An irreversible temperature indicator fabricated by citrate induced face-to-face assembly of silver triangular nanoplates.

Assembly of anisotropic nanoparticles which need well controlling of assembly direction and spatial arrangement is more interesting than one-dimensional nanoparticles assemblies. As confirmed by observing of transmission electron microscopy images and analysis of plasmon resonance spectrum transformations, we found that silver triangular nanoplates (TNPs) without further modification could be face-to-face assembled by citrate. The face-to-face assembly of silver TNPs could be disassembled quickly by heating at a wide temperature range from 30 to 80 °C. In this process, an obvious localized surface plasmon resonance (LSPR) peak shift and a color change of solution from pink to purple could be observed. Moreover, the disassembled silver TNPs suspension is very stable that no significant peak shift of silver TNPs spectrum was observed in 8 h after removing of silver TNPs from a hearing area. Therefore, we fabricated an irreversible temperature indicator by measuring the relationship between the shift of LSPR peak and heating temperature, and by watching the color change of the solution in a certain environment. The irreversible temperature indicator has potential to develop a temperature label for revealing temperature history of a thermosensitive product which cannot expose to excessive temperature.

Selective fluorescence quenching of papain-Au nanoclusters by self-polymerization of dopamine.

In this paper, we synthesized a papain-stabilized fluorescent Au nanocluster (NC) probe and studied its interaction with dopamine. As fluorescence of papain-Au NCs is quenched in the presence of dopamine under alkaline conditions, we were able to establish a simple, selective analytical method for dopamine determination. By studying the fluorescence lifetime and dynamic light scattering of the NCs before and after interaction with dopamine, we found that this fluorescence quenching mechanism was possibly due to dopamine self-polymerization that produced polydopamine that cross-linked papain-Au NCs. Based on this new phenomenon, we proposed a highly selective analytical method for dopamine detection. Other small organic molecules, such as amino acids, ascorbic acid and uric acid did not interfere with dopamine detection. Dopamine in the range 20-100 µM can be linearly detected by the fluorescence quenching ratio of gold nanoclusters. Dopamine detection could be visually realized by watching color changes of papain-Au NCs under UV light or daylight, as both fluorescence and absorption of the papain-Au NCs changed during dopamine polymerization.

[Fluorescence Resonance Energy Transfer Detection of Cobalt Ions by Silver Triangular Nanoplates and Rhodamine 6G].

In the present paper, the authors studied fluorescence resonance energy transfer (FRET) phenomenon between silver triangular nanoplates and bovine serum albumin (BSA)/Rhodamine 6G fluorescence complex, and established a fluorescence method for the detection of cobalt ions. We found that when increasing the silver triangular nanoplates added to certain concentrations of fluorescent bovine serum albumin (BSA)/Rhodamine 6G complex, the fluorescence of Rhodamine 6G would be quenched up to 80% due to the FRET between the quencher and donor. However, in the presence of cobalt ions, the disassociation of the fluorescent complex from silver triangular nanoplates occurred and the fluorescence of the Rhodamine 6G recovered. The recovery of fluorescence intensity rate (I/I0) has a good relationship with the cobalt ion concentration (cCO2+) added. Thus, the authors developed a fluorescence method for the detection of cobalt ions based on the FRET of silver triangular nanoplates and Rhodamine 6G.