Theory of director fluctuations about a hedgehog defect in a nematic drop.

We present calculations of eigenmode energies and wave functions of both azimuthal and polar distortions of the nematic director relative to a radial hedgehog trapped in a spherical drop with a smaller concentric spherical droplet at its core. All surfaces interior to the drop have perpendicular (homeotropic) boundary conditions. We also calculate director correlation functions and their relaxation times. Of particular interest is a critical mode whose energy, with fixed Frank constants, vanishes as the ratio µ=R_{2}/R_{1} increases toward a critical value µ_{c}, where R_{2} is the radius of the drop and R_{1} that of the inner droplet, and then becomes negative for µ>µ_{c}. Our calculations form a basis for interpreting experimental measurements of director fluctuations relative to a radial hedgehog state in a spherical drop. We compare results with those obtained by previous investigations, which use a calculational approach different from ours, and with our experimental observations.

Multifunctional twisted kagome lattices: Tuning by pruning mechanical metamaterials.

This article investigates phonons and elastic response in randomly diluted lattices constructed by combining (via the addition of next-nearest bonds) a twisted kagome lattice, with bulk modulus B=0 and shear modulus G>0, with either a generalized untwisted kagome lattice with B>0 and G>0 or with a honeycomb lattice with B>0 and G=0. These lattices exhibit jamming-like critical endpoints at which B, G, or both B and G jump discontinuously from zero while the remaining moduli (if any) begin to grow continuously from zero. Pairs of these jamming points are joined by lines of continuous rigidity percolation transitions at which both B and G begin to grow continuously from zero. The Poisson ratio and G/B can be continuously tuned throughout their physical range via random dilution in a manner analogous to "tuning by pruning" in random jammed lattices. These lattices can be produced with modern techniques, such as three-dimensional printing, for constructing metamaterials.

Signatures of Topological Phonons in Superisostatic Lattices.

Soft topological surface phonons in idealized ball-and-spring lattices with coordination number z=2d in d dimensions become finite-frequency surface phonons in physically realizable superisostatic lattices with z>2d. We study these finite-frequency modes in model lattices with added next-nearest-neighbor springs or bending forces at nodes with an eye to signatures of the topological surface modes that are retained in the physical lattices. Our results apply to metamaterial lattices, prepared with modern printing techniques, that closely approach isostaticity.

Jamming as a Multicritical Point.

The discontinuous jump in the bulk modulus B at the jamming transition is a consequence of the formation of a critical contact network of spheres that resists compression. We introduce lattice models with underlying undercoordinated compression-resistant spring lattices to which next-nearest-neighbor springs can be added. In these models, the jamming transition emerges as a kind of multicritical point terminating a line of rigidity-percolation transitions. Replacing the undercoordinated lattices with the critical network at jamming yields a faithful description of jamming and its relation to rigidity percolation.

Topological Phonons and Weyl Lines in Three Dimensions.

Topological mechanics and phononics have recently emerged as an exciting field of study. Here we introduce and study generalizations of the three-dimensional pyrochlore lattice that have topologically protected edge states and Weyl lines in their bulk phonon spectra, which lead to zero surface modes that flip from one edge to the opposite as a function of surface wave number.

Topological boundary modes in jammed matter.

Granular matter at the jamming transition is poised on the brink of mechanical stability, and hence it is possible that these random systems have topologically protected surface phonons. Studying two model systems for jammed matter, we find states that exhibit distinct mechanical topological classes, protected surface modes, and ubiquitous Weyl points. The detailed statistics of the boundary modes shed surprising light on the properties of the jamming critical point and help inform a common theoretical description of the detailed features of the transition.

Dynamics of ordered colloidal particle monolayers at nematic liquid crystal interfaces.

We prepare two-dimensional crystalline packings of colloidal particles on surfaces of the nematic liquid crystal (NLC) 5CB, and we investigate the diffusion and vibrational phonon modes of these particles using video microscopy. Short-time particle diffusion at the air-NLC interface is well described by a Stokes-Einstein model with viscosity similar to that of 5CB. Crystal phonon modes, measured by particle displacement covariance techniques, are demonstrated to depend on the elastic constants of 5CB through interparticle forces produced by LC defects that extend from the interface into the underlying bulk material. The displacement correlations permit characterization of transverse and longitudinal sound velocities of the crystal packings, as well as the particle interactions produced by the LC defects. All behaviors are studied in the nematic phase as a function of increasing temperature up to the nematic-isotropic transition.

Mechanical Weyl Modes in Topological Maxwell Lattices.

We show that two-dimensional mechanical lattices can generically display topologically protected bulk zero-energy phonon modes at isolated points in the Brillouin zone, analogs of massless fermion modes of Weyl semimetals. We focus on deformed square lattices as the simplest Maxwell lattices, characterized by equal numbers of constraints and degrees of freedom, with this property. The Weyl points appear at the origin of the Brillouin zone along directions with vanishing sound speed and move away to the zone edge (or return to the origin) where they annihilate. Our results suggest a design strategy for topological metamaterials with bulk low-frequency acoustic modes and elastic instabilities at a particular, tunable finite wave vector.

Elasticity of randomly diluted honeycomb and diamond lattices with bending forces.

We use numerical simulations and an effective-medium theory to study the rigidity percolation transition of the honeycomb and diamond lattices when weak bond-bending forces are included. We use a rotationally invariant bond-bending potential, which, in contrast to the Keating potential, does not involve any stretching. As a result, the bulk modulus does not depend on the bending stiffness κ. We obtain scaling functions for the behavior of some elastic moduli in the limits of small ΔP = 1-P, and small δP = P-Pc, where P is an occupation probability of each bond, and Pc is the critical probability at which rigidity percolation occurs. We find good quantitative agreement between effective-medium theory and simulations for both lattices for P close to one.

Entropic forces stabilize diverse emergent structures in colloidal membranes.

The depletion interaction mediated by non-adsorbing polymers promotes condensation and assembly of repulsive colloidal particles into diverse higher-order structures and materials. One example, with particularly rich emergent behaviors, is the formation of two-dimensional colloidal membranes from a suspension of filamentous fd viruses, which act as rods with effective repulsive interactions, and dextran, which acts as a condensing, depletion-inducing agent. Colloidal membranes exhibit chiral twist even when the constituent virus mixture lacks macroscopic chirality, change from a circular shape to a striking starfish shape upon changing the chirality of constituent rods, and partially coalesce via domain walls through which the viruses twist by 180°. We formulate an entropically-motivated theory that can quantitatively explain these experimental structures and measurements, both previously published and newly performed, over a wide range of experimental conditions. Our results elucidate how entropy alone, manifested through the viruses as Frank elastic energy and through the depletants as an effective surface tension, drives the formation and behavior of these diverse structures. Our generalizable principles propose the existence of analogous effects in molecular membranes and can be exploited in the design of reconfigurable colloidal structures.

Phonons and elasticity in critically coordinated lattices.

Much of our understanding of vibrational excitations and elasticity is based upon analysis of frames consisting of sites connected by bonds occupied by central-force springs, the stability of which depends on the average number of neighbors per site z. When z < zc ≈ 2d, where d is the spatial dimension, frames are unstable with respect to internal deformations. This pedagogical review focuses on the properties of frames with z at or near zc, which model systems like randomly packed spheres near jamming and network glasses. Using an index theorem, N0 -NS = dN -NB relating the number of sites, N, and number of bonds, NB, to the number, N0, of modes of zero energy and the number, NS, of states of self stress, in which springs can be under positive or negative tension while forces on sites remain zero, it explores the properties of periodic square, kagome, and related lattices for which z = zc and the relation between states of self stress and zero modes in periodic lattices to the surface zero modes of finite free lattices (with free boundary conditions). It shows how modifications to the periodic kagome lattice can eliminate all but trivial translational zero modes and create topologically distinct classes, analogous to those of topological insulators, with protected zero modes at free boundaries and at interfaces between different topological classes.

Mechanical instability at finite temperature.

Many physical systems including lattices near structural phase transitions, glasses, jammed solids and biopolymer gels have coordination numbers placing them at the edge of mechanical instability. Their properties are determined by an interplay between soft mechanical modes and thermal fluctuations. Here we report our investigation of the mechanical instability in a lattice model at finite temperature T. The model we used is a square lattice with a φ(4) potential between next-nearest-neighbour sites, whose quadratic coefficient κ can be tuned from positive to negative. Using analytical techniques and simulations, we obtain a phase diagram characterizing a first-order transition between the square and the rhombic phase and different regimes of elasticity, as well as an 'order-by-disorder' effect that favours the rhombic over other zigzagging configurations. We expect our study to provide a framework for the investigation of finite-T mechanical and phase behaviour of other systems with a large number of floppy modes.

Penrose tilings as jammed solids.

Penrose tilings form lattices, exhibiting fivefold symmetry and isotropic elasticity, with inhomogeneous coordination much like that of the force networks in jammed systems. Under periodic boundary conditions, their average coordination is exactly four. We study the elastic and vibrational properties of rational approximants to these lattices as a function of unit-cell size N(S) and find that they have of order sqrt[N(S)] zero modes and states of self-stress and yet all their elastic moduli vanish. In their generic form, obtained by randomizing site positions, their elastic and vibrational properties are similar to those of particulate systems at jamming with a nonzero bulk modulus, vanishing shear modulus, and a flat density of states.

Effective-medium theory of a filamentous triangular lattice.

We present an effective-medium theory that includes bending as well as stretching forces, and we use it to calculate the mechanical response of a diluted filamentous triangular lattice. In this lattice, bonds are central-force springs, and there are bending forces between neighboring bonds on the same filament. We investigate the diluted lattice in which each bond is present with a probability p. We find a rigidity threshold p(b) which has the same value for all positive bending rigidity and a crossover characterizing bending, stretching, and bend-stretch coupled elastic regimes controlled by the central-force rigidity percolation point at p(CF)=/~2/3 of the lattice when fiber bending rigidity vanishes.

Elasticity of a filamentous kagome lattice.

The diluted kagome lattice, in which bonds are randomly removed with probability 1-p, consists of straight lines that intersect at points with a maximum coordination number of 4. If lines are treated as semiflexible polymers and crossing points are treated as cross-links, this lattice provides a simple model for two-dimensional filamentous networks. Lattice-based effective-medium theories and numerical simulations for filaments modeled as elastic rods, with stretching modulus µ and bending modulus κ, are used to study the elasticity of this lattice as functions of p and κ. At p=1, elastic response is purely affine, and the macroscopic elastic modulus G is independent of κ. When κ=0, the lattice undergoes a first-order rigidity-percolation transition at p=1. When κ>0, G decreases continuously as p decreases below one, reaching zero at a continuous rigidity-percolation transition at p=p(b)≈0.605 that is the same for all nonzero values of κ. The effective-medium theories predict scaling forms for G, which exhibit crossover from bending-dominated response at small κ/µ to stretching-dominated response at large κ/µ near both p=1 and p(b), that match simulations with no adjustable parameters near p=1. The affine response as p→1 is identified with the approach to a state with sample-crossing straight filaments treated as elastic rods.

Influence of particle shape on bending rigidity of colloidal monolayer membranes and particle deposition during droplet evaporation in confined geometries.

We investigate the influence of particle shape on the bending rigidity of colloidal monolayer membranes (CMMs) and on evaporative processes associated with these membranes. Aqueous suspensions of colloidal particles are confined between glass plates and allowed to evaporate. Confinement creates ribbonlike air-water interfaces and facilitates measurement and characterization of CMM geometry during drying. Interestingly, interfacial buckling events occur during evaporation. Extension of the description of buckled elastic membranes to our quasi-2D geometry enables the determination of the ratio of CMM bending rigidity to its Young's modulus. Bending rigidity increases with increasing particle anisotropy, and particle deposition during evaporation is strongly affected by membrane elastic properties. During drying, spheres are deposited heterogeneously, but ellipsoids are not. Apparently, increased bending rigidity reduces contact line bending and pinning and induces uniform deposition of ellipsoids. Surprisingly, suspensions of spheres doped with a small number of ellipsoids are also deposited uniformly.

Surface phonons, elastic response, and conformal invariance in twisted kagome lattices.

Model lattices consisting of balls connected by central-force springs provide much of our understanding of mechanical response and phonon structure of real materials. Their stability depends critically on their coordination number z. d-dimensional lattices with z = 2d are at the threshold of mechanical stability and are isostatic. Lattices with z < 2d exhibit zero-frequency "floppy" modes that provide avenues for lattice collapse. The physics of systems as diverse as architectural structures, network glasses, randomly packed spheres, and biopolymer networks is strongly influenced by a nearby isostatic lattice. We explore elasticity and phonons of a special class of two-dimensional isostatic lattices constructed by distorting the kagome lattice. We show that the phonon structure of these lattices, characterized by vanishing bulk moduli and thus negative Poisson ratios (equivalently, auxetic elasticity), depends sensitively on boundary conditions and on the nature of the kagome distortions. We construct lattices that under free boundary conditions exhibit surface floppy modes only or a combination of both surface and bulk floppy modes; and we show that bulk floppy modes present under free boundary conditions are also present under periodic boundary conditions but that surface modes are not. In the long-wavelength limit, the elastic theory of all these lattices is a conformally invariant field theory with holographic properties (characteristics of the bulk are encoded on the sample boundary), and the surface waves are Rayleigh waves. We discuss our results in relation to recent work on jammed systems. Our results highlight the importance of network architecture in determining floppy-mode structure.

Order by disorder in the antiferromagnetic Ising model on an elastic triangular lattice.

Geometrically frustrated materials have a ground-state degeneracy that may be lifted by subtle effects, such as higher-order interactions causing small energetic preferences for ordered structures. Alternatively, ordering may result from entropic differences between configurations in an effect termed order by disorder. Motivated by recent experiments in a frustrated colloidal system in which ordering is suspected to result from entropy, we consider in this paper the antiferromagnetic Ising model on a deformable triangular lattice. We calculate the displacements exactly at the microscopic level and, contrary to previous studies, find a partially disordered ground state of randomly zigzagging stripes. Each such configuration is deformed differently and thus has a unique phonon spectrum with distinct entropy, lifting the degeneracy at finite temperature. Nonetheless, due to the free-energy barriers between the ground-state configurations, the system falls into a disordered glassy state.

Nonlinear smectic elasticity of helical state in cholesteric liquid crystals and helimagnets.

General symmetry arguments, dating back to de Gennes, dictate that at scales longer than the pitch, the low-energy elasticity of a chiral nematic liquid crystal (cholesteric) and of a Dzyaloshinskii-Morya (DM) spiral state in a helimagnet with negligible crystal symmetry fields (e.g., MnSi, FeGe) is identical to that of a smectic liquid crystal, thereby inheriting its rich phenomenology. Starting with a chiral Frank free energy (exchange and DM interactions of a helimagnet) we present a transparent derivation of the fully nonlinear Goldstone mode elasticity, which involves an analog of the Anderson-Higgs mechanism that locks the spiral orthonormal (director or magnetic moment) frame to the cholesteric (helical) layers. This shows explicitly the reduction of three orientational modes of a cholesteric down to a single-phonon Goldstone mode that emerges on scales longer than the pitch. At a harmonic level our result reduces to that derived many years ago by Lubensky and collaborators.