Ambient temperature liquid salt electrolytes.

Alkali metal salts usually have high melting points due to strong electrostatic interactions and solvents are needed to create ambient temperature liquid electrolytes. Here, we report on six phosphate-anion-based alkali metal salts, Li/Na/K, all of which are liquids at room temperature, with glass transition temperatures ranging from -61 to -29 °C, and are thermally stable up to at least 225 °C. While the focus herein is on various physico-chemical properties, these salts also exhibit high anodic stabilities, up to 6 V vs. M/M+ (M = Li/Na/K), and deliver some battery performance - at elevated temperatures as there are severe viscosity limitations at room-temperature. While the battery performance arguably is sub-par, solvent-free electrolytes based on alkali metal salts such as these should pave the way for conceptually different Li/Na/K-batteries, either by refined anion design or by using several salts to create eutectic mixtures.

Plasticized and salt-doped single-ion conducting polymer electrolytes for lithium batteries.

Single-ion conducting polymer electrolytes created by plasticizing LiPSTFSI with PPO and LiTFSI are shown to both improve the ionic conductivity and alter the ion conduction mechanism. This correlates with both local and macroscopic properties, opening for rational design of solid-state, but yet pliable electrolytes.

Si and Ge-Based Anode Materials for Li-, Na-, and K-Ion Batteries: A Perspective from Structure to Electrochemical Mechanism.

Silicon and germanium are among the most promising candidates as anodes for Li-ion batteries, meanwhile their potential application in sodium- and potassium-ion batteries is emerging. The access of their entire potential requires a comprehensive understanding of their electrochemical mechanism. This Review highlights the processes taking place during the alloying reaction of Si and Ge with the alkali ions. Several associated challenges, including the volumetric expansion, particle pulverization, and uncontrolled formation of solid electrolyte interphase layer must be surmounted and different strategies, such as nanostructures and electrode formulation, have been implemented. Additionally, a new approach based on the use of layered Si and Ge-based Zintl phases is presented. The versatility of this new family permits the tuning of their physical and chemical properties for specific applications. For batteries in particular, the layered structure buffers the volume expansion and exhibits an enhanced electronic conductivity, allowing high power applications.