Calling attention to opponents of climate action in climate and health messaging.

Previous research suggests that providing information about the health effects of climate change and the health benefits of climate action can increase public engagement with the issue. We sought to extend those findings with an experiment to test the motivational value of calling attention to opponents of climate action. In February, 2022, we conducted a survey experiment with adults from the USA, quota-sampled to represent the USA population (n=2201). Participants were randomly assigned to a no-message control condition, or one of four message conditions identified as authored by concerned health professionals. These messages warned recipients about the negative effects of climate change on health, and either made no mention of an opponent to climate action, or were messages augmented by identifying one of three opponents: (1) fossil fuel chief executive officers and their lobbyists, (2) politicians, or (3) a combination of the two. Portrayal of opponents to climate action increased attitudinal engagement, support for mitigation policies, and intentions to advocate for climate solutions, compared with message conditions not identifying an opponent-with the combined opponent portrayal tending to result in the largest effects; these effects were evident with audiences across political lines, especially political conservatives. Climate and health messages-with or without portrayal of an opponent-also increased trust in the messengers relative to the no-message control. These findings suggest that identifying opponents to climate action can be advantageous to building support for such action, reducing political issue polarisation, and fostering greater trust in health professionals as climate messengers.

Can Altruistic Emotions Promote Vaccine Advocacy? Examining the Use of Empathy and Elevation in Vaccine Messages.

This study examines the effectiveness of evoking other-oriented emotions in vaccine messages to promote vaccine advocacy behaviors. A between-subject experiment with a parent sample was conducted, in which portrayals of a victim exemplar (someone who is suffering from the consequence of vaccine hesitancy) and a moral exemplar (someone who is selflessly helping others) were varied. Results showed that the victim exemplar led to greater empathy, and the moral exemplar led to greater elevation, both of which predicted vaccine advocacy responses. Implications of the findings and future directions were discussed.

Stereodynamic Control of Collision-Induced Nonadiabatic Dynamics of NO (A2Σ+) with H2, N2, and CO: Intermolecular Interactions Drive Collision Outcomes.

Intermolecular interactions, stereodynamics, and coupled potential energy surfaces (PESs) all play a significant role in determining the outcomes of molecular collisions. A detailed knowledge of such processes is often essential for a proper interpretation of spectroscopic observations. For example, nitric oxide (NO), an important radical in combustion and atmospheric chemistry, is commonly quantified using laser-induced fluorescence on the A2Σ+ ← X2Π transition band. However, the electronic quenching of NO (A2Σ+) with other molecular species provides alternative nonradiative pathways that compete with fluorescence. While the cross sections and rate constants of NO (A2Σ+) electronic quenching have been experimentally measured for a number of important molecular collision partners, the underlying photochemical mechanisms responsible for the electronic quenching are not well understood. In this paper, we describe the development of high-quality PESs that provide new physical insights into the intermolecular interactions and conical intersections that facilitate the branching between the electronic quenching and scattering of NO (A2Σ+) with H2, N2, and CO. The PESs are calculated at the EOM-EA-CCSD/d-aug-cc-pVTZ//EOM-EA-CCSD/aug-cc-pVDZ level of theory, an approach that ensures a balanced treatment of the valence and Rydberg electronic states and an accurate description of the open-shell character of NO. Our PESs show that H2 is incapable of electronically quenching NO (A2Σ+) at low collision energies; instead, the two molecules will likely undergo scattering. The PESs of NO (A2Σ+) with N2 and CO are highly anisotropic and demonstrate evidence of electron transfer from NO (A2Σ+) into the lowest unoccupied molecular orbital of the collision partner, that is, the harpoon mechanism. In the case of ON + CO, the PES becomes strongly attractive at longer intermolecular distances and funnels population to a conical intersection between NO (A2Σ+) + CO and NO (X2Π) + CO. In contrast, for ON + N2, the conical intersection is preceded by an ∼0.40 eV barrier. Overall, our work shines new light into the impact of coupled PESs on the nonadiabatic dynamics of open-shell systems.

Dynamical signatures from competing, nonadiabatic fragmentation pathways of S-nitrosothiophenol.

S-Nitrosothiols (RSNOs) are derived from the combination of sulfur and nitric oxide (NO) radicals in the Earth's atmosphere and fragment to products following photolysis. Extensive theoretical studies have focused on the thermodynamic and, to a lesser extent, photochemical properties of RSNOs. However, experimental studies of these compounds have been limited due to the inherent instability of RSNOs at room temperature. Using velocity map imaging (VMI), we explore the photodissociation dynamics of jet-cooled S-nitrosothiophenol (PhSNO) from 355 nm photolysis. We report the translational and internal energy distributions of the NO and thiophenoxy (PhS) co-fragments, which are determined by spatial detection of the ionized NO photofragments using 1+1 resonance-enhanced multiphoton ionization (REMPI). The velocity distributions indicate competing PhSNO nonadiabatic dissociation pathways, in which PhS is formed in the ground and first excited electronic states when probing high- and low-energy NO (X2Π1/2, v'', J'') rovibrational states, respectively. The results of multireference electronic structure calculations suggest that direct dissociation on the bright S2 state results in PhS formed in its excited electronic state, whereas intersystem crossing into the triplet manifold leads to population of PhS in its electronic ground state. The dynamical signatures from the dissociation processes are imprinted on the fragments' quantum states and relative translation, which we explore in rigorous detail using state-resolved imaging and high-level theoretical calculations.

Talking about TV: Mother-Daughter Viewing and Discussion of an Entertainment Narrative about Teen Pregnancy.

Narratives can bring about related discussions, which can influence narrative comprehension and future conversations - though little is known about how these processes interact. This study considers the interplay of exposure to a teen pregnancy narrative and subsequent mother-daughter discussion in an experiment with mothers and their teenage daughters. Participants watched a teen pregnancy narrative or a control narrative. After watching, they either participated in a mother-daughter discussion of sexual health or completed a distractor activity. The teen pregnancy narrative led to greater endorsement of teen pregnancy myths on the part of daughters - particularly when identifying with the pregnant teen character - but maternal discussion mitigated their effects on overall attitudes toward pregnancy prevention. Moreover, participants who viewed the teen pregnancy narrative were more satisfied with their discussions afterwards than were those who discussed sexual health without first watching the teen pregnancy narrative. This conversational satisfaction, in turn, led to more frequent mother-daughter conversations about sexuality in the following weeks.

Visual Cancer Communication on Social Media: An Examination of Content and Effects of #Melanomasucks.

BACKGROUND: Instagram is increasingly becoming a platform on which visual communication of cancer takes place, but few studies have investigated the content and effects. In particular, a paucity of research has evaluated the effects of visual communication of cancer on participative engagement outcomes. OBJECTIVE: The objective of our study was to investigate cancer-related beliefs and emotions shared on Instagram and to examine their effects on participative engagement outcomes including likes, comments, and social support. METHODS: This study analyzed the content of 441 posts of #melanomasucks on Instagram and assessed the effects of the content characteristics on outcomes, including the number of likes and comments and types of social support using group least absolute shrinkage and selection operator logistic regression. RESULTS: Posts about controlling melanoma were most frequent (271/441, 61.5%), followed by 240 (54.4%) posts about outcomes of having melanoma. Ninety posts (20.4%) were about the causes of melanoma. A greater number of posts expressed positive (159/441, 36.1%) than negative emotions (100/441, 22.7%). Eighty posts (18.1%) expressed hope, making it the most frequently expressed emotion; 49 posts expressed fear (11.1%), 46 were humorous (10.4%), and 46 showed sadness (10.4%). Posts about self behavior as a cause of melanoma decreased likes (P<.001) and social support comments (P=.048). Posts about physical consequences of melanoma decreased likes (P=.02) but increased comments (P<.001) and emotional social support (P<.001); posts about melanoma treatment experience increased comments (P=.03) and emotional social support (P<.001). None of the expressions of positive emotions increased likes, comments, or social support. Expression of anger increased the number of likes (P<.001) but those about fear (P<.001) and joy (P=.006) decreased the number of likes. Posts about fear (P=.003) and sadness (P=.003) increased emotional social support. Posts showing images of melanoma or its treatment on the face or body parts made up 21.8% (96/441) of total posts. Inclusion of images increased the number of comments (P=.001). CONCLUSIONS: To our knowledge, this is the first investigation of the content and effects of user-generated visual cancer communication on social media. The findings show where the self-expressive and social engagement functions of #melanomasucks converge and diverge, providing implications for extending research on the commonsense model of illness and for developing conceptual frameworks explaining participative engagement on social media.