[Phosphorus Adsorption Characteristics of Different Biochar Types and Its Influencing Factors].

In order to understand the resource utilization of plant biomass, five types of biomass materials were used to produce biochar to treat wastewater containing phosphorus. The phosphorus adsorption capacity of five materials was preliminarily compared through laboratory experiments, and two materials with strong phosphorus adsorption capacity were screened out. The physicochemical characteristics of the selected biochar were analyzed using scanning electron microscopy and a BET specific surface area analyzer, and the effects of different pH values on phosphorus adsorption of the biochar were investigated. Furthermore, the phosphorus adsorption characteristics of the selected biochar were analyzed via isothermal adsorption and adsorption kinetics models. The results showed that among the five biochar materials, only rice straw and corn straw biochar had the ability to adsorb phosphorus. The Langmuir isothermal adsorption curve showed that the adsorption capacity of rice straw biochar for phosphorus in wastewater was stronger than that of corn straw biochar, and the theoretical maximum adsorption capacity was as follows:rice straw biochar (9.78 mg·g-1)>corn straw biochar (0.39 mg·g-1). The specific surface area (148.30 m2·g-1) and total pore volume (0.11 cm3·g-1) of rice straw biochar were much higher than those of corn straw biochar (8.26 m2·g-1 and 0.03 cm3·g-1, respectively), and the contents of Mg, Ca, Fe, and Al were higher in rice straw biochar. The best pH for phosphorus adsorption of rice straw biochar and corn straw biochar was acidic. In different pH ranges (3.0-11.0), the phosphorus adsorption capacity of rice straw and corn straw biochar decreased with the increase in pH. These results indicated that rice straw biochar has strong phosphorus adsorption capacity and has a better application prospect in wastewater treatment.

Effects of water level on nitrous oxide emissions from vegetated ditches.

Nitrous oxide (N2O) is considered a powerful greenhouse gas. Vegetated ditches are an important source of N2O emissions in the agricultural systems. However, few studies have examined on the relationship between N2O emissions and the water level in vegetated ditches. To investigate the effect of water level on the N2O emissions, three pilot-scale ditches vegetated with Myriophyllum aquaticum were constructed with low (LW), medium (MW), and high (HW) water levels. The examined results indicated that the M. aquaticum ditches decreased N2O emissions by 38.4% and 67.9% in MW and HW, respectively, as compared to the LW ditch. In addition, the N2O emission factor decreased with increasing water level in the order of: LW (0.18%) > MW (0.11%) > HW (0.06%). The MW and HW ditches reduced the N2O emissions by controlling the sediment nitrogen contents, in which the ammonia nitrogen increased with increasing the level of water, while nitrate nitrogen decreased with increasing the level of water. The increase in the level of water significantly reduced the gene abundance of ammonia-oxidizing archaea (AOA) (p < 0.05), thereby reducing the N2O emissions in the MW and HW conditions due to the positive correlation between N2O emissions and AOA gene abundances. The unclassified_k_norank_d_Bacteria was the dominant denitrifying bacterial genus observed in the M. aquaticum ditches, and its highly relative abundance yielded low N2O emissions in the HW ditch. These findings indicate that reducing N2O emissions may be achieved by controlling the water level in vegetated ditches.