ABSTRACT
In the title compound, C(7)H(6)ClN(3), the benzotriazole ring is essentially planar with a maximum deviation of 0.0110â (15)Å, and makes a dihedral angle of 0.46â (8)° with the benzene ring. In the crystal, mol-ecules are linked through inter-molecular C-Hâ¯N hydrogen bonds, forming chains along the c axis.
ABSTRACT
In the title complex, [ZnI(2)(C(14)H(19)BrN(2)O)], the Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand and by two iodide ions in a distorted tetra-hedral coordination. In the crystal structure, mol-ecules are linked through inter-molecular N-Hâ¯O hydrogen bonds, forming chains running along the b axis.
ABSTRACT
In the title complex, [Zn(C(12)H(18)N(2)O)I(2)], the Zn(II) ion is four-coordinated by the imine N and amine N atoms of the Schiff base ligand and by two iodide ions in a distorted tetra-hedral coordination.
ABSTRACT
In the title complex, [ZnI(2)(C(14)H(21)BrN(2)O)]·CH(3)OH, the asymmetric unit consists of a mononuclear zinc(II) complex mol-ecule and a methanol solvent mol-ecule. The compound was derived from the zwitterionic form of the Schiff base 4-bromo-2-[3-(diethyl-amino)propyl-imino-meth-yl]phenol. The Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand and by two iodide ions in a distorted tetra-hedral coordination. In the crystal structure, the methanol mol-ecules are linked to the Schiff base mol-ecules through N-Hâ¯O and O-Hâ¯O hydrogen bonds. One I atom is disordered over two positions in a 0.702â (19):0.298â (19) ratio.
ABSTRACT
In the title complex, [ZnI(2)(C(14)H(19)N(3)O(3))], the Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand, and by two iodide ions in a distorted tetra-hedral coordination. In the crystal structure, mol-ecules are linked through inter-molecular N-Hâ¯O hydrogen bonds, forming dimers.
ABSTRACT
The binuclear title complex, [Hg(2)(C(10)H(14)N(2)O(8))(2)(C(18)H(18)N(4))]·2CH(3)OH, lies on an inversion center with the unique Hg(II) ion coordinated in a disorted octa-hedral environment with one Hg-N bond significantly shorter than the other two. In the crystal structure, inter-molecular O-Hâ¯O hydrogen bonds link complex and solvent mol-ecules into a three-dimensional network.