1.
Nanoscale
; 10(40): 18915-18919, 2018 Oct 18.
Article
in English
| MEDLINE
| ID: mdl-30285022
ABSTRACT
The tert-butylethynide ligand has been employed to construct an atomically precise all-tert-butylethynide-protected silver superatom nanocluster, Ag51(tBuC[triple bond, length as m-dash]C)32 (hereafter denoted as Ag51). The identity of Ag51 is confirmed by high resolution ESI-MS and elemental analysis. Single crystal X-ray analysis revealed that the structure of Ag51 features a three-shell arrangement, Ag@Ag8/Ag6@Ag36@C24/C8. Ag51 exhibits a strong solvatochromic effect, and the emissions are strongly dependent on the solvent polarity and are tunable from blue to red by changing the solvent from less polar dichloromethane to highly polar methanol.