Acoustic Tweezer-Modulated Biomimetic Patterned Particle-Polymer Composite for Water Vapor Harvesting.

With the recent threat of climate change and global warming, ensuring access to safe drinking water is a great challenge in many areas worldwide. Designing functional materials for capturing water from natural resources like fog and mist has become one of the key research areas to maximize the production of clean water. From this aspect, nature is a great source for designing bioinspired functional materials as some of the plant leaves and animal exoskeletons can harness water and then store it to save themselves from arid, xeric conditions. Inspired by the Stenocara beetle, we have designed a composite surface structure with periodic islands made of aluminum microparticles surrounded by poly(dimethylenesiloxane) (PDMS). An acoustic tweezer-based method was used to fabricate the bioinspired composite structures, where surface acoustic waves at specific frequencies and amplitudes are applied to align the microparticles as islands in the polymer matrix. An oxygen plasma etching step was applied to expose the microparticles on the PDMS surface. The average water harvesting efficiencies for structures made with 120 and 80 kHz acoustic frequencies and 1 hour etching time were found to be 9.41 and 8.84 g cm-2 h-1, respectively. The acoustically patterned biomimetic composite surface showed higher water harvesting efficiency compared with completely hydrophobic PDMS and hydrophilic aluminum surfaces, demonstrating the advantages of the bioinspired composite material design and acoustic-assisted manufacturing technique. The biomimetic fog water harvesting material is a promising avenue to fulfill the demand for a cost-effective, sustainable, and energy-efficient solution to safe drinking water.

Integrating Rh Species with NiFe-Layered Double Hydroxide for Overall Water Splitting.

NiFe-layered double hydroxide (LDH) is thought of as a promising bifunctional water-splitting catalyst, owing to its excellent performances for alkaline oxygen evolution reactions (OERs). However, it shows extremely poor activity toward hydrogen evolution reactions (HERs) due to the weak hydrogen adsorption. We demonstrated that the integration of Rh species and NiFe-LDH can dramatically improve its HER kinetics without sacrificing the OER performance. The Rh species were initially integrated into NiFe-LDH as oxidized dopants and metallic clusters (< 1 nm). In 1 M KOH electrolyte, an overpotential of 58 mV is needed to catalyze 10 mA cm-2 HER current density. Furthermore, this catalyst only requires 1.46 V to drive an electrolyzer at 10 mA cm-2. A strong interaction between metallic Rh clusters and NiFe hydroxide during the HER process is revealed. The theoretical calculation shows the Rh ions replace Fe ions as the major active sites that are responsible for OERs.

Insertion of Platinum Nanoparticles into MoS2 Nanoflakes for Enhanced Hydrogen Evolution Reaction.

Pt as a chemical inert metal has been widely applied as the counter electrode in various electrochemical measurements. However, it can also be dissolved and redeposit to the working electrode under certain electrochemical circumstances. Herein we demonstrated a cyclic voltammetry (CV) cycling method to synthesize a catalyst comprising inserted Pt nanoparticles into MoS2 nanoflake stack structures on stainless steel mesh (SSM). The binder-free composite structure exhibits significantly enhanced hydrogen evolution reaction (HER) catalytic activity with an overpotentials of 87 mV at 10 mA cm-2. The deposited Pt nanoparticles significantly enhance the catalytic activity through changing the structure of MoS2 and increasing the amount of active sites. This work provides a new way forward for rational design of the nano-electrocatalysts.

Hierarchical FeNiP@Ultrathin Carbon Nanoflakes as Alkaline Oxygen Evolution and Acidic Hydrogen Evolution Catalyst for Efficient Water Electrolysis and Organic Decomposition.

Efficiency of hydrogen evolution via water electrolysis is mainly impeded by the kinetically sluggish oxygen evolution reaction (OER). Thus, it is of great significance to develop highly active and stable OER catalyst for alkaline water electrolysis or to substitute the more kinetically demanding acidic OER with a facile electron-donating reaction such that OER is no longer the bottleneck half-reaction for either acidic or alkaline water electrolysis. Herein, the hierarchical Fe-Ni phosphide shelled with ultrathin carbon networks on Ni foam (FeNiP@C) is reported and shows exceptional OER activity and enhanced chemical stability in 1 M KOH. This unique electrode provides large active sites, facile electron transport pathways, and rapid gas release, resulting in a remarkable OER activity that delivers a current density of 100 mA/cm2 at an overpotential of 182 mV with a Tafel slope of 56 mV/dec. Combining the hydrogen evolution reaction with organic pollutant (methylene blue) oxidation, a multifunctional electrolyzer for simultaneous cost-effective hydrogen generation and organic pollutant decomposition in acid wastewater is proposed. Our strategies in this work provide attractive opportunities in energy- and environment-related fields.

Redox-Active Hydrogel Polymer Electrolytes with Different pH Values for Enhancing the Energy Density of the Hybrid Solid-State Supercapacitor.

To enhance the energy density of solid-state supercapacitors, a novel solid-state cell, made of redox-active poly(vinyl alcohol) (PVA) hydrogel electrolytes and functionalized carbon nanotube-coated cellulose paper electrodes, was investigated in this work. Briefly, acidic PVA-[BMIM]Cl-lactic acid-LiBr and neutral PVA-[BMIM]Cl-sodium acetate-LiBr hydrogel polymer electrolytes are used as catholyte and anolyte, respectively. The acidic condition of the catholyte contributes to suppression of the undesired irreversible reaction of Br- and extension of the oxygen evolution reaction potential to a higher value than that of the redox potential of Br-/Br3- reaction. The observed Br-/Br3- redox activity at the cathode contributes to enhance the cathode capacitance. The neutral condition of the anolyte helps extend the operating voltage window of the supercapacitor by introducing hydrogen evolution reaction overpotential to the anode. The electrosorption of nascent H on the negative electrode also increases the anode capacitance. As a result, the prepared solid-state hybrid supercapacitor shows a broad voltage window of 1.6 V, with a high Coulombic efficiency of 97.6% and the highest energy density of 16.3 Wh/kg with power density of 932.6 W/kg at 2 A/g obtained. After 10 000 cycles of galvanostatic charge and discharge tests at the current density of 10 A/g, it exhibits great cyclic stability with 93.4% retention of the initial capacitance. In addition, a robust capacitive performance can also be observed from the solid-state supercapacitor at different bending angles, indicating its great potential as a flexible energy storage device.