Enhanced tensile and electrochemical performance of MXene/CNT hierarchical film.

Nowadays, it is highly desirable to achieve high strength, flexibility and electrochemical performance for supercapacitor electrodes simultaneously. Herein, few-layer MXene flakes are assembled into free-standing films by facile vacuum-filtration method, in which hydrophilic-functionalized carbon nanotubes (CNTs) are further incorporated. The morphology of MXene/CNT composite films evolves from compact to 'CNT in MXene' to laminar to 'MXene in CNT' and finally to separate structures when increasing the CNT weight percentage. Among them, the laminar structure in which thin MXene and CNT layers are stacked alternately is demonstrated to be the best. The laminar MXene/CNT film possesses much higher strength, elongation and specific capacitance than MXene film due to the engineered porosity, good interaction between MXene flakes and CNTs, and proper CNTs' distribution. As a result, high specific capacitance of 423.4 F g-1at 1 A g-1and capacitance retention of nearly 60% at 10 A g-1are accomplished. Moreover, the composite film is flexible and withstands bending up to 180°, indicating that the proposed laminar MXene/CNT composite film is a superb candidate for flexible supercapacitors.

Wearable strain sensor based on highly conductive carbon nanotube/polyurethane composite fibers.

Highly conductive and stretchable fibers have recently attracted increasing attention owing to their potential for application in flexible wearable electronics. Carboxylated carbon nanotubes (c-CNTs) are coated onto flexible fibers as a convenient way of fabricating wearable strain sensors. However, the conductivity of a c-CNT is reduced due to the destruction of the graphitized structure of the CNT during carboxylation. It still remains a significant challenge to endow c-CNT composite fibers with high conductivity. In this study, highly conductive fibers were prepared by coating metal ion-linked c-CNTs onto polyurethane (PU) fibers in order to improve the electron transport rate between the c-CNTs. The metal-coordination junctions formed by Fe2+ ions and carboxyl significantly enhanced the conductivity of the PU/CNT@Fe2+ fibers (up to 72 S m-1). The high conductivity is the result of coordination junctions with strong electronic state coupling facilitating electron transport, which was proved by density functional theory calculations. The resulting coordination effect enhanced the interaction between the c-CNTs, which made the conductive network more flexible. The strain sensor based on PU/CNT@Fe2+ fibers exhibited high sensitivity (gauge factor = 36 at 50% strain), a large strain range, inconspicuous drift and durability. The fibrous strain sensor was successfully used to monitor joint movement and facial expression.

Theoretical study of a p-n homojunction SiGe field-effect transistor via covalent functionalization.

p-n homojunctions are superior to p-n heterojunctions in constructing nanoscale functional devices, owing to the excellent crystallographic alignment. We tune the electronic properties of monolayer siligene (SiGe) into p/n-type via the covalent functionalization of electrophilic/nucleophilic dopants, using ab initio quantum transport calculations. It is found that the n-type doping effect of K atoms is stronger than that of benzyl viologen (BV) molecule on the surface of SiGe monolayer, owing to the strong covalent interaction. Both of p-type 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4TCNQ)-adsorbed and n-type 4 K-adsorbed SiGe systems show enhanced optical absorption in the infrared region, indicating their promising applications in infrared optoelectronic devices. By spatially adsorbing F4TCNQ molecule and K atoms on the source and drain leads, respectively, we designed a p-n homojunction SiGe field-effect transistor (FET). It is predicted that the built F4TCNQ-4K/SiGe FET can meet the requirements for high-performance (the high current density) and low-power (low subthreshold swing (SS)) applications, according to the International Technology Roadmap for Semiconductors in 2028. The present study gains some key insights into the importance of surface functionalization in constructing p-n homojunction electronic and optoelectronic devices based on monolayer SiGe.

Solid drug particles encapsulated bead-on-string nanofibers: the control of bead number and its corresponding release profile.

Bead-on-string nanofibers are explored as potential carriers of micro-level solid drug particles in recent years in drug release and tissue engineering. The special alternating distribution of nanoscale fiber and micro beads satisfied the fully encapsulation of particle drugs and the corresponding sustained release. Antibiotic drug tetracycline hydrochloride (TCH) was used as solid model drug particles. The present study fabricated poly (lactic-co-glycolic acid) (PLG A) bead-on-string nanofibers with different TCH loading rates for the controlled drug delivery. Bead number (BN), as one of the crucial factors that determine the encapsulation capability, was successfully controlled by tailoring the electrospinning parameters: voltage, flow rate and distance. The in vitro release experiment analyze by UV-Visible light spectrophotometer indicated that the bead-on-string nanofiber with more BN would increase the total release quantity of TCH. The drug released from bead-on-string nanofibers was mainly driven by classical Fickian diffusion. PLGA bead-on-string nanofibers suggest the potential as promising substrate for solid drug particles delivery applications.

A wearable fiber-shaped supercapacitor based on a poly(lactic acid) filament and high loading polypyrrole.

There is a growing interest in fiber-shaped supercapacitors, which are likely to meet the demands of wearable electronics. However, the loading of active material is so small that the energy density of fiber supercapacitors is low. In this research, a graphene oxide/poly(pyrrole) (GO/PPy) hybrid was applied as the active material and a novel method to accomplish a high loading of the active material on poly(lactic acid) (PLA) filaments is proposed. Iron ions, as positive ions, are intercalated into GO sheets to form complexes which can be absorbed on the surface of the PLA. Furthermore, iron ions can be used as initiators to initiate pyrrole polymerization. Using complexes in which iron ions are intercalated into GO, instead of pure GO, then coated onto PLA and then polymerized using pyrrole, this method could effectively increase the loading of PPy. As a result, the active material loading is 0.121 mg cm-1, and the weight gain rate even reached 72.4%. A high areal specific capacitance of 158.8 mF cm-2 and energy density of 3.5 µW h cm-2 are achieved using the proposed fiber-shaped supercapacitor. Meanwhile, it shows great potential for textile shaped electronics because of its fiber format.

A Li-Air Battery with Ultralong Cycle Life in Ambient Air.

The Li-air battery represents a promising power candidate for future electronics due to its extremely high energy density. However, the use of Li-air batteries is largely limited by their poor cyclability in ambient air. Herein, Li-air batteries with ultralong 610 cycles in ambient air are created by combination of low-density polyethylene film that prevents water erosion and gel electrolyte that contains a redox mediator of LiI. The low-density polyethylene film can restrain the side reactions of the discharge product of Li2 O2 to Li2 CO3 in ambient air, while the LiI can facilitate the electrochemical decomposition of Li2 O2 during charging, which improves the reversibility of the Li-air battery. All the components of the Li-air battery are flexible, which is particularly desirable for portable and wearable electronic devices.

Fast loading ester fluorescent Ca2+ and pH indicators into pollen of Pyrus pyrifolia.

Loading of Ca(2+)-sensitive fluorescent probes into plant cells is an essential step to measure activities of free Ca(2+) ions in cytoplasm with a fluorescent imaging technique. Fluo-3 is one of the most suitable Ca(2+) indicators for CLSM. We loaded pollen with fluo-3/AM at three different temperatures. Fluo-3/AM was successfully loaded into pollen at both low (4°C) and high (37°C) temperatures. However, high loading temperature was best suited for pollen, because germination rate of pollen and growth of pollen tubes were relatively little impaired and loading time was shortened. Moreover, Ca(2+) distribution increased in the three apertures of pollen after hydration and showed a Ca(2+) gradient, similar to the tip of growing pollen tubes. The same protocol can be used with the AM-forms of other fluorescent dyes for effective labeling. When loading BCECF-AM into pollen at high temperature, the pollen did not show a pH gradient after hydration. Ca(2+) activities and fluxes had the same periodicity as pollen germination, but pH did not show the same phase and mostly lagged behind. However, the clear zone was alkaline when pollen tube growth was slowed or stopped and turned acidic when growth recovered. It is likely that apical pH(i) regulated pollen tube growth.

Identification of hyperpolarization-activated calcium channels in apical pollen tubes of Pyrus pyrifolia.

The pollen tube has been widely used to study the mechanisms underlying polarized tip growth in plants. A steep tip-to-base gradient of free cytosolic calcium ([Ca(2+)](cyt)) is essential for pollen-tube growth. Local Ca(2+) influx mediated by Ca(2+)-permeable channels plays a key role in maintaining this [Ca(2+)](cyt) gradient. Here, we developed a protocol for successful isolation of spheroplasts from pollen tubes of Pyrus pyrifolia and identified a hyperpolarization-activated cation channel using the patch-clamp technique. We showed that the cation channel conductance displayed a strong selectivity for divalent cations, with a relative permeability sequence of barium (Ba(2+)) approximately Ca(2+) > magnesium (Mg(2+)) > strontium (Sr(2+)) > manganese (Mn(2+)). This channel conductance was selective for Ca(2+) over chlorine (Cl(-)) (relative permeability P(Ca)/P(Cl) = 14 in 10 mm extracellular Ca(2+)). We also showed that the channel was inhibited by the Ca(2+) channel blockers lanthanum (La(3+)) and gadolinium (Gd(3+)). Furthermore, channel activity depended on extracellular pH and pollen viability. We propose that the Ca(2+)-permeable channel is likely to play a role in mediating Ca(2+) influx into the growing pollen tubes to maintain the [Ca(2+)](cyt) gradient.