ABSTRACT
Nanoparticles have aroused widespread interest because of their unique surface structure and nano effect, which presents novel characteristics like as sound, light, electricity, magnetism, and thermal properties. However, two critical defects have hindered their applications: (1) poor processability resulting from the high melting temperature (e.g., >1000 °C) for some inorganic nanoparticles; (2) the restriction of the nano effect caused by the easy aggregation of the nanoparticles. To solve those issues, solvent-free nanofluids (SNFs) with hard cores and flexible organic chains were successfully designed and fabricated at the beginning of the twenty-first century. The promising technology of SNFs not only solved the dispersion problem of nanomaterials but also imparted novel functionalization to nanoparticles. Up to now, many researchers have been devoted to developing diverse cores and flexible organic polymer chains to endow SNFs with particular functions, such as conductivity, fluorescence, lubricity, and so on. However, there are few review reports on the research progress in the fabrication and applications of functional SNFs. To gain a better understanding of SNFs, this paper presents an overall investigation into the development, fabrication, as well as the applications of functional SNFs.
ABSTRACT
Biofilm-developed microplastics (MPs) may serve as important vectors for contaminants in aquatic environments. Elucidating the interactions between biofilm-developed MPs and coexisting contaminants is crucial for understanding the vector capacities of MPs. However, little is known about how the adverse effects of contaminants on MP surface-colonized biofilms influence their vector capacity. In this study, we aimed to investigate the interaction mechanism of biofilms colonizing the surface of MPs with coexisting contaminants using microcosm experiments and biofilm characterization techniques. The results indicated that the biofilm biomass on polystyrene increased over time, providing an additional abundance of oxygen-containing functional groups and promoting Cd accumulation by biofilm-developed polystyrene. Moreover, as a coexisting contaminant, Cd exerted adverse effects such as additional mortality of microorganisms and senescence and MP-colonized biofilm shedding. Consequently, the contaminant vector capacity of biofilm-developed MPs could be mitigated. Thus, the adverse effects of coexisting contaminants on biofilms influenced the ability of MPs to act as vectors in aquatic environments. Neglecting the negative effects of contaminants on biofilms may lead to an overestimation of the contaminant vector capacity of biofilm-developed MPs. This study provides support for more accurate assessment of the interactions between biofilm-developed MPs as vectors and contaminants in aquatic environments.
Subject(s)
Microplastics , Water Pollutants, Chemical , Microplastics/toxicity , Plastics , Polystyrenes/toxicity , Cadmium , Water Pollutants, Chemical/toxicity , Water Pollutants, Chemical/analysis , BiofilmsABSTRACT
Zwitterionic hydrogels have received considerable attention owing to their characteristic structures and integrating multifunctionality. However, the superhydrophilicity-induced poor mechanical properties severely hinder their potential applications. Besides, from the perspective of wide applications, zwitterionic hydrogels with integrated high mechanical properties, conductivity and multifunctionalities including self-adhesive, self-healing, and photothermal properties are highly desirable yet challenging. Herein, a new class of high-performance and multifunctional zwitterionic hydrogels are designed based on the incorporation of polydopamine-coated liquid metal nanoparticles (LM@PDA). Due to the efficient energy dissipation endowed by the isotropically extensible deformation of LM@PDA and the multiple interactions within the hydrogel matrix, the resultant hydrogels exhibited ultrahigh robustness with tensile strength of up to 1.3 MPa, strain of up to 1555% and toughness of up to 7.3 MJ m-3, superior or comparable to those of most zwitterionic hydrogels. The introduced LM@PDA also endows the hydrogels with high conductivity, versatile adhesion, autonomous self-healing, excellent injectability, three-dimensional printability, degradability, and photothermal conversion performance. These preferable properties enable the hydrogels promising as wearable sensors with multiple sensory capabilities for a wide range of strain values (1-500%), pressures (0.5-200 kPa) and temperatures (20-80 °C) with an impressive temperature coefficient of resistance (up to 0.15 °C-1). Moreover, these hydrogels can be also applied as solar evaporators with a high water evaporation rate (up to 2.42 kg m-2 h-1) and solar-thermal conversion efficiency (up to 90.3%) for solar desalination and wastewater purification. The present work can pave the way for the future development of zwitterionic hydrogels and beyond.
ABSTRACT
Lightweight and highly compressible materials have received considerable attention in flexible pressure sensing devices. In this study, a series of porous woods (PWs) are produced by chemical removal of lignin and hemicellulose from natural wood by tuning treatment time from 0 to 15 h and extra oxidation through H2O2. The prepared PWs with apparent densities varying from 95.9 to 46.16 mg/cm3 tend to form a wave-shaped interwoven structure with improved compressibility (up to 91.89 % strain under 100 kPa). The sensor assembled from PW with treatment time of 12 h (PW-12) exhibits the optimal piezoresistive-piezoelectric coupling sensing properties. For the piezoresistive properties, it has high stress sensitivity of 15.14 kPa-1, covering a wide linear working pressure range of 0.06-100 kPa. For its piezoelectric potential, PW-12 shows a sensitivity of 0.443 V·kPa-1 with ultralow frequency detection as low as 0.0028 Hz, and good cyclability over 60,000 cycles under 0.41 Hz. The nature-derived all-wood pressure sensor shows obvious superiority in the flexibility for power supply requirement. More importantly, it presents fully decoupled signals without cross-talks in the dual-sensing functionality. Sensor like this is capable of monitoring various dynamic human motions, making it an extremely promising candidate for the next generation artificial intelligence products.
ABSTRACT
Polymer dielectrics are the preferred materials of choice for power electronics and pulsed power applications. However, their relatively low operating temperatures significantly limit their uses in harsh-environment energy storage devices, e.g., automobile and aerospace power systems. Herein, hexagonal boron nitride (h-BN) films are prepared from chemical vapor deposition (CVD) and readily transferred onto polyetherimide (PEI) films. Greatly improved performance in terms of discharged energy density and charge-discharge efficiency is achieved in the PEI sandwiched with CVD-grown h-BN films at elevated temperatures when compared to neat PEI films and other high-temperature polymer and nanocomposite dielectrics. Notably, the h-BN-coated PEI films are capable of operating with >90% charge-discharge efficiencies and delivering high energy densities, i.e., 1.2 J cm-3 , even at a temperature close to the glass transition temperature of polymer (i.e., 217 °C) where pristine PEI almost fails. Outstanding cyclability and dielectric stability over a straight 55 000 charge-discharge cycles are demonstrated in the h-BN-coated PEI at high temperatures. The work demonstrates a general and scalable pathway to enable the high-temperature capacitive energy applications of a wide range of engineering polymers and also offers an efficient method for the synthesis and transfer of 2D nanomaterials at the scale demanded for applications.
ABSTRACT
The demand for a new generation of high-temperature dielectric materials toward capacitive energy storage has been driven by the rise of high-power applications such as electric vehicles, aircraft, and pulsed power systems where the power electronics are exposed to elevated temperatures. Polymer dielectrics are characterized by being lightweight, and their scalability, mechanical flexibility, high dielectric strength, and great reliability, but they are limited to relatively low operating temperatures. The existing polymer nanocomposite-based dielectrics with a limited energy density at high temperatures also present a major barrier to achieving significant reductions in size and weight of energy devices. Here we report the sandwich structures as an efficient route to high-temperature dielectric polymer nanocomposites that simultaneously possess high dielectric constant and low dielectric loss. In contrast to the conventional single-layer configuration, the rationally designed sandwich-structured polymer nanocomposites are capable of integrating the complementary properties of spatially organized multicomponents in a synergistic fashion to raise dielectric constant, and subsequently greatly improve discharged energy densities while retaining low loss and high charge-discharge efficiency at elevated temperatures. At 150 °C and 200 MV m(-1), an operating condition toward electric vehicle applications, the sandwich-structured polymer nanocomposites outperform the state-of-the-art polymer-based dielectrics in terms of energy density, power density, charge-discharge efficiency, and cyclability. The excellent dielectric and capacitive properties of the polymer nanocomposites may pave a way for widespread applications in modern electronics and power modules where harsh operating conditions are present.