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1.
Environ Sci Pollut Res Int ; 28(24): 31803-31813, 2021 Jun.
Article in English | MEDLINE | ID: mdl-33611732

ABSTRACT

Cut flowers and floral waste (CFW) is a major concern in the present era. This study emphasizes the reuse of cut flowers as a neat bioadsorbent and activated carbon (AC). The biomass from the cut flowers was utilized as a neat bioadsorbent for the removal of the antibiotic levofloxacin and lead ions from water. The results revealed that the neat bioadsorbent was able to remove 60% levofloxacin and 45% of lead ions. Upon chemical activation of the CFW (using KOH), almost all levofloxacin and more than 99% of lead ions were removed. Physical activation (using CO2) gave a material that removed 90% of levofloxacin and 85% of lead ions. The adsorption of levofloxacin and lead ions on all the adsorbents followed Langmuir isotherms and pseudo-second-order kinetic model. The results have been further explained via the prediction of interaction energies between the adsorbates and adsorbents using COSMO-RS simulation.


Subject(s)
Water Pollutants, Chemical , Water Purification , Adsorption , Flowers/chemistry , Hydrogen-Ion Concentration , Kinetics , Technology , Wastewater , Water Pollutants, Chemical/analysis
2.
Bioresour Technol ; 100(7): 2219-22, 2009 Apr.
Article in English | MEDLINE | ID: mdl-19028088

ABSTRACT

Raw bagasse or sugar cane cellulosic residues were modified using acylation grafting with fatty acid. The capability of the grafted bagasse to absorb oil from aqueous solution was studied and compared with the raw bagasse. It was found that the grafted material was significantly more hydrophobic than the raw bagasse. This grafted bagasse had little affinity for water and good affinity for oil. It was also found that bleaching of raw bagasse did not enhance its oil absorptivity. The grafted raw bagasse would be most suitable for applications where oil is to be removed from an aqueous environment. For oil absorbing applications in the absence of water, the raw bagasse was an excellent material.


Subject(s)
Cellulose/chemistry , Oils/chemistry , Absorption , Acylation , Lignin/chemistry , Water
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