ABSTRACT
Stiffness variable polymers are an essential family of materials that have aroused considerable attention in soft actuators. Although lots of strategies have been proposed to achieve variable stiffness, it remains a formidable challenge to achieve a polymer with a wide stiffness range and fast stiffness change. Herein, a series of variable stiffness polymers with a fast stiffness change and wide stiffness range were successfully synthesized, and the formulas were optimized via Pearson correlation tests. The rigid/soft stiffness ratio of the designed polymer samples can reach up to 1376-folds. Impressively, owing to the phase-changing side chains, the narrow endothermic peak can be observed with full width at half-maximum within 5 °C. Moreover, the shape memory properties of the shape fixity (Rf) and shape recovery ratio (Rr) values of the shape memory properties could reach up to 99.3 and 99.2%, respectively. Then, the obtained polymer was introduced into a kind of designed 3D printing soft actuator. The soft actuator can achieve sharp heating-cooling cycle of 19 s under a 1.2 A current with 4 °C water as coolant and can lift a 200 g weight at the actuating state. Moreover, the stiffness of the soft actuator can reach up to 718 mN/mm. The soft actuator exhibits an outstanding actuate behavior and stiffness switchable capability. We expect our design strategy and obtained variable stiffness polymers to be potentially applied in soft actuators and other devices.
ABSTRACT
Flexible power sources are crucial to developing flexible electronic systems; nonetheless, the current poor stretchability and stability of flexible power sources hinder their application in such devices. Accordingly, the stretchability and fatigue stability of flexible power sources are crucial for the practical application of flexible electronic systems. In this work, a flexible electrode with an arc-shaped star concave negative Poisson's ratio (NPR) structure is fabricated through the screen printing process. Using the combination of finite element analysis (FEA) and tensile tests, it is proven that the arc-shaped star concave NPR electrode can effectively reduce the maximum tensile stress and increase the maximum elongation (maximum elongation 140%). Furthermore, the flexible electrodes prepared in this study are assembled into all-solid-state symmetric supercapacitors (SSCs), and their electrochemical properties are tested. The SSC prepared in this study has a high areal capacitance of 243.1 mF cm-2. It retains 89.25% of its initial capacity after 5000 times of folding and can maintain a stable output even in extreme deformation, which indicates that the SSC prepared in this study has excellent stability. The SSC with the advantages mentioned above obtained in this study is expected to provide new opportunities to develop flexible electronic systems.
ABSTRACT
Flexible microfluidic chips have good application prospects in situations with easy bending and complex curvature. An important factor affecting the flexible microfluidic chip is its structural complexity. For example, the hybrid chip includes flow channels, mixing chambers, and one-way valves. How to achieve the same function with as few structures as possible has become an important research topic at present. In this paper, a Tesla valve micromixer with unidirectional flow characteristics is presented. A passive laminar flow Tesla valve micromixer is fabricated through 3D printing technology and limonene dissolution method. The main process is as follows: First of all, high impact polystyrene (HIPS) material was employed to make the Tesla valve channel mold. Second, the channel mold was dissolved in the limonene solvent. The mold of Tesla micromixer is made of HIPS material, the mixing experiment displace that the Tesla valve micromixer is characterized by unidirectional flow compared with the common T-shaped planar channel. At the same time, the 5-AAC Tesla valve micromixer can increase the mixing efficiency to 87%. By using four different groove structures and different flow rates of the mixing effect experiment, the conclusion is that the mixing efficiency of the 6-AAC Tesla valve micromixer is up to 0.89 when the flow rate is 2 mL/min. The results manifest that the Tesla valve structure can effectively improve the mixing efficiency.
ABSTRACT
Although lots of methods have been developed for self-healing materials, it remains a formidable challenge to achieve a thermosetting material with water-insensitive and self-healing properties at room temperature. Nature always provides intelligent strategies for developing advanced materials with superior properties. Herein, a novel self-healable polyurea-urethane was rationally designed by combining mussel adhesive protein-mimetic structure and dynamic aromatic disulfide bonds. It achieves high self-healing efficiency of 98.4% at room temperature for only 6 h and 90% at 60â for only 30 min without any external stimuli. Impressively, this self-healing capability possesses exceptional water-resistance, which presents high self-healing efficiency of 98.1% for 2 h and 82.1% for 6 h in 60â and 25â water, respectively. Besides, the designed polyurea-urethane exhibits excellent mechanical properties such as high elongation at break of 2400%, notch-insensitive stretching elongation of 1500% and notable recovery capability. This strategy shows promising application potential in solid propellants, protective coating, electronic skin, soft sensors and other water-resistant devices.
ABSTRACT
Self-healing efficiency and mechanical strength are always a pair of mechanical contradictions of a polymer. Herein, a series of novel mussel-inspired modified graphene oxide/polyurethane composites were successfully fabricated via rational molecular design and introducing hyperbranched polymer-modified graphene oxide. The composites exhibit outstanding self-healing performances with a self-healing efficiency of 87.9%. Especially, their self-healing properties possess exceptional water-insensitivity, which presents a high self-healing efficiency of 92.5% under 60 °C water for 2 h and 74.6% under 25 °C water for 6 h. Furthermore, the tensile strength of the composites increased by 107.7% with a high strain of 2170%. In addition, the composites show a remarkable recovery capability of 76.3% and 83.7% under tensile and compression loading, respectively, after 20 cycles. This strategy shows prominent application potential in high-performance solid propellants, protective coating, electronic skin, soft sensors and other water-insensitive devices.
ABSTRACT
As is well known, it is difficult to simultaneously improve both the strength and elongation at break of polymers filled with nanomaterials. This work obtained high-performance composites with enhanced strength and elongation at break via cross-linking hydroxyl-terminated polybutadiene (HTPB) chains with hyperbranched-polyamide-modified graphene oxide (HGO), and the preparation, characterization, and mechanical properties of the composites serving as a composite solid-propellant binder have been described in detail. Compared with pure HTPB polyurethane (P-HTPB), the tensile strength and elastic modulus of the composite containing 0.1 wt% HGO (H-0.1/HTPB) increase by 57.8% and 65.3%, respectively. Notably, the elongation at break of the H-0.1/HTPB composite can reach up to 1292.6%, which is even higher than that of P-HTPB. Moreover, the capabilities of the composites to resist deformation have also been enhanced significantly. The glass transition temperatures of the composites are still extremely low (â¼-73 °C), which is beneficial for their applications. It can be expected that this study can provide an effective fabrication approach and strategy for preparing high-performance polyurethane composites.
