ABSTRACT
Smart voltage-gated nanofiltration membranes have enormous potential for on-demand and precise separation of similar molecules, which is an essential element of sustainable water purification and resource recovery. However, the existing voltage-gated membranes are hampered by limited selectivity, stability, and scalability due to electroactive monomer dimerization. Here, for the first time, the host-guest recognition properties of cucurbit[7]uril (CB[7]) are used to protect the viologen derivatives and promote their assembly into the membrane by interfacial polymerization. Viologen functions as a voltage switch, whereas CB[7] complexation prevents its dimerization and improves its redox stability. The inhibited diffusion of the CB[7]-viologen complex enables the precise patterning of the surface structure. The resultant voltage-gated membrane displays 80% improved rejection performance, excellent recovery accuracy for similar molecules, and anti-fouling properties. This work not only provides an innovative strategy for the preparation of voltage-gated smart nanofiltration membranes but also opens up new avenues for ion-selective transmission in water treatment, bionic ion channels, and energy conversion.
Subject(s)
Bridged-Ring Compounds , Imidazoles , Bridged-Ring Compounds/chemistry , Dimerization , Imidazoles/chemistry , ViologensABSTRACT
Interesting molecular architectures were obtained by combining heterodimeric quadruple hydrogen-bonding and neutral metal corner braces. The selection of cyclic and noncyclic aggregates from a random mixture of two-component assemblies has been achieved through metal coordination and careful adjustment of monomer rigidity and dimensions.
