The processes and transport fluxes of land-based macroplastics and microplastics entering the ocean via rivers.

Approximately 80% of marine plastic waste originates from land-based sources and enters oceans through rivers. Hence, to create effective regulations, it is crucial to thoroughly examine the processes by which land-based plastic waste flows into marine environments. To this end, this review covers the complete journey of macro- and microplastics from their initial input into rivers to their ultimate release into oceans. Here, we also discuss the primary influencing factors and current popular research topics. Additionally, the principles, applicability, accuracy, uncertainty, and potential improvement of the standard methods used for flux estimation at each stage are outlined. Emission estimates of land-based macro- and microplastics are typically assessed using the emission factor approach, coefficient accounting approach, or material flow analysis. Accurately estimating mismanaged plastic waste is crucial for reducing uncertainty in the macroplastic emission inventory. In our review of the processes by which land-originating plastics enter rivers, we categorized them into two major types: point-source and diffuse-source pollution. Land surface hydrological models simulate transport from diffuse sources to rivers, necessitating further research. Riverine (micro)plastic flux to the ocean is often estimated using monitoring statistics and watershed hydrological models at the watershed scale; however, standardized monitoring methods have not yet been established. At the global scale, algorithms based on river datasets are often used, which require further improvements in river data selection and microplastic number-mass conversion factors. Furthermore, the article summarizes the accuracy and sources of uncertainty of various methods. Future research efforts should focus on quantifying and mitigating uncertainties in resultant projections. Overall, this review deepens our understanding of the processes by which land-based plastic waste enters the ocean and helps scholars efficiently select or improve relevant methods when studying land-ocean transport fluxes.

Spatial distribution and source apportionment of surface soil's polycyclic aromatic hydrocarbons in the Yangtze River Delta.

Soil acts as a crucial reservoir of polycyclic aromatic hydrocarbons (PAHs) in the environment, and its PAH content serves as a significant indicator of regional PAH pollution. Monitoring PAH levels in soil is important for assessing the potential risks to human and environmental health. In this study, 53 surface soil samples were collected from the Yangtze River Delta. These samples were monitored for 16 priority PAHs. Pollution levels, compositional profiles, and source differences of soil PAHs were analyzed among different regions, urban and rural areas, and functional zones. The total PAH content (Σ16PAHs) in the surface soil of the Yangtze River Delta was 2326.01 ± 2901.53 ng/g. High-ring PAHs (4-6 rings) accounted for the predominant portion (85.50%) of total PAHs. The average pollution level of soil PAHs in Jiangsu Province (2651.92 ± 3242.87 ng/g) was significantly higher than that of Zhejiang Province (2001.44 ± 2621.71 ng/g) and Shanghai (1669.13 ± 1758.34 ng/g), and high-ring PAHs constituted a predominant portion in these three regions. There was no significant difference in the PAH content between urban and rural areas. In different functional areas, automobile stations exhibited the highest PAH levels among the functional zones analyzed, with traffic emissions identified as a major source of soil PAH in this area. The primary factors influencing the distribution of soil PAHs in the study area were the duration of urbanization exposure (r = 0.753, p < 0.01) and soil organic carbon content (r = 0.452, p < 0.01). This provides novel evidence for the cumulative build-up of PAHs during urbanization. The positive matrix factorization model was used to analyze the sources of PAHs in the surface soil of the Yangtze River Delta, revealing that biomass and coal combustion (60.19%) and traffic emissions and coal combustion (31.82%) were the primary sources of PAHs in the region.

Simulation of seasonal transport of microplastics and influencing factors in the China Seas based on the ROMS model.

Elucidating the mechanisms governing microplastic transport and spatial distribution in offshore waters is essential to microplastic control. However, current research on microplastic transport in the China Seas is largely restricted to small-scale investigations, which do not provide a comprehensive result. Therefore, in this study, we used the Regional Ocean Modeling System (ROMS) combined with the Lagrangian Transport (LTRANS v.2) model to investigate how microplastics are transported around the China Seas during different seasons and under climatological river discharge. Our findings showed that the microplastic pathways and spatial distributions exhibit marked seasonal variations controlled by circulation patterns in the China Seas, river discharge values, and the characteristics of the microplastic materials. Floating microplastics exhibited the longest transport distance in summer, when microplastics from the Pearl River could be transported up to 1375.8 km through the Tokara and Tsushima straits. The heavy pollution areas in summer were located in the South Yellow Sea and East China Sea, mainly resulting from the contribution of the Yangtze River (>66%). In autumn and winter, more than three-quarters of the microplastics beached off the south-central Chinese coast. In addition, simulating the vertical velocity of the water prolonged the time required for microplastics to reach the open ocean, thereby reducing the amount of microplastics entering the Pacific Ocean by 6% compared to the simulation without the vertical velocity of the water in summer. Microplastics with higher densities were generally transported shorter distances. The transmission distances of PET and PS were two orders of magnitude smaller than that of PE. This study enhances knowledge of the sources and fates of offshore microplastics and provides scientific support for offshore microplastic control.