmon modes. It is found that TiN/Air surface plasmon mode damping distances drop non-linearly from 40 to 16µm as the resistivity of the layers increases from 28 to 130µΩ.cm, respectively. The relevance of the direct current (dc) electrical resistivity for the characterization of TiN plasmonic properties is investigated in the framework of the Drude model, on the basis of parameters extracted from spectroscopic ellipsometry experiments. By probing a parametric space of realistic values for parameters of the Drude model, we obtain a nearly univocal dependence of the surface plasmon damping distance on the dc resistivity demonstrating the relevance of dc resistivity for the evaluation of the plasmonic performances of TiN at telecom frequencies. Finally, we show that better plasmonic performances are obtained for TiN films featuring a low content of oxygen. For low oxygen content and corresponding low resistivity, we attribute the increase of the surface plasmon damping distances to a lower confinement of the plasmon field into the metal and not to a decrease of the absorption of TiN.

Characterization of CMOS metal based dielectric loaded surface plasmon waveguides at telecom wavelengths.

Dielectric loaded surface plasmon waveguides (DLSPPWs) comprised of polymer ridges deposited on top of CMOS compatible metal thin films are investigated at telecom wavelengths. We perform a direct comparison of the properties of copper (Cu), aluminum (Al), titanium nitride (TiN) and gold (Au) based waveguides by implementing the same plasmonic waveguiding configuration for each metal. The DLSPPWs are characterized by leakage radiation microscopy and a fiber-to-fiber configuration mimicking the cut-back method. We introduce the ohmic loss rate (OLR) to analyze quantitatively the properties of the CMOS metal based DLSPPWs relative to the corresponding Au based waveguides. We show that the Cu, Al and TiN based waveguides feature extra ohmic loss compared to Au of 0.027 dB/µm, 0.18 dB/µm and 0.52 dB/µm at 1550nm respectively. The dielectric function of each metal extracted from ellipsometric spectroscopic measurements is used to model the properties of the DLSP-PWs. We find a fairly good agreement between experimental and modeled DLSPPWs properties except for Al featuring a large surface roughness. Finally, we conclude that TiN based waveguides sustaining intermediate effective index (in the range 1.05-1.25) plasmon modes propagate over very short distances restricting the the use of those modes in practical situations.

Plasmonic modulator with >170 GHz bandwidth demonstrated at 100 GBd NRZ.

We demonstrate a plasmonic Mach-Zehnder (MZ) modulator with a flat frequency response exceeding 170 GHz. The modulator comprises two phase modulators exploiting the Pockels effect of an organic electro-optic material in plasmonic slot waveguides. We further show modulation at 100 GBd NRZ and 60 GBd PAM-4. The electrical drive signals were generated using a 100 GSa/s digital to analog converter (DAC). The high-speed and small-scale devices are relevant for next-generation optical interconnects.

Plasmonic phased array feeder enabling ultra-fast beam steering at millimeter waves.

In this paper, we demonstrate an integrated microwave phoneeded for beamtonics phased array antenna feeder at 60 GHz with a record-low footprint. Our design is based on ultra-compact plasmonic phase modulators (active area <2.5µm2) that not only provide small size but also ultra-fast tuning speed. In our design, the integrated circuit footprint is in fact only limited by the contact pads of the electrodes and by the optical feeding waveguides. Using the high speed of the plasmonic modulators, we demonstrate beam steering with less than 1 ns reconfiguration time, i.e. the beam direction is reconfigured in-between 1 GBd transmitted symbols.

Integrated optical frequency shifter in silicon-organic hybrid (SOH) technology.

We demonstrate for the first time a waveguide-based frequency shifter on the silicon photonic platform using single-sideband modulation. The device is based on silicon-organic hybrid (SOH) electro-optic modulators, which combine conventional silicon-on-insulator waveguides with highly efficient electro-optic cladding materials. Using small-signal modulation, we demonstrate frequency shifts of up to 10 GHz. We further show large-signal modulation with optimized waveforms, enabling a conversion efficiency of -5.8 dB while suppressing spurious side-modes by more than 23 dB. In contrast to conventional acousto-optic frequency shifters, our devices lend themselves to large-scale integration on silicon substrates, while enabling frequency shifts that are several orders of magnitude larger than those demonstrated with all-silicon serrodyne devices.

Pre-equalization technique enabling 70 Gbit/s photonic-wireless link at 60 GHz.

In this paper, we demonstrate a 70 Gbit/s photonic-based wireless link at 60 GHz using a single RF carrier and a single polarization. This high capacity is achieved by using 32QAM modulation with a symbol rate of 14 GBd. We show a novel pre-equalization technique that enables usage of such very high bandwidths at 60 GHz. Our work indicates that the consumer oriented 60 GHz band could be a viable alternative to more expensive E-band or sub-THz links for high capacity photonic wireless transmission, mobile backhauling and last-mile high-capacity connections.

High speed plasmonic modulator array enabling dense optical interconnect solutions.

Plasmonic modulators might pave the way for a new generation of compact low-power high-speed optoelectronic devices. We introduce an extremely compact transmitter based on plasmonic Mach-Zehnder modulators offering a capacity of 4 × 36 Gbit/s on a footprint that is only limited by the size of the high-speed contact pads. The transmitter array is contacted through a multicore fiber with a channel spacing of 50 µm.

Plasmonic-organic hybrid (POH) modulators for OOK and BPSK signaling at 40 Gbit/s.

We report on high-speed plasmonic-organic hybrid Mach-Zehnder modulators comprising ultra-compact phase shifters with lengths as small as 19 µm. Choosing an optimum phase shifter length of 29 µm, we demonstrate 40 Gbit/s on-off keying (OOK) modulation with direct detection and a BER < 6 × 10(-4). Furthermore, we report on a 29 µm long binary-phase shift keying (BPSK) modulator and show that it operates error-free (BER < 1 × 10(-10)) at data rates up to 40 Gbit/s and with an energy consumption of 70 fJ/bit.

Amplification of advanced modulation formats with a semiconductor optical amplifier cascade.

The convergence of optical metro networks and access networks extends the area of network coverage, and therefore requires the use of optical amplifiers. For this purpose, semiconductor optical amplifiers (SOA) would be attractive, because they are broadband, can be centered between 1250 nm and 1600 nm, and because they are cheap in production and operation. We show that signals encoded with advanced modulation formats such as BPSK, QPSK, 8PSK, and 16QAM can be amplified by a cascade of at least four SOAs. This enables high-capacity paths with a capacity in the order of Tbit/s for converged metro-access networks.

Wireless control and selection of forces and torques--towards wireless engines.

Powering and manipulating translational and rotational motions of objects wirelessly, and controlling several objects independently is of significant importance in numerous fields such as robotics, medicine, biology, fluid dynamics, optics. We propose a method based on coupled LC resonators, to control objects selectively by steering the frequency of an external magnetic field. This concept does not need any magnetic materials and it brings a rich variety of features concerning forces and torques. We theoretically and experimentally show that the forces can be enhanced by the interaction of resonators and that both direction and magnitude of forces can be controlled by the frequency of the applied external magnetic field. Moreover, we demonstrate interesting rotational effects, such as bi-directionally controllable torques, controllable stable orientations, and spinning, which leads to a wirelessly powered motor.

Full flex-grid asynchronous multiplexing demonstrated with Nyquist pulse-shaping.

We demonstrate full flex-grid operation with Nyquist frequency division multiplexing. The technique supports high spectral efficiency, asynchronous operation of channels, variable channel loading with different modulation formats and dynamic bandwidth allocation. Data from different sources with different bit and symbol rates are encoded onto electrical Nyquist pulses with different electrical subcarrier frequencies, and then transmitted optically. We give details on the transceiver design with digital signal processing and investigate the implementation penalty as a function of several design parameters such as limited filter length and effective number of bits. Finally, experiments are performed for receivers with direct detection, intradyne and remote heterodyne reception.

Nanomagnonic devices based on the spin-transfer torque.

Magnonics is based on signal transmission and processing by spin waves (or their quanta, called magnons) propagating in a magnetic medium. In the same way as nanoplasmonics makes use of metallic nanostructures to confine and guide optical-frequency plasmon-polaritons, nanomagnonics uses nanoscale magnetic waveguides to control the propagation of spin waves. Recent advances in the physics of nanomagnetism, such as the discovery of spin-transfer torque, have created possibilities for nanomagnonics. In particular, it was recently demonstrated that nanocontact spin-torque devices can radiate spin waves, serving as local nanoscale sources of signals for magnonic applications. However, the integration of spin-torque sources with nanoscale magnetic waveguides, which is necessary for the implementation of integrated spin-torque magnonic circuits, has not been achieved to date. Here, we suggest and experimentally demonstrate a new approach to this integration, utilizing dipolar field-induced magnonic nanowaveguides. The waveguides exhibit good spectral matching with spin-torque nano-oscillators and enable efficient directional transmission of spin waves. Our results provide a practical route for the implementation of integrated magnonic circuits utilizing spin transfer.

Timing, carrier frequency and phase recovery for OFDM and Nyquist signals using a mean modulus algorithm.

Efficient algorithms for timing, carrier frequency and phase recovery of Nyquist and OFDM signals are introduced and experimentally verified. The algorithms exploit the statistical properties of the received signals to efficiently derive the optimum sampling time, the carrier frequency offset, and the carrier phase. Among the proposed methods, the mean modulus algorithm (MMA) shows a very robust performance at reduced computational complexity. This is especially important for optical communications where data rates can exceed 100 Gbit/s per wavelength. All proposed algorithms are verified by simulations and by experiments using optical M-ary QAM Nyquist and OFDM signals with data rates up to 84 Gbit/s.

Silicon-organic hybrid (SOH) frequency comb sources for terabit/s data transmission.

We demonstrate frequency comb sources based on silicon-organic hybrid (SOH) electro-optic modulators. Frequency combs with line spacings of 25 GHz and 40 GHz are generated, featuring flat-top spectra with less than 2 dB power variations over up to 7 lines. The combs are used for WDM data transmission at terabit/s data rates and distances of up to 300 km.

Real-time Nyquist signaling with dynamic precision and flexible non-integer oversampling.

We demonstrate two efficient processing techniques for Nyquist signals, namely computation of signals using dynamic precision as well as arbitrary rational oversampling factors. With these techniques along with massively parallel processing it becomes possible to generate and receive high data rate Nyquist signals with flexible symbol rates and bandwidths, a feature which is highly desirable for novel flexgrid networks. We achieved maximum bit rates of 252 Gbit/s in real-time.

Low-power silicon-organic hybrid (SOH) modulators for advanced modulation formats.

We demonstrate silicon-organic hybrid (SOH) electro-optic modulators that enable quadrature phase-shift keying (QPSK) and 16-state quadrature amplitude modulation (16QAM) with high signal quality and record-low energy consumption. SOH integration combines highly efficient electro-optic organic materials with conventional silicon-on-insulator (SOI) slot waveguides, and allows to overcome the intrinsic limitations of silicon as an optical integration platform. We demonstrate QPSK and 16QAM signaling at symbol rates of 28 GBd with peak-to-peak drive voltages of 0.6 V(pp). For the 16QAM experiment at 112 Gbit/s, we measure a bit-error ratio of 5.1 × 10⁻5 and a record-low energy consumption of only 19 fJ/bit.

Real-time OFDM or Nyquist pulse generation--which performs better with limited resources?

We investigate the performance and DSP resource requirements of digitally generated OFDM and sinc-shaped Nyquist pulses. The two multiplexing techniques are of interest as they offer highest spectral efficiency. The comparison aims at determining which technology performs better with limited processing capacities of state-of-the-art FPGAs. It is shown that a novel Nyquist pulse shaping technique, based on look-up tables requires lower resource count than equivalent IFFT-based OFDM signal generation while achieving similar performance with low inter-channel guard-bands in ultra-dense WDM. Our findings are based on a resource assessment of selected DSP implementations in terms of both simulations and experimental validations. The experiments were performed with real-time software-defined transmitters using a single or three optical carriers.

Efficient modulation cancellation using reflective SOAs.

Modulation cancellation and signal inversion are demonstrated within reflective semiconductor optical amplifiers. The effect is necessary to implement colorless optical network units for network end-users, where downstream signals need to be erased in order to reuse the carrier for upstream transmission. The results presented here indicate that reflective semiconductor optical amplifiers possess the perfect high-speed all-optical gain saturation characteristics to completely cancel the downstream modulation at microwatt optical power levels and are thus the prime candidate to be constituents of future optical network units. Theoretical considerations are supported by experiments that show the cancellation of signals with a 6 dB extinction ratio at 2.5 Gbit/s.