1.
Chem Commun (Camb)
; 53(52): 7076-7079, 2017 Jun 27.
Article
in English
| MEDLINE
| ID: mdl-28627534
ABSTRACT
We report a {Cu16} embedded within a {W44} cluster containing four cubane-like [Cu4O4] units within an isopolyoxotungstate (isoPOT) in a {Na4Cu4[(H2W11O38) (CH3COO)(OH)3]}4·88H2O (1) and a polyanion Cu-linked {W11} chain Na6Cu2[(H2W11O38)(CH3COO)(OH)]·26H2O (2). Electronically, the redox properties show that both compounds 1 and 2 undergo irreversible reductions resulting in the demetalation of the compounds, whilst the magnetic behavior of 1 and 2 shows a weak antiferromagnetic and a stronger ferromagnetic coupling, respectively.
2.
Angew Chem Int Ed Engl
; 51(9): 2115-8, 2012 Feb 27.
Article
in English
| MEDLINE
| ID: mdl-22298462
3.
Angew Chem Int Ed Engl
; 50(39): 9154-7, 2011 Sep 19.
Article
in English
| MEDLINE
| ID: mdl-21919149