ABSTRACT
Triplet exciton is both a luminescence quenching factor and an important luminescence sensitization technology solution, which is widely concerned in the field of optoelectronic materials. Since X-ray excited triplet excitons are dissipated through various pathways, there are still huge difficulties in achieving efficient triplet sensitized emission. Here, the antenna ligand is regulated through the carboxyl group, increasing the steric hindrance between the conjugated groups and improving triplet-enhanced radioluminescence (RL) efficiencies of Tb3+. The lanthanide metal-organic frameworks (Ln-MOFs) formed by the coordination of Tb3+ with mellitic acid (MA), pyromellitic acid (PMA) and trimesic acid (TMA) under low temperature preparation conditions. Among them, MA-Tb has a longer spacing between conjugated groups than PMA-Tb and TMA-Tb, and its triplet RL is relatively strongest, with a light yield of 28,000 photons MeV-1. Mechanistic studies revealed that the RL efficiency of Ln-MOFs is related to the π-π stacking effect in the benzene ring. In addition, the application of MA-Tb in the field of X-ray detection was demonstrated. The RL intensity of MA-Tb has a good linear relationship with the X-ray dose rate, and the detection limit for X-ray reaches 82 nGy/s, which is 66 times lower than the typical medical imaging dose. These results will provide a universal strategy for the design of Ln-MOFs scintillator.
ABSTRACT
As the demand for the development and utilization of marine resources continues to strengthen, the service requirements for advanced marine equipment are rapidly increasing. Surface protection technology has become an important way of solving the tribological problems of extreme operating conditions and improving the safety performance of equipment by imparting certain special properties to the surface of the material through physical, chemical or mechanical processes to enhance the ability of the material to withstand external environmental factors. Combined with the extremely complex characteristics of the marine environment, this paper describes the commonly used surface protection technologies for metal materials in the marine environment. Research on surface texture was summarized under different surface reshaping technologies, as well as processes and coating materials under different surface modification technologies. Combined with the existing research progress and development trends of marine metallic materials, the surfaces of metal materials under the marine environment protection technology foreground are prospected and provide a reference for the improvement of equipment performance in extreme marine environments.
ABSTRACT
Pressurized electro-dewatering technology is considered to be one of the most effective methods for improving dewatering performance of sewage sludge. In this paper, four dewatering protocols were developed to further explore the coupling mechanism of sludge dewatering through mechanical pressure, electric field and their joint. The results showed that the dewatering performance of the four dewatering protocols were as follows: pressurized electro-dewatering with constant voltage gradient mode (G-PEDW) > first mechanical dewatering then electro-dewatering > mechanical dewatering > electro-dewatering. The coupling mechanism was revealed from the perspectives of pore structure and moisture distribution of sludge cakes. The pore structure was discussed in detail from the whole pore size distribution and fractal dimension. The fractal dimension could quantitatively describe the change of pore structure. The moisture distribution was analyzed by the thermogravimetric differential scanning calorimetry test. The results showed that the electric field could reduce bound strength of moisture and produce new micro-pores to build more water flow paths, the water was discharged through interior capillary channels, and mechanical pressure could accelerate the water removing process. Response surface method was used to establish an empirical prediction model of G-PEDW, and discussed the selection of optimal parameters. The R-square values of mathematical models of moisture content and energy consumption were as high as 0.9863 and 0.9838, respectively, which was more advanced than other mathematical models. Experiments showed that G-PEDW could reduce the time to 20 min or reduce the energy consumption to 7.1 Wh/kgâ¢H2O when the target moisture content was set to 41.7%.
