Reduction and adsorption of uranium(VI) from aqueous solutions using nanoscale zero-valent manganese.

Nano zero-valent manganese (nZVMn) is theoretically expected to exhibit high reducibility and adsorption capacity, yet its feasibility, performance, and mechanism for reducing and adsorbing hexavalent uranium (U(VI)) from wastewater remain unclear. In this study, nZVMn was prepared via borohydride reduction, and its behaviors about reduction and adsorption of U(VI), as well as the underlying mechanism, were investigated. Results indicated that nZVMn exhibited a maximum U(VI) adsorption capacity of 625.3 mg/g at a pH of 6 and an adsorbent dosage of 1 g/L, and the co-existing ions (K+, Na+, Mg2+, Cd2+, Pb2+, Tl+, Cl-) at studied range had little interference on U(VI) adsorption. Furthermore, nZVMn effectively removed U(VI) from rare-earth ore leachate at a dosage of 1.5 g/L, resulting in a U(VI) concentration of lower than 0.017 mg/L in the effluent. Comparative tests demonstrated the superiority of nZVMn over other manganese oxides (Mn2O3 and Mn3O4). Characterization analyses, including X-ray diffraction and depth profiling X-ray photoelectron spectroscopy, combined with density functional theory calculation revealed that the reaction mechanism of U(VI) using nZVMn involved reduction, surface complexation, hydrolysis precipitation, and electrostatic attraction. This study provides a new alternative for efficient removal of U(VI) from wastewater and improves the understanding of the interaction between nZVMn and U(VI).

Thallium removal from wastewater using sulfidized zero-valent manganese: Effects of sulfidation method and liquid nitrogen pretreatment.

Zero-valent manganese (ZVMn) possesses high reducibility in theory, while sulfide exhibits strong affinity towards a variety of heavy metals owing to the low solubility of metal sulfides. Yet the performance and mechanisms on using sulfidized zero-valent manganese (SZVMn) to remove thallium (Tl) from wastewater still remain unclear. In this study, the performance of Tl(I) removal using SZVMn synthesized by borohydrides reduction followed by sulfides modification, with and without liquid nitrogen treatment, was compared and the mechanism behind was investigated. The results show that at a S/Mn molar ratio of 1.0, liquid nitrogen modified SZVMn (LSZVMn) possessed more interior channels and pores than SZVMn, with 65.3% higher specific surface area and 73.7% higher porosity, leading to 6.4-8.1% improvement in adsorption of Tl(I) at pH 4-10. LSZVMn showed effectiveness and robustness in Tl(I) removal in the presence of co-existing ions up to 0.1 M. The adsorption of Tl(I) conformed to the pseudo-1st-order kinetic model, and followed the Langmuir isothermal model, with the maximum Tl adsorption capacity of 264.9 mg·g-1 at 288 K. The mechanism of Tl(I) removal with SZVMn was found to include sulfidation-induced precipitation, manganese reduction, surface complexation, and electrostatic attraction. The liquid nitrogen pretreatment embrittled and cracked the outer shell of S/Mn compounds, resulted in a highly hierarchical structure, enhancing the manganese reduction and improving the Tl(I) removal. Based on the above results, the SZVMn and its liquid nitrogen-modified derivatives are novel and effective environmental materials for Tl(I) removal from wastewater, and the application of SZVMn to the removal of other pollutants merits investigation in future study.

Oil/water separation using elastic bio-aerogels derived from bagasse: Role of fabrication steps.

Bio-aerogels hold great promise for selective oil separation from water due to their light weight and high sustainability. However, how the fabrication methods impact the elasticity and oil sorption performance of bio-aerogels still needs systematic comparison and in-depth investigation. In this study, the fabrication of hydrophobic bio-aerogels with good elasticity and reusability was optimized using a factorial design based on the dosages of bagasse-derived cellulose nanofiber, sodium alginate, and calcium carbonate. The role of each key fabrication step, including ice-templating, calcium crosslinking, solvent dehydration, freeze-drying, and silanization, played in the material properties was also elucidated. The optimized bio-aerogels had a low density (7.55 mg/cm3), high porosity (99.47%), large specific surface area (39 m2/g), and strong hydrophobicity (water contact angle of 135°). In addition, the bio-aerogels exhibited outstanding selective oil separation ability towards the oil-water mixture, with oil sorption capacity of 89-126 times its weight. The in-situ calcium crosslinking and solvent dehydration were vital to create porosity and preserve the microstructure of the bio-aerogels. The chemical vapor deposition rendered the bio-aerogels hydrophobic and oleophilic, greatly enhancing the separability of oil from the water-oil mixture.

Potential application of Fusarium fungal strains (Fusarium sp. FP, Arthrinium sp. FB, and Phoma sp. FR) for removal of Tl (I) ions from water.

Water pollution caused by heavy metals poses a serious threat to the ecosystem and human health. Among the various treatment techniques for water remediation, adsorption is an efficient method due to its high capacity, low cost, and simplicity. Thallium (Tl) is highly toxic to mammals and its removal from water is gaining increasingly prominent attention. In this study, three fungal strains (Fusarium sp. FP, Arthrinium sp. FB, and Phoma sp. FR) were tested for removal of Tl (I) from aqueous solutions and showed excellent removal performance. The prepared inactive fungal strains were characterized by XRD, FT-IR, SEM, and XPS analyses. The effects of pH, contact time, biomass dosage, and reaction temperature on the removal efficiency of Tl (I) were systematically investigated. The results indicated that the adsorption isotherm data fit well with the Langmuir model, and the pseudo-second-order model was more consistent with the kinetic data description. The maximum adsorption capacity of the fungal strain (Fusarium sp. FP, Arthrinium sp. FB, and Phoma sp. FR) for Tl (I) was found to be 94.69 mg/g, 66.97 mg/g, and 52.98 mg/g, respectively. The thermodynamic data showed that the sorption process was spontaneous and endothermic. The present study showed that the inactive fungal strains could be a promising adsorbent material for Tl (I) removal.

Multi-step purification of electrolytic manganese residue leachate using hydroxide sedimentation, struvite precipitation, chlorination and coagulation: Advanced removal of manganese, ammonium, and phosphate.

Water pollution caused by the release of manganese (Mn2+) and ammonia nitrogen (NH4+-N) from electrolytic manganese residue (EMR) generated from industrial activities poses a serious threat to ecosystems and human health. In this study, an integrated process consisting sequentially of hydroxide sedimentation, struvite precipitation, breakpoint chlorination, and ferric chloride coagulation was optimized to remove Mn2+ and NH4+-N from EMR leachate, and to address the issue of residual orthophosphate caused by struvite precipitation. The precipitates were characterized using X-ray diffraction, scanning electron microscopy, and thermogravimetric analyses. Results show that Mn2+ ions and the resulting chemical oxygen demand (COD) were mainly removed using hydroxide precipitation at a sedimentation pH of 10.2, with poor-crystalline manganese hydroxide as the main precipitate. NH4+-N was primarily removed and recovered using struvite precipitation with well crystalline struvite as the main product, and then further eliminated using breakpoint chlorination. The residual orthophosphate introduced by struvite precipitation is successfully removed with ferric coagulation, and the effluent pH (7.5) is also lowered to discharge limits by means of hydrolysis of ferric coagulant. The concentration of COD, Mn2+, NH4+-N, and orthophosphate concentrations in the final effluent were 30.52 ± 9.38, 0.026 ± 0.013, 0.87 ± 0.01, and 0.06 ± 0.002 mg/L, respectively, meeting all local discharge standards. This combined process has robust pollutant removal efficiency, high resource recovery potential and few environmental constraints; thus, it is recommended as a potential solution for the treatment of Mn2+- and NH4+-N-rich acid mine drainage.

Characterization of cadmium biosorption by inactive biomass of two cadmium-tolerant endophytic bacteria Microbacterium sp. D2-2 and Bacillus sp. C9-3.

In this study, two cadmium-tolerant endophytic bacteria (Microbacterium sp. D2-2 and Bacillus sp. C9-3) were employed as biosorbents to remove Cd(II) from aqueous solutions. The influence of initial pH, initial Cd(II) concentration, adsorbent biomass, temperature and contact time on Cd(II) removal were investigated. Results showed that the Langmuir isotherms were found to best fit the equilibrium data, and the maximum biosorption capacities were found to be 222.22 and 163.93 mg/g at a solution pH of 5.0 for Microbacterium sp. D2-2 and Bacillus sp. C9-3, respectively. The biosorption kinetics followed well pseudo-second-order kinetics. Fourier transform infrared spectroscopic analysis suggested that the hydroxyl, carboxyl, carbonyl and amino groups on Microbacterium sp. D2-2 and Bacillus sp. C9-3 biomass were the main binding sites for Cd(II). The results presented in this study showed that Microbacterium sp. D2-2 and Bacillus sp. C9-3 are potential and promising adsorbents for the effective removal of Cd(II) from aqueous solutions.

Highly efficient removal of thallium(I) from wastewater via hypochlorite catalytic oxidation coupled with adsorption by hydrochar coated nickel ferrite composite.

In this study, tannery wastewater was used as carbon source to hydrothermally synthesize magnetic carbon-coated nickel ferrite composite (NiFe2O4@C), which was employed as a catalyst for thallium (Tl) oxidation by hypochlorite and simultaneously as an adsorbent for Tl removal from wastewater. Compared with NiFe2O4@C adsorption or hypochlorite oxidation alone, the combination of NiFe2O4@C and hypochlorite substantially enhanced the rate and efficiency of Tl(I) removal. In addition, this process was highly effective for Tl(I) removal over a wide pH range (6-12). The maximum Tl(I) removal capacity was 1699 mg/g at pH 10, which is the highest one reported so far. Electron spin resonance spectra suggested the formation of hypochlorite-based free radicals induced by the NiFe2O4@C composite, which enhanced the Tl(I) oxidation and removal. Oxidation-induced surface precipitation and surface complexation were found to be the main Tl(I) removal mechanisms. Consecutive cyclic regeneration tests implied robust regeneration and reuse performance of the composite. Moreover, it was effective for Tl(I) removal from real industrial wastewater. Therefore, the hypochlorite catalytic oxidation coupled with adsorption by the magnetic NiFe2O4@C composite is a promising technique for Tl(I) removal from wastewater. This hybrid process also has great potential for the removal of other pollutants.

Zero-valent iron-manganese bimetallic nanocomposites catalyze hypochlorite for enhanced thallium(I) oxidation and removal from wastewater: Materials characterization, process optimization and removal mechanisms.

Nano zero-valent metals adsorption coupled with advanced oxidation for environmental pollutants removal has been gaining attention recently. In this study, zero-valent iron-manganese (nZVIM) bimetallic nanocomposites were prepared via one-pot borohydride reduction and coupled with hypochlorite (ClO-) oxidation for enhanced thallium (Tl) removal from wastewater. Amorphous nZVIM nanoparticles were successfully synthesized, with a specific surface area of 106.89 m2/g, and a saturation magnetization of 65.16 emu/g. In comparison with the nZVIM adsorption or ClO- oxidation alone, the hybrid nZVIM/ClO- process achieved much faster Tl(I) removal rate over a wide pH range from 6 to 10. Maximum Tl(I) removal capacity was as high as 990.0 mg/g. The oxidation-induced adsorption for Tl(I) removal well followed the pseudo-first kinetic order model. Stable and effective adsorbent regeneration was achieved during the cyclic adsorption-desorption tests. This process also had high resistance to the interference of external cations, can act as an effective pretreatment for Tl(I) removal from the actual saline industrial wastewater. The main mechanisms for Tl(I) removal were found to be oxidation, surface precipitation, pore retention, and surface complexation. The nZVIM coupled with ClO- approach has great potential for Tl(I) removal from wastewater, and its application in other fields is highly anticipated.

Carbon quantum dots derived from the extracellular polymeric substance of anaerobic ammonium oxidation granular sludge for detection of trace Mn(vii) and Cr(vi).

Carbon quantum dots (CQDs) were synthesized via a hydrothermal method, in which extracellular polymeric substance (EPS) from anaerobic ammonium oxidation (anammox) granular sludge was used as a carbon precursor, while citric acid and ethylenediamine were applied as auxiliary carbon source and passivation agent, respectively. The synthesized CQDs, with orderly spherical shape and mean size of 7.15 nm, emitted blue fluorescent light under UV radiation of 365 nm. The CQDs had a high fluorescence yield (40.84%), with good water solubility and excellent spectroscopic properties. In addition, the CQDs exhibited selective, sensitive and distinctive fluorescence quenching behaviors for Cr(vi) and Mn(vii) in a PBS buffer solution (NaH2PO4-Na2HPO4) of pH 7, with a detection limit of 5.8 nM for Cr(vi) and 2.3 nM for Mn(vii). Owing to the nitrogen components from the EPS of anammox granules, the CQDs were well nitrogen-doped, promoting electron-transfer and leading to reduction between the CQDs and Mn(vii)/Cr(vi). These results indicate that CQD-based chemical sensing is a simple and efficient means for the fluorescence detection of Mn(vii) and Cr(vi).

Enhanced thallium(I) removal from wastewater using hypochlorite oxidation coupled with magnetite-based biochar adsorption.

The development of efficient and regenerable adsorbent coupled with advanced oxidation for enhanced thallium (Tl) removal has been a recent focus on wastewater treatment. In this study, a magnetite-based biochar derived from watermelon rinds was synthesized and used as a sustainable adsorbent and catalyst for hypochlorite oxidation and removal of Tl(I) from wastewater. The addition of hypochlorite substantially enhanced the Tl(I) removal under normal pH range (6-9). Maximum Tl adsorption capacity of 1123 mg/g was achieved, which is 12.3% higher than the highest value previously reported. The magnetic biochar can be regenerated using 0.1 mol/L HNO3 solution for elution in only 5 min, with a Tl desorption efficiency of 78.9%. The Tl removal efficiency was constantly higher than 98.5% during five consecutive recycle tests, indicating the effective reuse performance of the adsorbent. Oxidation, surface precipitation, pore retention and surface complexation were the main mechanisms for Tl(I) removal. The re-dissolution of Tl compounds and ion exchange of Tl cations with proton were the main mechanisms for adsorbent regeneration. Given the fast oxidation rate, high adsorption capacity, steady reusability and facile separability, this magnetic biochar-hypochlorite technique is a promising means for Tl(I) removal from wastewater. The catalytic hypochlorite oxidation induced by the magnetic biochar has also great potential to the effective removal of other pollutants.

Preparation of novel aminated chitosan schiff's base derivative for the removal of methyl orange dye from aqueous environment and its biological applications.

A novel, eco-friendly aminated chitosan Schiff's base (ACSSB@ZnO) was developed and utilized to remove MO from aqueous environment. The impact of different significant parameters, for example, pH (3-11), adsorbent dose (0.1-0.6 g), contact time (0-120 min), and temperature (303-323 K) have been explored by batch process. Kinetic data was illustrated by pseudo-second-order model and the isotherms fitted well with Langmuir isotherm model. The highest sorption capacity of ACSSB@ZnO was observed to be 111.11 mg/g at 323 K. Positive enthalpy and entropy values demonstrated that the MO adsorption procedure was an endothermic. Negative Gibbs free energy values implied the spontaneous nature of the adsorption system. Moreover, reusability experiments were studied and it can be regenerated by using NaOH as effluent.

Synthesis of manganese dioxide with different morphologies for thallium removal from wastewater.

Manganese dioxide (MnO2) with different morphologies (tube-, wire-, rod-, and flower-like) was synthesized via hydrothermal method and then applied for thallium (Tl) removal from wastewater. During material synthesis, short reaction time (6 h) and low temperature (110 °C) were prone to form polycrystalline flower-like birnessite type MnO2, while long reaction time (24 h) and high temperature (240 °C) were inclined to produce polycrystalline wire-like birnessite type MnO2. Moderate reaction time (12 h) with low temperature at 120 °C/140 °C led to formation of mono-crystalline rod- and tube-like α-MnO2, respectively. Wire-like MnO2 was the most effective adsorbent for Tl(I) removal from both the synthetic and industrial wastewaters. The MnO2 of four morphologies exhibited similarly high Tl(III) removal owing to the precipitation of Tl(III) as Tl2O3. Effective Tl(I)/Tl(III) removal (99%) was achieved with wire-like MnO2 at an initial pH of 6 and an adsorbent dosage of 0.25 g/L. The Tl(I)/Tl(III) adsorption can be described with the pseudo-second-order kinetic. The Tl(I) removal was best fitted with the Freundlich model, with a maximum adsorption capacity of 450 mg/g. While the Tl(III) removal was best fitted with the Langmuir model, with an extremely high capacity of 6250 mg/g. Based on the results from XRD, SEM-EDS, FT-IR, and XPS analyses, the mechanisms of Tl removal using wire-like MnO2 are primarily surface complexation and oxidative precipitation. Overall, wire-like MnO2 is a highly effective adsorbent for Tl removal from both synthetic and actual wastewaters.

Accelerated phosphorus recovery from aqueous solution onto decorated sewage sludge carbon.

In search of efficient phosphorus resource recovery and pollution remediation should be highly concerned due to the view of phosphorus nonrenewable and eutrophication. This work presented a new insight into conversion of sewage sludge into favorable carbonaceous adsorbent for accelerated removing and recovering phosphorus from aqueous solution, what addressed the issues of phosphorus recovery and pollution remediation as well as sludge disposal. Ca and water hyacinth were evolved to decorate sludge derived carbon. Effect of mass ratio of sludge, water hyacinth and calcium carbonate on the morphologies and adsorption kinetics was investigated. The adsorbents (SW-Ca-112) resulted from sludge in the presence of water hyacinth and CaCO3 in a mass ratio of 1:1:2 had the highest adsorption capacity of 49.50 mg/g P and adsorption rate. Decoration of Ca favored adsorption ability and the presence of water hyacinth accelerated the adsorption rate due to the enhanced porosity. Formation of acicular Ca5(PO4)3OH nanoparticles contributed to the favorable adsorption process. Thus, the contribution of decorated Ca and water hyacinth to the adsorption ability and rate to phosphorus was understand, providing important information on resource utilization of sewage sludge as efficient adsorbent for immobilizing phosphorus from aqueous solution.

Effective adsorption of nickel (II) with Ulva lactuca dried biomass: isotherms, kinetics and mechanisms.

This study aimed to evaluate the Ni2+ ions adsorption capability of Ulva lactuca. The isotherms, kinetics and mechanisms for the adsorption of Ni2+ from aqueous solution by Ulva lactuca were also investigated. Influencing factors including initial pH, initial Ni2+ concentration, biomass, contact time were examined. The results indicate that the maximum Ni2+ adsorption capacity of 38.28 mg/g was obtained at pH 5, initial Ni2+ concentration 250 mg/L, biomass dosage 0.5 g/L and contact time 30 min. The adsorption can be well fitted with Langmuir isotherm, and the kinetics were well described by the pseudo-second-order model. The parameters of thermodynamics verified that Ni2+ adsorption on Ulva lactuca was a spontaneous and endothermic process. Analyses of FT-IR, SEM-EDS and XPS indicate that carboxyl and hydroxyl groups on the surface of biomass are involved in Ni2+ adsorption. The dried biomass of Ulva lactuca can be a cost-effective and eco-friendly adsorbent for the removal of Ni2+ from wastewater.

Enhanced plasmon-driven photoelectrocatalytic methanol oxidation on Au decorated α-Fe2O3 nanotube arrays.

Highly ordered, porous α-Fe2O3/Au nanotube arrays (NTAs) were successfully synthesized through a facile approach. Benefitting from the plasmonic effect, and unique aligned and porous structural features, the α-Fe2O3/Au NTAs offer efficient and stable operation and exhibit a significantly enhanced catalytic activity for photoelectrochemical methanol oxidation with a faradaic efficiency of 79.23%.

Synthesis of FC-supported Fe through a carbothermal process for immobilizing uranium.

The abundant generation of uranium (U), a radioactive nuclide, engenders a severe hazard to the environment. Iron based materials were used to immobilize U from water, however, the immobilization is limited by the agglomeration of nanoparticle Fe. In this study, a novel carbothermal process was proposed to synthesize flour carbon (FC) supported nano-flake Fe (Fe-FC). Scanning electron microscopy (SEM) and nitrogen isotherm adsorption-desorption analysis were conducted to characterize Fe-FC. The immobilization characteristics were investigated through batch sorption experiments. Results indicated that nano-flake was appropriately dispersed on the surface. The sorption capacity reached 19.12 mg/g when the initial concentration of U and the dosage of Fe-FC were 20 mg/L and 1 g/L, respectively. Langmuir isotherm sorption and pseudo-second-order models were fitted well to sorption experimental data. The sorption mechanism is ascribed to surface chemisorptions between U(VI) and Fe-FC. Subsequently, X-ray diffraction (XRD) analysis validated that formation of Fe2UO3 contributed to the favorable immobilization of U and that Fe2UO3 was the fate of U.

Shape-dependent adsorption of CeO2 nanostructures for superior organic dye removal.

Highly efficient removal of dye pollutants from water resources remains a great challenge. Herein, we demonstrate a new approach for the efficient removal of anionic organic dyes from wastewater using shape-dependent CeO2 nanostructures. It was found that the volume stoichiometry ratio of ethanol to water (EtOH/H2O) was a key factor affecting the CeO2 nanostructures. Accordingly, the adsorption capacity of the spindle CeO2 nanostructure for Congo red reached 162.4 mg g-1, which is much higher than that of octahedral and spherical CeO2 or other adsorbents previously reported. The superior adsorption performance may be mainly attributed to the peculiar structure and presence of electrostatic interactions between the sample surface and dye molecules. This finding will provide new avenues for using promising adsorbent materials for dye removal in water treatments.

Adsorption of phosphorus by calcium-flour biochar: Isotherm, kinetic and transformation studies.

Discharging phosphorus (P)-contaminated water directly into the aquatic environment leads to resource loss and eutrophication. Thus, removing P from waste streams is imperative. In this study, calcium-decorated biochar (Ca-BC) in different mass ratios of Ca to BC was designed to effectively adsorb P from solution. Ca-BC was characterized through X-ray diffraction (XRD) analysis, followed by isotherm and kinetic adsorption experiments. The decorated Ca on the BC surface was found to have preferred P adsorption ability. A design of calcium hydroxide (Ca(OH)2) to flour in a mass ratio of 2:1 was found to have a maximum adsorption capacity of 314.22 mg g-1 for P. The Langmuir and pseudo-second-order models fit the sorption process adequately. XRD analysis indicated that the preferable adsorption ability to P was due to the reaction of Ca(OH)2 and PO43-, forming the hydroxylapatite (Ca5(PO4)3(OH)) crystal. The P in solution was transformed to the crystal. Thus, Ca-BC is an environmental friendly and low-cost sorbent for P removal.

Nano-rod Ca-decorated sludge derived carbon for removal of phosphorus.

Recovering phosphorus (P) from waste streams takes the unique advantage in simultaneously addressing the crisis of eutrophication and the shortage of P resource. A novel calcium decorated sludge carbon (Ca-SC) was developed from dyeing industry wastewater treatment sludge by decorating calcium (Ca) to effectively adsorb phosphorus from solution. The X-ray diffraction (XRD) and Fourier transform infrared (FTIR) techniques were used to characterize the Ca-SCs, followed by isotherm and kinetic sorption experiments. A preferred design with CaCO3 to sludge mass ratio of 1:2 was found to have a sorption capacity of 116.82 mg/g for phosphorus. This work reveals the crucial role of well-dispersed nano-rod calcium on the Ca-SC surface for the sorption of phosphorus. Moreover, the decoration of nano-rod calcium was found to further promote the uptake of phosphorus through the formation of hydroxylapatite (Ca5(PO4)3(OH)). Thus, the development of decorated Ca-SC for sorption of phosphorus is very important in solving the P pollution and resource loss.

Fractional distribution of thallium in paddy soil and its bioavailability to rice.

To investigate the bioavailability of thallium (Tl) in soil and rice in a Tl-contaminated area in Guangdong, China, the topsoil and rice samples were collected from 24 sampling sites and analyzed. Moreover, a modified sequential extraction procedure was applied to determine the different Tl fractions in the soil. The mean pH value of the soil samples was 4.50. The total Tl concentration in the paddy soil was about 4-8 times higher than the Canadian guideline value (1mgkg-1) for agricultural land uses. The mean ecological risk index of Tl was determined to be 483, indicating that potential hazard of the paddy soil was serious. The mean content of Tl in rice was 1.42mgkg-1, which exceeded the German maximum permissible level (0.5mgkg-1) of Tl in foods and feedstuffs by a factor of nearly 3. The hazard quotient value via rice intake was 57.6, indicating a high potential health risk to the local residents. The distribution of various Tl fractions followed the order of easily reducible fraction (40.3%) > acid exchangeable fraction (30.5%) > residual fraction (23.8%) > oxidizable fraction (5.4%). Correlation analyses showed that the easily reducible fraction correlates positively with the soil Fe and Mn contents, whereas the acid exchangeable fraction is significantly correlated with the S content. The soil pH was negatively correlated with the Tl content in both soil and rice. The Tl content in rice was more strongly correlated with the exchangeable fraction than the total Tl content in the soil. Overall, the bioavailability of Tl in more acidic soil is higher, and is strongly dependent on the speciation of Tl, especially the content of acid exchangeable fraction.