ABSTRACT
Asymmetric membranes derived from the stacking of graphene oxide (GO) nanosheets have attracted great attention for the fabrication of ionic diodes. Herein, we described an ionic diode based on a polypyrrole-modified GO membrane with a vertical asymmetry, which was achieved by a spontaneous oxidation polymerization of pyrrole monomers on one side of the GO membrane in vapor phase. This asymmetric modification resulted in an asymmetric geometry due to the occupation of the interlayer space of one side of the GO membrane by polypyrrole. Our ionic diode demonstrated an obvious ionic rectification behavior over a wide voltage range. A calculation based on Poisson-Nernst-Planck equations was used to theoretically investigate the role of asymmetric modification of polypyrrole.
ABSTRACT
The controllable ion transport in the photoreceptors of rod cells is essentially important for the light detection and information transduction in visual systems. Herein, inspired by the photochromism-regulated ion transport in rod cells with stacking structure, layered ion channels have been developed with a visual photochromic function induced by the alternate irradiation with visible and UV light. The layered structure is formed by stacking spiropyran-modified montmorillonite 2D nanosheets on the surface of an alumina nanoporous membrane. The visual photochromism resulting from the photoisomerization of spiropyran chromophores reversibly regulates the ion transport through layered ion channels. Furthermore, the cooperation of photochromism and pH value achieves multiple switchable states of layered ion channels for the controllable ion transport mimicking the biological process of the visual cycle. The ion transport properties of these states are explained quantitatively by a theoretical calculation based on the Poisson and Nernst-Plank (PNP) equations.
