Experimental Investigation on Environmentally Sustainable Cement Composites Based on Wheat Straw and Perlite.

Environmentally sustainable cement mortars containing wheat straw (Southern Italy, Apulia region) of different length and dosage and perlite beads as aggregates were prepared and characterised by rheological, thermal, acoustic, mechanical, optical and microstructural tests. A complete replacement of the conventional sand was carried out. Composites with bare straw (S), perlite (P), and with a mixture of inorganic and organic aggregates (P/S), were characterised and compared with the properties of conventional sand mortar. It was observed that the straw fresh composites showed a decrease in workability with fibre length decrease and with increase in straw volume, while the conglomerates with bare perlite, and with the aggregate mixture, showed similar consistency to the control. The thermal insulation of the straw mortars was extremely high compared to the sand reference (85-90%), as was the acoustic absorption, especially in the 500-1000 Hz range. These results were attributed to the high porosity of these composites and showed enhancement of these properties with decrease in straw length and increase in straw volume. The bare perlite sample showed the lowest thermal insulation and acoustic absorption, being less porous than the former composites, while intermediate values were obtained with the P/S samples. The mechanical performance of the straw composites increased with length of the fibres and decreased with fibre dosage. The addition of expanded perlite to the mixture produced mortars with an improvement in mechanical strength and negligible modification of thermal properties. Straw mortars showed discrete cracks after failure, without separation of the two parts of the specimens, due to the aggregate tensile strength which influenced the impact compression tests. Preliminary observations of the stability of the mortars showed that, more than one year from preparation, the conglomerates did not show detectable signs of degradation.

Performance Characterization of Broad Band Sustainable Sound Absorbers Made of Almond Skins.

In order to limit the environmental impact caused by the use of non-renewable resources, a growing research interest is currently being shown in the reuse of agricultural by-products as new raw materials for green building panels. Moreover, the European directives impose the goal of sustainability supporting the investigation of passive solutions for the reduction of energy consumption. Thus, the promotion of innovative building materials for the enhancement of acoustic and thermal insulation of the buildings is an important issue. The aim of the present research was to evaluate the physical, acoustical, and thermal performances of building panels produced by almond skin residues, derived from the industrial processing of almonds. In this paper different mix designs were investigated using polyvinyl acetate glue and gum Arabic solution as binders. Air-flow resistivity σ and normal incidence sound absorption coefficient α were measured by means of a standing wave tube. Thermal conductivity λ, thermal diffusivity α, volumetric heat capacity ρc were measured using a transient plane source device. Finally, water vapor permeability δp was experimentally determined using the dry cup method. Furthermore, a physical characterization of the specimens in terms of bulk density ρb and porosity η allowed to study the correlation existing between the binder and the aggregates and the consequent acoustical and hygrothermal behavior occurring on the different mix designs. The achieved results suggested the investigated materials comparable to the main products currently existing on the market.

Composite Eco-Friendly Sound Absorbing Materials Made of Recycled Textile Waste and Biopolymers.

In recent years, the interest in reusing recycled fibers as building materials has been growing as a consequence of their ability to reduce the production of waste and the use of virgin resources, taking advantage of the potential that fibrous materials may offer to improve thermal and acoustic comfort. Composite panels, made of 100% wool waste fibers and bound by means of either a chitosan solution and a gum Arabic solution, were tested and characterized in terms of acoustic and non-acoustic properties. Samples with a 5 cm thickness and different density values were made to investigate the influence of flow resistivity on the final performance. Experimental results demonstrated that the samples had thermal conductivity ranging between 0.049 and 0.060 W/(m K), well comparable to conventional building materials. Similarly, acoustic results were very promising, showing absorption coefficients that, for the given thickness, were generally higher than 0.5 from 500 Hz on, and higher than 0.9 from 1 kHz on. Finally, the effects of the non-acoustic properties and of the air gap behind the samples on the acoustic behavior were also analyzed, proving that the agreement with absorption values predicted by empirical models was also very good.

Porous Waste Glass for Lead Removal in Packed Bed Columns and Reuse in Cement Conglomerates.

A porous waste glass (RWPG = recycled waste porous glass) was used in wastewater treatments for the removal of lead ions from single, binary, and ternary metal solutions (with cadmium and nickel ions). Experiments were performed in columns (30 cm³, 10 g) filled with 0.5⁻1 mm beads till complete glass exhaustion (breakthrough). In the case of single and binary solutions, the columns were percolated at 0.2 Lh-1 (2 mg Me+2 L-1); in the case of ternary solutions, the columns were percolated at 0.15⁻0.4 Lh-1 (2 mg Me2+ L-1) and with 2⁻5 mg Me2+ L-1 influent concentration (0.2 Lh-1). Lead ions were removed mainly by ion exchange and also by adsorption. From a kinetic point of view, the rate controlling step of the process was the interdiffusion of the lead ions in the Nernst stationary liquid film around the sorbent. The uptake of the metals and the glass selectivity were confirmed by Energy Dispersive X-ray spectroscopy (EDX) analysis. After lead retention process, glass beads were reused as lightweight aggregates for thermal insulating and environmental safe mortars.

Evaluation of thermal comfort in university classrooms through objective approach and subjective preference analysis.

Assessing thermal comfort becomes more relevant when the aim is to maximise learning and productivity performances, as typically occurs in offices and schools. However, if, in the offices, the Fanger model well represents the thermal occupant response, then on the contrary, in schools, adaptive mechanisms significantly influence the occupants' thermal preference. In this study, an experimental approach was performed in the Polytechnic University of Bari, during the first days of March, in free running conditions. First, the results of questionnaires were compared according to the application of the Fanger model and the adaptive model; second, using a subjective scale, a complete analysis was performed on thermal preference in terms of acceptability, neutrality and preference, with particular focus on the influence of gender. The user possibility to control the indoor plant system produced a significant impact on the thermal sensation and the acceptability of the thermal environment. Gender was also demonstrated to greatly influence the thermal judgement of the thermal environment when an outdoor cold climate occurs.