ABSTRACT
It is still challenging to develop multi-step cascaded artificial light-harvesting systems (ALHSs) with tunable efficiency. Here, we designed novel cascaded ALHSs with AIE-active metallacycles as the light-harvesting antenna, Eosin Y (ESY) and sulforhodamine 101 (SR101) as conveyors, near-infrared emissive chlorin-e6 (Ce6) as the final acceptor. The close contact and fair spectral overlap between donor and acceptor molecules at each level ensured the efficient sequential three-step energy transfer. The excited energy was sequentially and efficiently funneled to Ce6 along the cascaded line MTPEPt1 â ESY â SR101 â Ce6. Additionally, a unique strategy for regulating the efficiency of ALHS was illustrated by adjusting hydrophilic and hydrophobic interactions.
ABSTRACT
Combination of platinum(II) metallacycles and photodynamic inactivation presents a promising antibacterial strategy. Herein, a cascaded artificial light-capturing system is developed in which an aggregation-induced emission-active platinum(II) metallacycle (PtTPEM) is utilized as the antenna, sulforhodamine 101 (SR101) as a key conveyor, and the near-infrared emissive photosensitizer Chlorin-e6 (Ce6) as the final energy acceptor. The well-dispersed Ce6 in the proximity of energy donors not only avoids self-quenching in the physiological environment but also contributes to energy transfer from donor to acceptor, thereby significantly improving the 1 O2 generation ability of the light-harvesting system under white light irradiation. By integrating the platinum(II) metallacycle and 1 O2 , a more efficient synergistic antibacterial effect is achieved at low concentrations, along with a significant decrease in dark toxicity caused by PtTPEM.
