ABSTRACT
Stretchable electroluminescent devices represent an emerging optoelectronic technology for future wearables. However, their typical construction on sub-millimeter-thick elastomers has limited moisture permeability, leading to discomfort during long-term skin attachment. Although breathable textile displays may partially address this issue, they often have distinct visual appearances with discrete emissions from fibers or fiber junctions. This study introduces a convenient procedure to create stretchable, permeable displays with continuous luminous patterns. The design utilizes ultrathin nanocomposite devices embedded in a porous elastomeric microfoam to achieve high moisture permeability. These displays also exhibit excellent deformability, low-voltage operation, and excellent durability. Additionally, the device is decorated with fluorinated silica nanoparticles to achieve self-cleaning and washable capabilities. The practical implementation of these nanocomposite devices is demonstrated by creating an epidermal counter display that allows intimate integration with the human body. These developments provide an effective design of stretchable and breathable displays for comfortable wearing.
ABSTRACT
In the context of an aging population and escalating work pressures, cardiovascular diseases pose increasing health risks. Electrocardiogram (ECG) monitoring presents a preventive tool, but conventional devices often compromise comfort. This study proposes an approach using Ag NW/TPU composites for flexible and breathable epidermal electronics. In this new structure, TPU fibers are used to support Ag NWs/TPU nanocomposites. The TPU fiber-reinforced Ag NW/TPU (TFRAT) nanocomposites exhibit excellent conductivity, stretchability, and electromechanical durability. The composite ensures high steam permeability, maintaining stable electrical performance after washing cycles. Employing this technology, a flexible ECG detection system is developed, augmented with a convolutional neural network (CNN) for automated signal analysis. The experimental results demonstrate the system's reliability in capturing physiological signals. Additionally, a CNN model trained on ECG data achieves over 99% accuracy in diagnosing arrhythmias. This study presents TFRAT as a promising solution for wearable electronics, offering both comfort and functionality in long-term epidermal applications, with implications for healthcare and beyond.
ABSTRACT
Stretchable electronics has emerged as a new class of electronic technology to expand the applications of conventional electronics built on rigid wafers. Among various systems, liquid-state devices utilize electronically active liquids to achieve excellent stretchability and durability. The widespread adaption to such attractive form of device is hindered by the lack of robust fabrication approach to precisely and efficiently assemble liquid-state materials into functional systems. In this study, an additive manufacturing platform for digital fabrication of three-dimensional elastomeric structures is reported. The shear-thinning ink is formulated to enable omnidirectional printing process. Various elastic features with complex architectures are generated without using sacrificial materials, which consist of overhanging parts, suspended structures, and embedded channels. Harnessing the unique printability allows facile creation of elastomeric sensors with strain- and pressure-sensing capabilities by simply filling the embedded microchannels with liquid metal. A smart glove to capture hand gestures is also demonstrated as a fully integrated electronic system with liquid-state components. The liquid-state stretchable electronics developed here may find potential applications in biomedical instruments, wearable devices, and soft robotics.
ABSTRACT
The extractive separation of tellurium (IV) from hydrochloric acid media with tri-n-butyl phosphate (TBP) in kerosene was investigated. The dependence on the extraction of tellurium species, concentrations of tellurium and TBP, extraction time and stage, organic/aqueous ratio, and interferences from coexist metallic ions were examined and are discussed. Besides, the stripping agent and stripping time were also studied. It was found that the extraction reaction corresponds to the neutral complex formation mechanism and the extracted species is TeCl4 · 3TBP and that the extraction process is exothermic. The thermodynamic parameters of enthalpy (ΔH), entropy (ΔS), and free energy (ΔG) of the extraction process were evaluated at -26.2 kJ · mol(-1), -65.6 J · mol(-1) · K(-1), and -7.0 kJ · mol(-1), respectively at 293 K.
