Plasmonic coupling in gold nanoring dimers: observation of coupled bonding mode.

We investigate the optical properties of gold nanoring (NR) dimers in both simulation and experiment. The resonance peak wavelength of gold NR dimers is strongly dependent on the polarization direction and gap distance. As the gold NR particles approach each other, exponential red shift and slight blue shift of coupled bonding (CB) mode in gold NR dimers for longitudinal and transverse polarizations are obtained. In finite element method analysis, a very strong surface plasmon coupling in the gap region of gold NR dimers is observed, whose field intensity at the gap distance of 10 nm is enhanced 23% compared to that for gold nanodisk (ND) dimers with the same diameter. In addition, plasmonic dimer system exhibits a great improvement in the sensing performance. Near-field coupling in gold NR dimers causes exponential increase in sensitivity to refractive index of surrounding medium with decreasing the gap distance. Compared with coupled dipole mode in gold ND dimers, CB mode in gold NR dimers shows higher index sensitivity. This better index sensing performance is resulted form the additional electric field in inside region of NR and the larger field enhancement in the gap region owing to the stronger coupling of collective dipole plasmon resonances for CB mode. These results pave the way to design plasmonic nanostructures for practical applications that require coupled metallic nanoparticles with enhanced electric fields.

High sensitivity plasmonic index sensor using slablike gold nanoring arrays.

We investigate the index sensing characteristics of plasmonic arrays based on square lattice slablike gold nanorings (NRs) with different ring widths. The gold NR arrays exhibit two extinction peaks in the visible and near-infrared corresponding to antibonding and bonding modes. Redshift and blueshift in antibonding and bonding modes when broadening the average ring width are observed. We experimentally demonstrate the sensitivity of bonding mode can be tuned by varying the average ring width. High sensitivity of 691 nm per refractive index unit is obtained for NRs with 199 nm average ring width.