ABSTRACT
In situ formation of carbon dots on halloysite nanotubes is demonstrated by treating polyacrylamide-grafted halloysite nanotubes with polycarboxylic acid without the recourse to extremely high temperatures or solvents. Thermosensitive luminescence and phosphorescence properties are carefully investigated. The polyacrylamide-grafted halloysite nanotubes are further processed as composite films for encryptable thermal printing.
ABSTRACT
Maleimide-functionalized HNTs (HNTs-I) were prepared and explored as a nanophotoinitiator. Vinyl monomers can be grafted onto the nanotubes following a spatially controllable, metal-free and non-contact photoinitiated approach. The obtained HNTs-I were further used in a 3D printing system to fabricate hydrogels with designed configurations.