ABSTRACT
It is an urgent need to develop a new catalyst with high efficiency and low cost. In the present study, we successfully prepared bimetallic-supported denitration catalysts using the blast furnace slag as the main material and calcium bentonite as the binder. The as-prepared catalyst was characterized via X-ray diffraction analysis (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Besides, the mechanism of denitration was further determined with the help of the denitration and sulfur resistance of the catalyst. The results indicated that when the Mn load was 5%, and the second metal reactive component was loaded at 3%, Mn-Cu/GGBS (catalyst prepared by loading Mn and Cu on the blast furnace slag) had the best effects on low temperature denitration. Moreover, the conversion rate of NO was up to 97%, and it possessed the capability of specific sulfur resistance; when the third metal reactive component, Ce, was introduced with 1% load, the sulfur resistance of the Mn-Cu-Ce/GGBS (catalyst prepared by loading Mn, Cu, and Ce on the blast furnace slag) catalyst was further improved compared with that of the Mn-Cu/GGBS catalyst.
ABSTRACT
Nitrogen oxides (NOx) are the main pollutants of air, which mainly come from the combustion of coal and fossil fuels. In this paper, with fly ash used as the catalyst carrier, the effects on the denitration and sulfur resistance of Mn-Ce loading sequence and molar ratio were studied. The catalyst was characterized and analyzed by XRD, XPS, SEM. The results show that when Mn-Ce bimetal is loaded at the same time, Mn ions enter the CeO2 lattice to form a solid solution of Mn-O-Ce fluorite structure, which makes the catalyst has the best denitration and sulfur resistance. The catalyst denitration performance increases first and then decreases with the increase of Mn-Ce molar ratio. When Mn-Ce is 1:1, the denitration efficiency is higher, the total conversion rate of NO is the highest and the deactivation time is the longest, the catalyst is resistant to sulfur performance is also the best.
Subject(s)
Coal Ash , Nitrogen Oxides , Catalysis , Oxidation-Reduction , SulfurABSTRACT
The development of high-efficiency and low-cost new catalysts is an extremely attractive topic. In this study, two different matrix bentonite-modified fly ash catalysts were successfully prepared, and the compressive strength of the catalyst was studied by using unsaturated dynamic and static triaxial technology. The axial compressive strength of FC (fly ash catalysts added with Ca-based bentonite) was greater than that of FN (fly ash catalysts added with Na-based bentonite). The catalyst reached 978 kPa. The prepared catalyst was characterized by X-ray diffraction analysis, Fourier transform infrared spectroscopy, scanning electron microscopy, and specific surface area analysis (BET) of the catalyst. In addition, denitration performance of different catalysts was explored, and the reaction conditions were optimized. The results demonstrate that when the mixing ratio of fly ash and calcium-based bentonite in the FC is 4:1, the compressive strength is relatively high, and the denitration rate reaches about 82%.
