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1.
Angew Chem Int Ed Engl ; 61(22): e202201590, 2022 May 23.
Article in English | MEDLINE | ID: mdl-35289052

ABSTRACT

Achieving white-light emission, especially white circularly polarized luminescence (CPL) from a single-phase material is challenging. Herein, a pair of chiral CuI coordination polymers (1-M and 1-P) have been prepared by the asymmetrical assembly of achiral ligands and Cu2 I2 clusters. The compounds display dual emission bands and can be used as single-phase white-light phosphors, achieving a "warm"-white-light-emitting diode with an ultra-high color rendering index (CRI) of 93.4 and an appropriate correlated color temperature (CCT) of 3632 K. Meanwhile, corresponding CPL signals with maximum dissymmetry factor |glum |=8×10-3 have been observed. Hence, intrinsic white-light emission and CPL have been realized simultaneously in coordination polymers for the first time. This work gains insight into the nature of chiral assembly from achiral units and offers a prospect for the development of single-phase white-CPL materials.

2.
Opt Lett ; 42(19): 3952-3955, 2017 Oct 01.
Article in English | MEDLINE | ID: mdl-28957169

ABSTRACT

We investigate the nonlinear Ramsey interferometry of a bosonic Josephson junction coupled to an optical cavity by applying two identical pumping field pulses separated by a holding field in the time domain. When the holding field is absent, we show that the atomic Ramsey fringes are sensitive to both the cavity-pump detuning and the initial state, and their periods can encode the information on both the atom-field coupling and the atom-atom interaction. For a weak holding field, we find that the fringes characterized by the oscillation of the intra-cavity photon number can completely reflect the frequency information of the atomic interference due to the weak atom-cavity coupling. This finding allows a nondestructive observation of the atomic Ramsey fringes via the cavity transmission spectra.

3.
Phys Rev E ; 93(3): 032215, 2016 Mar.
Article in English | MEDLINE | ID: mdl-27078352

ABSTRACT

We study rational solutions of continuous wave backgrounds with the critical frequencies of the Sasa-Satsuma equation, which can be used to describe the evolution of the optical field in a nonlinear fiber with some high-order effects. We find a striking dynamical process that two W-shaped solitons are generated from a weak modulation signal on the continuous wave backgrounds. This provides a possible way to obtain stable high-intensity pulses from a low-intensity continuous wave background. The process involves both modulational instability and modulational stability regimes, in contrast to the rogue waves and W-shaped solitons reported before which involve modulational instability and stability, respectively. Furthermore, we present a phase diagram on a modulational instability spectrum plane for the fundamental nonlinear localized waves obtained already in the Sasa-Satsuma equation. The interactions between different types of nonlinear localized waves are discussed based on the phase diagram.

4.
Article in English | MEDLINE | ID: mdl-26764672

ABSTRACT

We numerically demonstrate the dynamic stabilization of a strongly interacting many-body bosonic system which can be realized by coupled ultracold atom-molecule gases. The system is initialized to an unstable equilibrium state corresponding to a saddle point in the classical phase space, where subsequent free evolution gives rise to atom-molecule conversion. To control and stabilize the system, periodic modulation is applied that suddenly shifts the relative phase between the atomic and the molecular modes and limits their further interconversion. The stability diagram for the range of modulation amplitudes and periods that stabilize the dynamics is given. The validity of the phase diagram obtained from the time-average calculation is discussed by using the orbit tracking method, and the difference in contrast with the maximum absolute deviation analysis is shown as well. A brief quantum analysis shows that quantum fluctuations can put serious limitations on the applicability of the mean-field results.

5.
Article in English | MEDLINE | ID: mdl-25353598

ABSTRACT

We investigate the solution in rational form for the Sasa-Satsuma equation on a continuous background which describes a nonlinear fiber system with higher-order effects including the third-order dispersion, Kerr dispersion, and stimulated inelastic scattering. The W-shaped soliton in the system is obtained analytically. It is found that the height of hump for the soliton increases with decreasing the background frequency in certain parameter regime. The maximum height of the soliton can be three times the background's height and the corresponding profile is identical with the one for the well-known eye-shaped rogue wave with maximum peak. The numerical simulations indicate that the W-shaped soliton is stable with small perturbations. Particularly, we show that the W-shaped soliton corresponds to a stable supercontinuum pulse by performing exact spectrum analysis.

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