Raman evaluation of the crystallinity degree and composition of poly(L-lactide-co-ε-caprolactone).

In this work, we study two series of the copolymers of L-lactide (LLA) and ε-caprolactone (CL) with the CL molar content of 5, 15, and 30 %. The first series was the commercial semicrystalline granules (Corbion, Netherlands), which we analyzed without any additional modification. The second series was amorphous films, prepared from the granules by hot pressing with the subsequent fast quenching in order to avoid the crystallization. We used Raman spectroscopy in conjunction with the quantum chemical modeling to evaluate the structure of the copolymers. As additional methods, we applied X-ray diffraction (XRD) analysis and differential scanning calorimetry (DSC). The main result of our study is the elaboration of the Raman methods of quantitative analysis of the relative contents of the comonomers and the crystallinity degree of the poly(L-lactide-co-ε-caprolactone). These methods are based on measurements of the ratios of the peak intensities of the poly(L-lactide) (PLLA) bands at 411 and 874 cm-1, the PLLA band at 2947 cm-1 and the poly(ε-caprolactone) band at 2914 cm-1. Raman study shows that growth of the CL content causes the monotonous decrease in the crystallinity degree of PLLA blocks. Density functional theory analysis of LLA decamer in the conformation of helix 103 allows us to assign the PLLA Raman bands. The Raman data on the composition and crystallinity degree of the copolymers correlate very well with the results of XRD and DSC studies, as well as with the information on the composition of the copolymers provided by manufacturer.

Raman structural study of ethylene glycol and 1,3-propylene glycol aqueous solutions.

Raman spectra of ethylene glycol (EG) and 1,3-propylene glycol (1,3-PG) aqueous solutions with the diol content from 10 to 90 mol% were measured. The diol content weakly influences the EG and 1,3-PG Raman bands in the spectra of the solutions in the region 250-1800 cm-1. This fact means that the conformational compositions of both the diols do not change significantly with dissolving in water. The intensity of the OH stretching band with respect to the diol bands intensities is the linear function of the ratio of the mole contents of water and the diol in the solutions. The spectral region 2800-3800 cm-1 can be used to evaluate the chemical composition of these binary solutions. DFT modeling of the Raman spectra of EG molecule in water shell confirms the prevalence of the gauche-conformation of EG in the aqueous solutions.