Nanorough Is Not Slippery Enough: Implications on Shedding and Heat Transfer.

Lowering droplet-surface interactions via the implementation of lubricant-infused surfaces (LISs) has received important attention in the past years. LISs offer enhanced droplet mobility with low sliding angles and the recently reported slippery Wenzel state, among others, empowered by the presence of the lubricant infused in between the structures, which eventually minimizes the direct interactions between liquid droplets and LISs. Current strategies to increase heat transfer during condensation phase-change relay on minimizing the thickness of the coating as well as enhancing condensate shedding. While further surface structuring may impose an additional heat transfer resistance, the presence of micro-structures eventually reduces the effective condensate-surface intimate interactions with the consequently decreased adhesion and enhanced shedding performance, which is investigated in this work. This is demonstrated by macroscopic and optical microscopy condensation experimental observations paying special attention at the liquid-lubricant and liquid-solid binary interactions at the droplet-LIS interface, which is further supported by a revisited force balance at the droplet triple contact line. Moreover, the occurrence of a condensation-coalescence-shedding regime is quantified for the first time with droplet growth rates one and two orders of magnitude greater than during condensation-coalescence and direct condensation regimes, respectively. Findings presented here are of great importance for the effective design and implementation of LISs via surface structure endowing accurate droplet mobility and control for applications such as anti-icing, self-cleaning, water harvesting, and/or liquid repellent surfaces as well as for condensation heat transfer.

3D Solar Evaporation Enhancement by Superhydrophilic Copper Foam Inverted Cone and Graphene Oxide Functionalization Synergistic Cooperation.

Solar evaporation has become a promising and sustainable technique for harvesting freshwater from seawater and wastewater. However, the applicability and efficacy of solar evaporation need further improvement to achieve high production closer to theoretical limits in compact systems. A 3D (three-dimensional) hierarchical inverted conical solar evaporation is developed, which consists of a 3D copper foam skeleton cone decorated with micro-/nano-structures functionalized with graphene oxide, fabricated via easy and scalable wet oxidation, impregnation, and drying at room temperature. The proposed configuration empowers high-efficiency solar absorption, continuous liquid film spreading and transport, enhanced interfacial local evaporation, and rapid vapor diffusion through the pores. More notably, the 3D conical evaporator realizes thermal localization at the skeleton interface and allows evaporation to occur along the complete structure with unimpeded liquid and vapor rapid diffusion. The solar-thermal evaporation efficiency under 1-Sun is as high as 93% with a maximum evaporation rate per unit area of 1.71 kg·m-2 ·h-1 . This work highlights the benefits of synergistic cooperation of an easily scalable 3D hierarchical functiomicro-/nano-structured copper foam skeletons and functionalized graphene oxide for high-efficient solar evaporation of interest to numerous applications.

Bioinspired functional SLIPSs and wettability gradient surfaces and their synergistic cooperation and opportunities for enhanced condensate and fluid transport.

Bioinspired smart functional surfaces have received increasing attention in recent years owed to their tunable wettability and enhanced droplet transport suggesting them as excellent candidates for industrial and nanotechnology-related applications. More specifically, bioinspired slippery lubricant infused porous surfaces (SLIPSs) have been proposed for their low adhesion enabling continuous dropwise condensation (DWC) even of low-surface tension fluids. In addition, functional surfaces with chemical and/or structural wettability gradients have also been exploited empowering spontaneous droplet transport in a controlled manner. Current research has focused on the better understanding of the mechanisms and intimate interactions taking place between liquid droplets and functional surfaces or on the forces imposed by differences in surface wettability and/or by Laplace pressure owed to chemical or structural gradients. Nonetheless, less attention has been paid to the synergistic cooperation of efficiently driving droplet transport via chemical and/or structural patterns/gradients on a low surface energy/adhesion background imposed by SLIPSs, with the consequent promising potential for microfluidics and condensation heat transfer applications amongst others. This review provides a detailed and timely overview and summary on recent advances and developments on bioinspired SLIPSs and on wettability gradient surfaces with focus on their synergistic cooperation for condensation and fluid transport related applications. Firstly, the fundamental theory and mechanisms governing complex droplet transport on homogeneous, on wettability gradient surfaces and on inclined SLIPSs are introduced. Secondly, recent advances on the fabrication and characterization of SLIPSs and functional surfaces are presented. Then, the condensation performance on such functional surfaces comprising chemical or structural wettability gradients is reviewed and their applications on condensation heat transfer are summarized. Last a summary outlook highlighting the opportunities and challenges on the synergistic cooperation of SLIPSs and wettability gradient surfaces for heat transfer as well as future perspective in modern applications are presented.

Enhanced Coalescence-Induced Droplet-Jumping on Nanostructured Superhydrophobic Surfaces in the Absence of Microstructures.

Superhydrophobic surfaces are receiving increasing attention due to the enhanced condensation heat transfer, self-cleaning, and anti-icing properties by easing droplet self-removal. Despite the extensive research carried out on this topic, the presence or absence of microstructures on droplet adhesion during condensation has not been fully addressed yet. In this work we, therefore, study the condensation behavior on engineered superhydrophobic copper oxide surfaces with different structural finishes. More specifically, we investigate the coalescence-induced droplet-jumping performance on superhydrophobic surfaces with structures varying from the micro- to the nanoscale. The different structural roughness is possible due to the specific etching parameters adopted during the facile low-cost dual-scale fabrication process. A custom-built optical microscopy setup inside a temperature and relative humidity controlled environmental chamber was used for the experimental observations. By varying the structural roughness, from the micro- to the nanoscale, important differences on the number of droplets involved in the jumps, on the frequency of the jumps, and on the size distribution of the jumping droplets were found. In the absence of microstructures, we report an enhancement of the droplet-jumping performance of small droplets with sizes in the same order of magnitude as the microstructures. Microstructures induce further droplet adhesion, act as a structural barrier for the coalescence between droplets growing on the same microstructure, and cause the droplet angular deviation from the main surface normal. As a consequence, upon coalescence, there is a decrease in the net momentum in the out-of-plane direction, and the jump does not ensue. We demonstrate that the absence of microstructures has therefore a positive impact on the coalescence-induced droplet-jumping of micrometer droplets for antifogging, anti-icing, and condensation heat transfer applications.