ABSTRACT
A pure organic molecule 2,6-di(phenothiazinyl)naphthalene (DPTZN) with room-temperature phosphorescence (RTP) features was developed. Remarkably, a triazine-benzimidazole-based molecule TRZ-BIM can significantly improve the RTP efficiency of DPTZN in DPTZN:TRZ-BIM blend films. The photoluminescence quantum yield (PLQY) of 10 wt % DPTZN:TRZ-BIM blend film is 38%. The RTP property of DPTZN:TRZ-BIM blend films was characterized by steady, time-resolved, and temperature-dependent emission spectra. An organic light-emitting diode (OLED) with 10 wt % DPTZN:TRZ-BIM blend film as the emitting layer showed a high maximum external quantum efficiency of 11.5%, current efficiency of 33.8 cd A-1, and power efficiency of 32.6 lm W-1. Herein, we have developed an efficient approach to achieve precious-metal-free organic films that can be employed to fabricate high-performance phosphorescence OLEDs.
ABSTRACT
The design and synthesis of blue thermally activated delayed fluorescence (TADF) emitters that have high electroluminescence efficiency and low efficiency roll-off features remain a great challenge. Herein, we developed a facile and efficient strategy by shielding acceptors with carbazole units for constructing high-performance blue TADF emitters. Benzonitrile (BN), 9,9-diphenylacridan (DPAc), and carbazole (Cz) were adopted as the acceptor, donor, and protector, respectively, to build two TADF emitters named DPAc-DCzBN and DPAc-DtCzBN. The nondoped organic light-emitting diodes (OLEDs) of DPAc-DCzBN as the emitter exhibited a standard sky-blue emission with Commission Internationale de L'Eclairage (CIE) coordinates of (0.16, 0.26), high external quantum efficiency (EQE) of 20.0%, and low efficiency roll-off (EQEs of 19.5, 16.1, and 12.6% at 100, 500, and 1000 cd m-2, respectively), which is an outstanding nondoped blue TADF OLED. The doped device of DPAc-DtCzBN displayed a pure blue emission and the corresponding CIE coordinates are (0.16, 0.15). Meanwhile, it also demonstrated high and stabilized EQE values of 23.1, 18.3, and 11.5% at maxima, 100 and 500 cd m-2, respectively, which is a quite high level among the pure blue TADF OLEDs. This study testifies the feasibility of our strategy in constructing high-performance TADF electroluminescent materials.
