Changes of water-soluble inorganic sulfate and nitrate during severe dust storm episodes in a coastal city of North China.

Dust storms are one of the largest sources of non-exhaust emissions in China, which can adversely affect air quality and human health during long-distance transportation. To study the influence of dust storms on aerosol particle composition, samples of fine aerosol (PM2.5) were collected before, during, and after the severe dust storm episodes in a coastal city of North China. Then the water-soluble inorganic ions in the filters were analyzed. The results showed that the chemical composition varied significantly in different sampling periods. Before the dust storm periods (Phase 1), the weather was characterized by high relative humidity. NO3- was the main water-soluble inorganic ion, accounting for about 1/3 of the total mass of PM2.5, which is very different from the situation a few years ago when sulfate was the dominant. The results indicated that the chemical composition of the atmosphere in China has changed significantly after the implementation of strict air pollution control measures. During the severe dust storm periods (within a few hours after the dust invasion, Phase 2), the proportion of Ca2+ in PM2.5 was high; the sulfate formation was limited due to adiabatic air mass affected by the cold front, and the sulfate content might be mainly from desert soil. However, a small amount of nitrate can be formed during their long-distance transportation. After the dust storm periods (Phase 3), dust plums and local polluted air mass mixed well. The proportion of secondary inorganic ions increased, and nitrate formation was still the main. The changes in the chemical composition from a few years ago during Phase 1 and the sharp changes in different water-soluble inorganic ions during different Phases should be carefully considered to evaluate their implications for air quality and human health.

Primary Carbonaceous Particle Emission from Four Power Plants with Ultralow Emission in China.

Particulate matters (PMs) were collected in stacks from two types of ultralow emission coal-fired power plants by a heated electrical low-pressure impactor (HT-ELPI+), including ultralow emission pulverized combustion technology boilers (ULPCBs) and ultralow emission circulating fluidized bed boilers (ULCFBs). The characteristics of organic carbon (OC) and elemental carbon (EC) in size-resolved particles were analyzed. The ultralow emission technologies significantly decreased the mass concentrations of the carbonaceous content, and the emission concentrations of OC and EC ranged from 5.64 to 17.9 µg/m3 for ULPCBs and from 0.57 to 1.85 µg/m3 for ULCFBs. However, the number concentration of particles was not significantly decreased in the four ultralow emission power plants. The OC in the particle emission of ULPCBs presents a bimodal size distribution with the particle size, while three successive unimodal distributions were observed in the ULCFB emission. Compared to ULPCBs, much more char-EC and soot-EC condensed in the particles, which were collected from ULCFBs. Furthermore, the char-EC/soot-EC in the particle fractions of ULPCBs characterized by the "V" type with the sequence of PM1.0 > PM2.5-10 > PM1.0-2.5, differing from the PM1.0 > PM1.0-2.5 > PM2.5-10 of ULCFBs. The ratios of OC/EC in the stacks from two types of boilers did not show obvious variations in particle size distributions, and the mean OC/EC was far higher than those for non-ultralow emission power plants. Considering the impact of OC1, OC4, and EC1, the ratio of high-temperature organic carbon (HTOC, defined as OC2 + OC3) and soot-EC was studied. The HTOC/soot-EC increased with the increase of RH in the stack, and the highest HTOC/soot-EC values were obtained from ULPCBs (33.0% (PM1.0), 11.4% (PM1.0-2.5), and 23.9% (PM2.5-10)). Meanwhile, strong correlations (0.69-0.85, p < 0.001) between HTOC and soot-EC were obtained, implying that HTOC and soot-EC probably simultaneously condensed in the purification equipment.