ABSTRACT
Glass has been obtained by melting red mud from Shandong Province in China with different additives. Suitable thermal treatments were employed to convert the obtained glass into nano-crystal glass-ceramics. X-ray diffraction (XRD) patterns showed that the main crystalline phase in both the glass-ceramics is wollastonite (CaSiO3). These crystals are homogeneously dispersed within the parent glass, with an average crystal size of less than 100 nm. The size of nano-crystals varies when different thermal processes were used. Physical and mechanical properties, such as density, thermal expansion coefficient, hardness, and bending strength, of the two glasses have been examined and the corresponding microstructures are discussed. These results demonstrate that both glass-ceramics have potential for a wide range of construction application.
Subject(s)
Aluminum , Ceramics , Conservation of Natural Resources , Industrial Waste , Calcium Compounds , China , Crystallization , Glass , Hot Temperature , Nanotechnology , Silicates , X-Ray DiffractionABSTRACT
The breakthrough of low concentration methyethylketone (MEK) and benzene vapors in beds packed with rayon-based activated carbon fiber (ACF) with different surface areas was investigated. The breakthrough characteristics depend on the properties of the ACF and the vapors, as well as on the adsorption conditions. The results of dynamic adsorption in an ACF bed were consistent with those of equilibrium adsorption by gravimetric methods. The breakthrough adsorption indicates that ACF, with an appropriate surface area, could be utilized in controlling volatile organic compounds (VOCs) in indoor air.
Subject(s)
Air Pollution, Indoor/prevention & control , Carbon , Adsorption , Benzene , Butanones , Humidity , TemperatureABSTRACT
Silica xerogels were prepared by thermal drying wet gels in an electric oven (70 degrees C) after certain duration of ambient drying, and the relevant effect is investigated on the mesopore structures and surface fractal dimensions of the resultant xerogels. The silica gels were derived from a hydrochloric acid-catalyzed TEOS (tetraethylorthaosilicate) system, and both magnetic stirring and ultrasonic vibration were adopted during sol preparation. The percentage mesoporosity and surface fractal dimensions are evaluated using image analysis methods, based on FE-SEM (field emission gun-scanning electron microscopy) images. The results show that the mesoporosity of the resultant xerogels decreases with the duration of ambient drying for samples prepared using magnetic stirring and low-intensity ultrasonic vibration, while samples subjected to high-intensity ultrasound show a somewhat reverse trend. Samples prepared with magnetic stirring have almost constant surface fractal dimensions (nearly 3), irrespective of the ambient drying before thermal drying. The surface fractal dimensions of samples prepared using ultrasound increase with the duration of ambient drying.
ABSTRACT
The pore microstructures in two viscouse rayon-based ACF samples were characterized by nitrogen adsorption and HRTEM. For TEM, a two-dimensional fast Fourier transform (FFT) of the original TEM images was performed, and pores in different size ranges were extracted by the inverse FFT (IFFT) operation. The surface fractal dimensions of the samples were evaluated by using both N(2) adsorption and TEM image analysis. The results show that TEM can portray the shapes of the pore, and it can give a quantitative evaluation of surface irregularity that is consistent with nitrogen adsorption results.