Synthesis of magnetic sodium lignosulfonate hydrogel(Fe3O4@LS) and its adsorption behavior for Cd2+ in wastewater.

Heavy metal pollution is becoming increasingly serious. Heavy metal pollutants are nonbiodegradable and can be bioenriched through the food chain, and thus, they greatly threaten the environment and human health. Hydrogels, as an ideal adsorbent, have been widely used to treat heavy metal industrial wastewater. Sodium lignosulfonate hydrogel (LS) was prepared by free-radical grafting copolymerization, and nano-Fe3O4 particles were loaded in LS by an in-situ precipitation method (Fe3O4@LS). The magnetic properties and adsorption capacity of Fe3O4@LS are closely related to the load capacity of Fe3O4. XRD, FTIR, XPS, SEM, TEM, BET, and TGA analyses of the materials were performed. Subsequently, the removal effect of the typical pollutant Cd2+ in heavy metal-polluted water was studied with Fe3O4@LS as the adsorbent. The influences of the Fe3O4@LS dosage and initial pH were investigated, and the adsorption kinetics and thermodynamics were further explored and discussed. Finally, the adsorption mechanism of Fe3O4@LS on Cd2+ was obtained. Results show that Fe3O4@LS has a more stable spatial network structure than LS, and the pore size, specific surface area and active sites increase. The maximum adsorption capacity can reach 88.00 mg/g when pH = 6 and the dosage of Fe3O4@LS is 1000 mg/L. The adsorption of Cd2+ by Fe3O4@LS conforms to pseudosecond-order kinetics and the Temkin isothermal adsorption model. Further mechanistic investigations show that the sorption of Cd2+ on Fe3O4@LS is mainly attributed to surface complexation, electrostatic attraction and coprecipitation. The coexistence of cations in water will inhibit the adsorption of Fe3O4@LS. Fe3O4@LS has superparamagnetism and a good response to an external magnetic field. The adsorption rate can still reach >60 % after four elutions with NaCl as the eluent. This material can be reused and has good application potential.

Synthesis of cationic biomass lignosulfonate hydrogel for the efficient adsorption of Cr(VI) in wastewater with low pH.

In the present study, we synthesized a cationic lignosulfonate hydrogel (LS-g-P (AM-co-DAC)) by grafting acrylamide (AM) and acryloxyethyl trimethyl ammonium chloride (DAC) onto sodium lignosulfonate (LS) via free radical copolymerization. The solution pH, contact time, initial concentration, and temperature were comprehensively investigated through the static adsorption method for the adsorption behaviours of Cr(VI) by the hydrogel. The experimental results show that the best conditions were a temperature of 30°C, a dosage of 0.1 g, pH = 3, a concentration of 50 mg / L, and contact time = 2 h with removal efficiencies of above 70% and adsorption capacity of 18.14 mg·g-1. The adsorption process followed the Langmuir isothermal model, indicating monolayer adsorption, and the maximum adsorption capacity was 58.86 mg·g-1. Adsorption kinetics results show that the pseudo-second-order kinetic model dominated the adsorption process, and the adsorption activation energy was 5.489 kJ·mol-1. In addition, the adsorption involved spontaneous exothermic and entropy reduction. The combination of FT-IR, SEM, and XRD was used to characterize the structure and properties of the prepared hydrogel, and the adsorption mechanism was the result of electrostatic attraction, physical and chemical adsorption, and hydrogen bond. The hydrogel has good regenerative properties after desorption. Overall, this work synthesized an environmentally friendly biomass lignin-based hydrogel, which can be used as an adsorbent for the treatment of anionic pollutants, and explored a new method for the high-value utilization of industrial lignin.HighlightsNovel cationic lignosulfonate hydrogel (LS-g-P (AM-co-DAC)) was synthesized by a free radical method.SEM and XRD results confirmed the surface of the obtained hydrogel shows a 3D network structure and does not have a crystal structure.LS-g-P (AM-co-DAC) hydrogel adsorbent can selectively adsorb Cr6+ at pH 3.0.The adsorption conditions and the adsorption mechanism were studied in detail.Electrostatic interaction plays a key role in the adsorption of Cr6+.

Adsorption of Rhodamine B from an aqueous solution by acrylic-acid-modified walnut shells: characterization, kinetics, and thermodynamics.

A batch experiment was used in studying the effect of acrylic-acid-modified walnut shell (MWNS) as a low-cost adsorbent for removing Rhodamine B (RB) cationic dye in aqueous solutions. The adsorbent dosage, initial dye concentration, contact time, temperature, pH, and supporting electrolyte concentration on the adsorption behaviour of the adsorbent were explored. The adsorbent was characterized using the point of zero charge (pHPZC), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), automatic specific surface analysis (BET), and X-ray photoelectron spectroscopy (XPS). Results showed that MWNS had abundant active groups and rough surface, which is conducive to the adsorption process. The kinetics and equilibrium data of MWNS-to-RB adsorption were in accordance pseudo-second-order kinetic and Freundlich isotherm models, respectively. Under optimal adsorption conditions, the maximum adsorption capacity of RB was 48.87 mg·g-1. Thermodynamic results showed spontaneously and exothermically the adsorption process. Moreover, the addition of electrolyte had a negative effect on equilibrium adsorption capacity and adsorption rate.HIGHLIGHTS Acrylic-acid-modified walnut shells was used as an adsorbent for the removal of Rhodamine B (RB).The adsorption of RB by modified walnut shells was greatly affected by pH.Pseudo-second-order kinetic and Freundlich model fit the experimental data.The modified walnut shell can remove RB through electrostatic attraction, hydrogen bonding, and electron donor-acceptor interaction.

Tracing sources of oilfield wastewater based on excitation-emission matrix fluorescence spectroscopy coupled with chemical pattern recognition techniques.

In order to prevent the illegal discharge of oilfield wastewater, this work proposed excitation-emission matrix fluorescence (EEMF) spectroscopy coupled with two kinds of chemical pattern recognition methods for tracing the sources of oilfield wastewater. The first pattern recognition method was built from the relative concentrations extracted by alternating trilinear decomposition (ATLD) based on partial least squares-discriminant analysis (PLS-DA) algorithm, and the other one was modeled based on strictly multi-way partial least squares-discriminant analysis (N-PLS-DA). Both methods showed good discrimination abilities for oilfield wastewater samples from three different sources. The total recognition rates of the training and prediction sets are 100%, the values of sensitivity and selectivity are 1. This study showed that EEMF spectroscopy combined with chemical pattern recognition techniques could be used as a potential tool for tracing the sources of oilfield wastewater.