ABSTRACT
Easy access to clean water is essential to functioning and development of modern society. However, it remains arduous to develop energy-efficient, facile, and portable water treatment systems for point-of-use (POU) applications, which is particularly imperative for the safety and resilience of society during extreme weather and critical situations. Here, we propose and validate a meritorious working scheme for water disinfection via directly capturing and removing pathogen cells from bulk water using strategically designed three-dimensional (3D) porous dendritic graphite foams (PDGFs) in a high-frequency AC field. The prototype, integrated in a 3D-printed portable water-purification module, can reproducibly remove 99.997% E. coli bacteria in bulk water at a few voltages with among the lowest energy consumption at 435.5 J·L-1. The PDGFs, costing $1.47 per piece, can robustly operate at least 20 times for more than 8 h in total without functional degradation. Furthermore, we successfully unravel the involved disinfection mechanism with one-dimensional Brownian dynamics simulation. The system is practically applied that brings natural water in Waller Creek at UT Austin to the safe drinking level. This research, including the working mechanism based on dendritically porous graphite and the design scheme, could inspire a future device paradigm for POU water treatment.
Subject(s)
Graphite , Water Purification , Disinfection/methods , Escherichia coli , Porosity , Water Purification/methodsABSTRACT
Solar steaming has emerged as a promising green technology that can address the global issue of scarcity of clean water. However, developing high-performance, cost-effective, and manufacturable solar-steaming materials, and portable solar steaming-collection systems for individuals remains a great challenge. Here, a one-step, low-cost, and mass-producible synthesis of polypyrrole (PPy) origami-based photothermal materials, and an original portable low-pressure controlled solar steaming-collection unisystem, offering synergetic high rates in both water evaporation and steam collection, are reported. Due to enhanced areas for vapor dissipation, the PPy origami improves the water evaporation rate by at least 71% to 2.12 kg m-2 h-1 from that of a planar structure and exhibits a solar-thermal energy conversion efficiency of 91.5% under 1 Sun. When further controlling the pressure to ≈0.17 atm in the steaming-collection unisystem, the water collection rate improves by up to 52% systematically and dramatically. Although partial energy is utilized toward obtaining low-pressure, evaluations show that the overall energy efficiency is improved remarkably in the low-pressure system compared to that in ambient pressure. Furthermore, the device demonstrates effective decontamination of heavy metals, bacteria, and desalination. This work can inspire new paradigms toward developing high-performance solar steaming technologies for individuals and households.
ABSTRACT
Nanostructured forms of crystalline silicon represent an attractive materials building block for photovoltaics due to their potential benefits to significantly reduce the consumption of active materials, relax the requirement of materials purity for high performance, and hence achieve greatly improved levelized cost of energy. Despite successful demonstrations for their concepts over the past decade, however, the practical application of nanostructured silicon solar cells for large-scale implementation has been hampered by many existing challenges associated with the consumption of the entire wafer or expensive source materials, difficulties to precisely control materials properties and doping characteristics, or restrictions on substrate materials and scalability. Here we present a highly integrable materials platform of nanostructured silicon solar cells that can overcome these limitations. Ultrathin silicon solar microcells integrated with engineered photonic nanostructures are fabricated directly from wafer-based source materials in configurations that can lower the materials cost and can be compatible with deterministic assembly procedures to allow programmable, large-scale distribution, unlimited choices of module substrates, as well as lightweight, mechanically compliant constructions. Systematic studies on optical and electrical properties, photovoltaic performance in experiments, as well as numerical modeling elucidate important design rules for nanoscale photon management with ultrathin, nanostructured silicon solar cells and their interconnected, mechanically flexible modules, where we demonstrate 12.4% solar-to-electric energy conversion efficiency for printed ultrathin (â¼ 8 µm) nanostructured silicon solar cells when configured with near-optimal designs of rear-surface nanoposts, antireflection coating, and back-surface reflector.
ABSTRACT
Iron sulfide compounds are emerging as an important family of functional materials owing to their important properties and their applications in different technical fields. Well-defined Fe7 S8 nanowires templated by thermal decomposition of [Fe16 S20 ]/diethylenetriamine hybrid nanowires under an argon atmosphere are reported. As-prepared Fe7 S8 nanowires show typical Michaelis-Menten kinetics and good affinity to both H2 O2 and 3,3',5,5'-tetramethylbenzidine. At pHâ 7.0, the constructed UV/Vis sensor showed a linear range for the detection of H2 O2 from 0.5 to 150â µM with a correlation coefficient of 0.9998. The H2 O2 sensor based on the Fe7 S8 nanowires shows a highly sensitive response and has better stability than horseradish peroxidase when exposed to solutions with different pH values and temperatures. These excellent properties make the as-prepared Fe7 S8 nanowires powerful tools for potential applications as an "artificial peroxidase" in biosensors and biotechnology.