Environmental impact assessment of the electrokinetic adsorption barriers to remove different herbicides from agricultural soils.

In this study, the sustainability of the electrokinetic remediation soil flushing (EKSFs) process integrated without and with adsorption barriers (EKABs) have been evaluated for the treatment of four soils contaminated with Atrazine, Oxyfluorfen, Chlorosulfuron and 2,4-D. To this purpose, the environmental effects of both procedures (EKSFs and EKABs) have been determined through a life cycle assessment (LCA). SimaPro 9.3.0.3 was used as software tool and Ecoinvent 3.3 as data base to carry out the inventory of the equipment of each remediation setup based on experimental measurements. The environmental burden was quantified using the AWARE, USEtox, IPPC, and ReCiPe methods into 3 Endpoint impact categories (and damage to human health, ecosystem and resources) and 7 Midpoints impact categories (water footprint, global warming potential, ozone depletion, human toxicity (cancer and human non-cancer), freshwater ecotoxicity and terrestrial ecotoxicity). In general terms, the energy applied to treatment (using the Spanish energy mix) was the parameter with the greatest influence on the carbon footprint, ozone layer depletion and water footprint accounting for around 70 % of the overall impact contribution. On the other hand, from the point of view of human toxicity and freshwater ecotoxicity of soil treatments with 32 mg kg-1 of the different pesticides, the EKSF treatment is recommended for soils with Chlorosulfuron. In this case, the carbon footprint and water footprint reached values around 0.36 kg of CO2 and 114 L of water per kg of dry soil, respectively. Finally, a sensitivity analysis was performed assuming different scenarios.

Supplementation of sulfate polysaccharides in the seminal cooling medium of common curimata (Prochilodus brevis).

BACKGROUND: The use of sulfated polysaccharides (PS) in seminal cooling is known to improve seminal quality. OBJECTIVE: To evaluate the effect of different concentrations of PS, extracted from the macroalgae Gracilaria domigensis as a supplement to the seminal cooling medium of the reophilic fish Prochilodus brevis (common curimatã). MATERIALS AND METHODS: Five semen pools were diluted in ACP-104 (treatment T1), in BTS® (T2) and in BTS® with different concentrations of PS (0.5 [T3]; 1.0 [T4] and 1.5 [T5]). The samples were cooled for different times (0, 6, 24, 48, 72, 96 and 120 h) and after each hour they were analyzed for: morphology, membrane integrity, DNA integrity and sperm kinetics. RESULTS: There were no significant differences between the treatments containing different concentrations of sulfated polysaccharides. Regarding the different cooling times, it was possible to observe that after hour 96, there was a reduction in the parameters of sperm kinetics. For DNA integrity there was no significant difference in relation to the treatments nor in relation to the hours. For membrane integrity, a reduction was noted as of hour 96, but there was no influence of polysaccharides. For the sperm morphology, there was no statistical difference between the hours, however the BTS was better than the ACP-104. CONCLUSION: It is concluded that the use of polysaccharides in seminal cooling has no negative effect on sperm parameters and proves that seminal cooling keeps the material viable for up to 72 hours. Doi: 10.54680/fr23410110512.

Adapting the low-cost pre-disinfection column PREDICO for simultaneous softening and disinfection of pore water.

In previous works, a low-cost predisinfection column that combined coagulation-flocculation and GAC filtration was proposed for combination with electrodisinfection in the successful treatment of highly faecal polluted surface water. In this work, this column is adapted for the treatment of pore water by transforming the coagulation chamber into a chemical reactor with lime and replacing the GAC of the filter with ion exchange resins. This adapted system can soften water, remove nitrate and condition water for very efficient electrochemical disinfection, where 4 logs and 3 logs in the removal of E. coli and P. aeruginosa, respectively, were reached using commercial electrochemical cells, i.e., CabECO ® or MIKROZON®. The availability and low cost of the technology are strong points for usage in poor areas of developing countries.

Can the green energies improve the sustainability of electrochemically-assisted soil remediation processes?

The green powering of electrochemically-assisted soil remediation processes had been strongly discouraged. Low remediation efficiencies have been reported as a consequence of the reversibility of the transport processes when no power is applied to the electrodes, due to the intermittent powering of renewable sources. However, it has been missed a deeper evaluation from the environmental point of view. This work goes further and seeks to quantify, using life cycle assessment tools, the environmental impacts related to the electro-kinetic treatments powered by different sources: grid (Spanish energy mix), photovoltaic and wind sources. The global warming potential and the ozone depletion showed higher environmental impacts in case of using green energies, associated with the manufacturing of the energy production devices. In contrast to that, results pointed out the lowest water consumption for the treatment powered with solar panels. The huge water requirements to produce energy, considering a Spanish energy mix, drop the sustainability of this powering strategy in terms of water footprint. Regarding toxicities, the pollutant toxicity was highly got rid of after 15 days of treatment, regardless the powering source used. Nevertheless, the manufacturing of energy and green energy production devices has a huge impact into the toxicity of the remediation treatments, increasing massively the total toxicity of the process, being this effect less prominent by the electro-kinetic treatment solar powered. In view of the overall environmental impact assessed, according to mid and endpoint impact categories, it can be claimed that, despite the high energy requirements and affectation to the global warming potential, the use of solar power is a more sustainable alternative to remediate polluted soils by electrochemical techniques.

Toward more sustainable photovoltaic solar electrochemical oxidation treatments: Influence of hydraulic and electrical distribution.

Powering electrochemical technologies with renewable energies is a promising way to get more sustainable environmental remediation techniques. However, the operational conditions of those processes must be optimized to undergo fast and efficient treatments. In this work, the influence of electrical and hydraulic connections in the performance of a set of two electrolyzers directly powered by photovoltaic panels was evaluated. Despite both electrolyzers were assembled using the same electrode material, they showed different performances. Results indicate that the electrolyzer with higher ohmic resistance and higher overpotential attained a greater production of oxidant species, being produced under the most efficient strategy around 4.8 and 15.1 mmol of oxidants per Ah by electrolyzer 1 and 2, respectively. Nevertheless, an excess of oxidant production because of an inefficient energy management, led to low removal efficiencies as a consequence of a waste of energy into undesirable reactions. Regarding the hydraulic distribution of wastewater between the cells, it was found to influence on the total remediation attained, being the serial connection 2.5 and 1.8 more efficient than a parallel wastewater distribution under series and parallel electrical strategies, respectively. Regarding electrical strategies, parallel connections maximize the use of power produced by the photovoltaic panels. Furthermore, this allows the system to work under lower current densities, reducing the mass transfer limitations. Considering both advantages, a hydraulic connection of the cells in series and an electrical connection in parallel was found to reach the highest specific removal of pollutant, 2.52 mg clopyralid (Wh)-1. Conversely, the opposite strategy (parallel hydraulic connection-series electrical connection) showed the lowest remediation ratio, 0.48 mg clopyralid (Wh)-1. These results are important to be considered in the design of electrolytic treatments of waste directly powered by photovoltaic panels, because they show the way to optimize the cells stack layout in full-scale applications, exhibiting significant impact on the sustainability of the electrochemical application.

Improving sustainability of electrolytic wastewater treatment processes by green powering.

This work focuses on the evaluation of the impact of powering electrolytic wastewater treatment processes with grid or renewable energy on the sustainability of this electrochemical remediation technology. To face this goal, it was performed an inventory of three bench-scale plants made up by the same treatment technology but powered from different supplies: connected to grid and directly coupled with solar photovoltaic panels or a wind turbine. Results show that the powering mode can significantly affect the environmental risks of the treatment, not only in terms of electricity demand but also on the formation of intermediates, which are more important in the cases in which the intensity profile varied. A life cycle assessment (LCA) is carried out in order to quantify the environmental impacts of green powering electrolytic wastewater treatment processes. Ecoinvent 3.3 data base, AWARE, USEtox, IPPC and ReCiPe methodologies are used to quantify the environmental burden into 5 midpoint (water footprint, global warming 100a, ozone layer depletion, human toxicity, freshwater ecotoxicity) and 17 endpoint impact categories. All impact categories are higher in the case in which the supplied power cames from a electricity grid mix. For the removal of 0.1 g 2,4-dichlorophenoxyacetic acid (2,4D) per liter (functional unit) of treated wastewater releases 0.14 kg CO2 eq. If the energy is provided by a wind turbine or a solar panel the processes emit 0.020 kg CO2 eq and 0.019 kg CO2 eq, respectively. A comparison of the impact based on the grid mix used in different countries is also made, which has pointed out the relevance of this input on the sustainability of the environmental electrochemical technologies.

Does intensification with UV light and US improve the sustainability of electrolytic waste treatment processes?

This work aims to assess the influence of ultrasounds (US) application or ultraviolet (UV) light irradiation on the efficiency and sustainability of the treatment of wastes by conductive diamond electrochemical oxidation (CDEO). To do this, a life cycle assessment (LCA) is carried out in order to quantify the environmental impacts of the intensified CDEO processes. Inventories of three bench scale remediation plants (CDEO, Sono-CDEO and Photo-CDEO) in which the different technologies are implemented are performed by means of Ecoinvent 3.3 data base. AWARE, USEtox, IPPC and ReCiPe methodologies are used to quantify the environmental burden into 5 midpoint (water footprint, global warming 100a, ozone layer depletion, human toxicity, freshwater ecotoxicity) and 17 endpoint impact categories. Photo-CDEO attains the faster and more efficient removal in terms of energy consumed. All impact categories are lower in the case in which UV light irradiation is coupled to the CDEO treatment, particularly if the electrolyte does not contain chloride anions. From the point of view of toxicity and ecotoxicity, it is essential to achieve a complete mineralization, because of the intermediates generated into wastes containing chloride anions can become more hazardous than the initial pesticide. The operation of these technologies at large current densities shows positive results from the sustainability point of view, despite the huge environmental impact related to the energy production. Data notice that almost a 99.0% of the total global warming potential is mainly due to the electricity required during the electrochemical treatment, being higher by the sono and photo CDEO treatments because of the use of additional devices. Nevertheless, this issue can be overcome by means of using renewable energies as power sources of these remediation treatments. According to results, it can be claimed that the electrochemical technologies may successfully compete with other AOPs in terms of sustainability.

Performance of calves born in different periods of the calving season in intensive beef cattle farming / [Desempenho em pecuária de corte intensiva de progênies nascidas em diferentes períodos da estação de parição]

The objective of this study was to evaluate, for two years, the performance of 124 female and 105 male Braford calves born during the first and second halves of the same calving season and the effects of birth period on the development of males until slaughter, as yearlings, and of females until calving, after having mated at 13-15 months of age. Early-born females were heavier than those born late at weaning (119.3 vs 109.9kg; P<0.05), at the start of the breeding season (275.0 vs 263.0kg; P<0.05), and at the end of the breeding season (300.0 vs 289.5kg; P<0.05), in addition to being more fertile (70 vs 50% pregnancy rate). There was no difference (P>0.05) in the development of males born early in relation to those born late, except for weaning weight, which was higher in the former. Steers born early were ready for slaughter at a younger age (459.6 vs 490.1 days; P<0.05), and both groups (early- and late-born) had a body condition classified as fat (4.21 points). In intensive production systems, both male and female calves perform better if they are born during the first half of the calving season.(AU)

O objetivo deste estudo foi avaliar, por dois anos, o desempenho de 124 bezerras e 105 bezerros Braford nascidos durante a primeira e segunda metades da mesma estação, bem como os efeitos do período de nascimento no desenvolvimento dos machos até o abate e das fêmeas até o primeiro parto, após serem acasalados entre 13/15 meses de idade. As fêmeas nascidas precocemente foram mais pesadas do que as nascidas tardiamente ao desmame quando bezerras (119,3 vs. 109,9kg; P<0,05), no início da estação reprodutiva (275,0 vs. 263,0kg; P<0,05) e no final da estação reprodutiva (300,0 vs. 289,5kg; P<0,05), além de terem maior fertilidade (taxa de prenhez 70 vs. 50%). Não houve diferença (P>0,05) no desenvolvimento de bezerros nascidos precocemente em relação aos nascidos mais tardiamente, exceto no peso ao desmame, com superioridade dos primeiros. Os novilhos nascidos mais cedo ficaram prontos para o abate à idade mais jovem (459,6 vs. 490,1 dias; P<0,05), e ambos os grupos (nascidos precoce e tardiamente) tinham uma condição corporal classificada como gordura (4,21 pontos). Em sistemas de produção intensiva, os bezerros machos e fêmeas nascidos precocemente, na primeira metade da estação de parição, possuem melhor desempenho.(AU)

Strategies for powering electrokinetic soil remediation: A way to optimize performance of the environmental technology.

The electro-kinetic remediation of soils using different powering strategies has been studied, in order to clarify which is the best strategy to couple solar powering with this remediation technology, in a context of developing more sustainable electrochemical remediation technologies. Direct powering from photovoltaic panels (Case a), application of constant electric fields with the same average value of Case a (Case b) and application of constant specific power with the same average value of Case a (Case c) have been compared. Results show an outstanding influence of the powering strategy on the removal efficiency of clopyralid (model of herbicide used in this work). The direct use of solar power profiles obtained the lowest removal efficiencies, which contrasts with the higher expected sustainability of this powering strategy. Reversion of pollutant transport overnight and extreme electric field values at noon help to explain the lower efficiency of this strategy. Evaporation mechanisms are promoted by operating at extreme large electric fields. In addition, harsher conditions lead to a higher negative soil affectation in terms of regions affected by extreme pHs, water contents and/or conductivities and to lower specific pollutant removals. Therefore, maximum efficiencies were found for Case b (constant electric potential gradient) with a total removal over 110 g kWh-1 and only a slight affectation into the final soil properties.

How to avoid the formation of hazardous chlorates and perchlorates during electro-disinfection with diamond anodes?

This work focuses on disinfection of water using electrolysis with diamond coatings avoiding or minimizing the formation of hazardous chlorates and perchlorates using a special type of commercial cells designed by CONDIAS (Itzehoe, Germany) in two different sizes: the CabECO and the MIKROZON cells. In these cells, the electrolyte that separates the anode and cathode is a proton exchange membrane. This helps to minimize the production of perchlorate and this behavior is enhanced in the smallest cell for which the very low contact times between the electrodes and the water allows to avoid the production of perchlorates when operating in a single-pass mode, which becomes a really remarkable point. In this paper, we report tests in which we demonstrate this outstanding performance and we also explain the differences observed in the two cells operating with the same water.

Testing the use of cells equipped with solid polymer electrolytes for electro-disinfection.

This work focuses on disinfection of water using electrolysis with boron doped diamond (BDD) coatings and faces this challenge by comparing the performance of two different cells manufactured by CONDIAS GmbH (Izehoe, Germany): CONDIACELL® ECWP and CabECO cells. They are both equipped with diamond electrodes, but the mechanical design is completely different, varying not only by geometry but also by the flow conditions. ECWP is a flow-through cell with perforated electrodes while the CabECO cell is a zero-gap cell with a proton exchange membrane as a solid polymer electrolyte (SPE) separating the anode and cathode. At 0.02 Ah dm-3 both cells attain around 3-5 logs pathogen removal, but design and sizing parameters give an advantage to the CabECO: it can minimize the production of chlorates and perchlorates when operating in a single-pass mode, which becomes a really remarkable point. In this paper, we report tests in which we demonstrate this outstanding performance and we also explain the differences observed in the two cells operating with the same water.

Storage of energy using a gas-liquid H2/Cl2 fuel cell: A first approach to electrochemically-assisted absorbers.

In this work, the use in fuel cell mode of three electro-absorbers is evaluated for the chloralkaline process and performance is compared with that of a conventional PEMFC operated at the same operation conditions (room temperature). To do this, four cells have been in-house manufactured and compared, in order to determine which electrolyte (solution containing the active species or the membrane) is the best and which is the influence of the absorption stage on the operation of the cell. Because of the high solubility of chlorine, only the hydrogen absorption has been considered in order to evaluate relevant differences in the performance. Results demonstrate that design of the cell has a superb significance on the performances obtained. Cells with membrane-electrode assemblies are more efficient than those in which the membrane is used only as an electrodic compartment separator and utilization of devices which produce tiny bubbles of gas into the electrolyte is also very advantageous in order to obtain higher efficiencies. Results are of a great significance for the design of electro-absorbers and this paper is a first approach to face the design of reversible electrochemical cells for the chloralkaline process.

Clinical risk scores do not accurately identify a very high risk population with diffuse large B cell lymphoma-an analysis of 386 Portuguese patients.

The identification of high-risk patients deserving alternative first-line treatments to R-CHOP is a research priority in diffuse large B cell lymphoma (DLBCL). Despite the increasing recognition of biological features underlying aggressive behavior, clinical scores remain the basis for prognostic evaluation and treatment stratification in DLBCL. We performed a retrospective analysis of patients with DLBCL uniformly treated with immunochemotherapy with the aim of assessing the discriminative power of the NCCN international prognostic index (IPI) and the GELTAMO-IPI scores in risk group stratification and compared them with the IPI. Additionally, we investigated if bulky disease, gender, beta-2 microglobulin (ß2m), body mass index, and B-symptoms have independent prognostic impact. We confirmed the discriminative ability of the three prognostic scores in terms of progression-free survival and overall survival and found that the NCCN-IPI performs better in the identification of a high-risk population compared to the IPI and the GELTAMO scores. In an attempt to improve the prognostic power of the NCCN-IPI we analyzed additional clinical variables. Bulky disease and elevated ß2m were found to be independent predictors of prognosis when controlling for the NCCN-IPI risk groups. However, they seem to bring no incremental power to the latter in the identification of poor outcome patients. We support the use of the NCCN-IPI for the clinical identification of high-risk patients in DLBCL. Future studies to unravel the biological heterogeneity within NCCN-IPI groups are needed to improve risk prediction and design targeted therapies for poor prognosis patients.

Influence of hydraulic retention time and carbon loading rate on the production of algae.

This paper is focused on the assessment of the production of algae in batch bioreactors. Hydraulic retention time, carbon loading rate and light color were the inputs of the study and algae production the main output. Bioreactors were operated in semi-continuous mode and tests lasted two months, more than two times the period required to meet a steady-state response. This steady-state was verified with plateau responses in both, soluble parameters and suspended solids. Results points out the great relevance of temperature. Likewise, they show that green light improves the production of algae, as well as long HRT and high CLR. Maximum production rates attained were in the range 4-14 mg d-1 L-1. The ratio COD /TSS for this biofuel was almost constant (3.13 mg COD mg-1 TSS) but the quality of the product obtained in terms of the Mean Oxidation State of Carbon is completely different. Longer HRT leads to lower MOSC and hence to potentially more valuable fuels.

Pre-disinfection columns to improve the performance of the direct electro-disinfection of highly faecal-polluted surface water.

This work presents the design and evaluation of a new concept of pre-disinfection treatment that is especially suited for highly polluted surface water and is based on the combination of coagulation-flocculation, lamellar sedimentation and filtration into a single-column unit, in which the interconnection between treatments is an important part of the overall process. The new system, the so-called PREDICO (PRE-DIsinfection Column) system, was built with low-cost consumables from hardware stores (in order to promote in-house construction of the system in poor countries) and was tested with a mixture of 20% raw wastewater and 80% surface water (in order to simulate an extremely bad situation). The results confirmed that the PREDICO system helps to avoid fouling in later electro-disinfection processes and attains a remarkable degree of disinfection (3-4 log units), which supplements the removal of pathogens attained by the electrolytic cell (more than 4 log units). The most important sizing parameters for the PREDICO system are the surface loading rate (SLR) and the hydraulic residence time (HRT); SLR values under 20 cm min-1 and HRT values over 13.6 min in the PREDICO system are suitable to warrant efficient performance of the system.

Development of asymmetric resorbable membranes for guided bone and surrounding tissue regeneration.

Membranes design for guided tissue engineering have been studied to aid in cell viability and function as tissue barriers. Two asymmetric resorbable membranes for guided bone regeneration (GBR) were produced: chitosan/pectin/poly-caprolactone (PECm) and poly(vinyl alcohol)/polyethylenimine/poly(ethylene glycol) (PVAm). Both membranes were characterized by physical, chemical, mechanical, degradation rate, and in vitro biological assessment. Scanning electron microscopy (SEM) confirmed the membranes asymmetry, in which PECm asymmetry is given by roughness and chemical composition, while PVAm's only by differences in porosity. Fourier transform infrared spectroscopy (FTIR) identified chemical groups and bonds between polymers. Both sides of PVAm revealed to be hydrophobic, whereas the PECm presented one side with higher hydrophobicity than the other. In vitro biological assessment disclosed that PECm presented a higher cell adhesion growth pattern than PVAm, where it seemed to occur a delay in proliferation due to initial low cell adhesion. Both developed membranes are suitable for GBR, since both membranes fulfil the requirements to be used as a tissue barrier. The PECm has an additional role in cell viability that was not observed in the PVAm. © 2018 Wiley Periodicals, Inc. J Biomed Mater Res Part A: 106A: 2141-2150, 2018.

Reflexiones sobre la neurotoxicidad inducida por opioides en el contexto de una anestesia general en población pediátrica / Opioid related neurotoxicity on pediatric population after general anestesia

Introducción: Desde el año 2000 vienen apareciendo en distintas publicaciones científicas los resultados de numerosos estudios experimentales realizados en animales, evaluando el impacto neurotóxico que sobre sus cerebros tenía la exposición a combinaciones de anestésicos de uso habitual. Se constata que la exposición en periodo de máxima sinaptogénesis conlleva una apoptosis neural diseminada. Comienzan entonces a preocuparse los anestesiólogos que trabajan con niños, pues quizás ese daño neuronal también pudiera acontecer a la población pediátrica. Así, son varios los estudios que están en marcha desde hace años valorando el desarrollo neurocognitivo de cohortes de niños que se sometieron a anestesias generales en edades tempranas de sus vidas. En este sentido, la necesidad de medir un daño cerebral agudo nos anima a utilizar marcadores que han demostrado su asociación con dicho deterioro cerebral en diferentes situaciones clínicas como la hipoxia perinatal, la parada cardiorrespiratoria o el traumatismo craneoencefálico. Objetivos: Planteamos este trabajo con el objetivo de determinar si la proteína S100B podría comportarse como un biomarcador de daño cerebral agudo postanestésico y si pudiéramos establecer asociación entre la elevación de este marcador en sangre y alguno de los fármacos anestésicos utilizados habitualmente. Metodología: Determinación sanguínea de la proteína S100B en 76 pacientes pediátricos intervenidos de hipertrofia amigdalar bajo anestesia general, antes y después de la cirugía Conclusión: Tras analizar los resultados podemos concluir que existe una elevación estadísticamente significativa entre los niveles de proteína S100B antes y después de la exposición anestésica. En segundo lugar, podemos establecer una correlación positiva, también con significación estadística, entre el fentanilo administrado y la elevación de dicha proteína al final del acto anestésico (AU)

Introduction: In the last decade many scietific publications bring out the results of experimental studies about the neurotoxic impact of an anesthetic expossure in animal´s brain. It is confirm that when this expossure occurs in a maximum synaptogenesis period of the animal´s live a widespread neuroapoptosis befall. From there on all the pediatrics anesthesiologist warried about if this damage could also affect the pediatric population. Nowadays there are several observational studies exploring the neurobehavioral conduct of many children who underwent general anesthesia early in their lives. Objetive: As a results of this we propose to use actual neuronal damage biomarkes, wich have demonstrated association between brain damage and perinatal hypoxia, or cardiac arrest or mild brain injury. When we planned this essay we intend to determine if S100B protein could work as an accute postanesthetic expossure neuronal damage biomarker, and if there would be any relationship between the biomarker elevation and any of the drugs commonly use for anesthesia. Metodology: In order to determinate the S100B protein serum level is, we obtained a blood sample before and after general anaesthesia expousure in 76 paediatric patient undergoing amigdalar hypertropy surgery. Conclusions: Once we analized our results we can coclude that an elevation of the blood levels of S100B protein occurs after anesthesia. We have also found a possitive correlation between the total amount of fentanyl administred and the higher level of this protein concentration at the end of the anesthetic expossure (AU)

Influence of the fuel and dosage on the performance of double-compartment microbial fuel cells.

This manuscript focuses on the evaluation of the use of different types and dosages of fuels in the performance of double-compartment microbial fuel cell equipped with carbon felt electrodes and cationic membrane. Five types of fuels (ethanol, glycerol, acetate, propionate and fructose) have been tested for the same organic load (5,000 mg L(-1) measured as COD) and for one of them (acetate), the range of dosages between 500 and 20,000 mg L(-1) of COD was also studied. Results demonstrate that production of electricity depends strongly on the fuel used. Carboxylic acids are much more efficient than alcohols or fructose for the same organic load and within the range 500-5,000 mg L(-1) of acetate the production of electricity increases linearly with the amount of acetate fed but over these concentrations a change in the population composition may explain a worse performance.

Long-term effects of the transient COD concentration on the performance of microbial fuel cells.

In this work, the long-term effects of transient chemical oxygen demands (COD) concentrations over the performance of a microbial fuel cell were studied. From the obtained results, it was observed that the repetitive change in the COD loading rate during 12 h conditioned the behavior of the system during periods of up to 7 days. The main modifications were the enhancement of the COD consumption rate and the exerted current. These enhancements yielded increasing Coulombic efficiencies (CEs) when working with COD concentrations of 300 mg/L, but constant CEs when working with COD concentrations from 900 to 1800 mg/L. This effect could be explained by the higher affinity for the substrate of Geobacter than that of the nonelectrogenic organisms such as Clostridia. © 2016 American Institute of Chemical Engineers Biotechnol. Prog., 32:883-890, 2016.

Bioelectro-Claus processes using MFC technology: Influence of co-substrate.

This work is focused on the removal of sulphide from wastewater using a two chamber microbial fuel cell, seeded with activated sludge and operated in semi-continuous mode. Two co-substrates were used in order to provide the system for carbon and nutrient source: actual urban wastewater and synthetic wastewater. Results show that sulphide is efficiency depleted (removals over 94%) and that electricity is efficiently produced (maximum power density is 150 mW m(-2)) meanwhile COD is also oxidised (removals higher than 60%). Sulphur and sulphate are obtained as the final products of the oxidation and final speciation depends on the type of co-substrate used. The start-up of the system is very rapid and production of electricity and polarisation curves do not depend on the co-substrate.