ABSTRACT
The (95)Nb/(95)Zr activity ratio can be used to determine the date of a nuclear event. Several proficiency test exercises organised by the National Physical Laboratory (NPL) showed in general relatively poor results for (95)Nb, presumably caused by incorrect decay corrections. In this paper, the integrated Bateman equation taking account of the multiple branching of the parents (95)Zr and (95m)Nb, ingrowth/decay during measurement and the decay correction to a specific reference time is presented.
ABSTRACT
A recent paper has reviewed methods for the evaluation of discrepant sets of data and demonstrated the results of applying these methods to the published half-life data of 90Sr and 137Cs [MacMahon, T.D., Pearce, A., Harris, P., 2004. Convergence of techniques for the evaluation of discrepant data. Appl. Radiat. Isot. 60, 275-281]. The half-life data for 3H has been subject to a comprehensive review and critical evaluation by Lucas and Unterweger [2000. Comprehensive review and critical evaluation of the half-life of tritium. J. Res. Natl. Inst. Stand. Technol. 105, 541-549]. The current paper reports the results of applying the various evaluation procedures of MacMahon et al. Convergence of techniques for the evaluation of discrepant data. Appl. Radiat. Isot. 60, 275-281] to the data of Lucas and Unterweger [Comprehensive review and critical evaluation of the half-life of tritium. J. Res. Natl. Inst. Stand. Technol. 105, 541-549], resulting in a recommended half-life of 4497(4) days. MacMahon et al. [Convergence of techniques for the evaluation of discrepant data. Appl. Radiat. Isot. 60, 275-281] highlighted problems in the evaluation of the discrepant half-life data of 90Sr, in particular the worrying upward trend in the data, where the weighted mean of all the measurements increases, on average, by 35 days each time a new measurement result is added. The current paper reports on further analyses of these data. New measurements of the half-life of 90Y have been reported by Kossert and Schrader [2004. Standardization by liquid scintillation counting and half-life measurements of 90Y. Appl. Radiat. Isot. 60, 741]. This has prompted a new evaluation of all available published 90Y half-life data. The data are fairly consistent, and a value of 64.063(16) h is recommended.
Subject(s)
Models, Chemical , Radiometry/methods , Strontium Radioisotopes/analysis , Tritium/analysis , Yttrium Radioisotopes/analysis , Computer Simulation , Guidelines as Topic , Half-Life , Radiation Dosage , Reference Standards , Reference Values , Reproducibility of Results , Sensitivity and Specificity , Strontium Radioisotopes/chemistry , Strontium Radioisotopes/standards , Tritium/chemistry , Tritium/standards , Yttrium Radioisotopes/chemistry , Yttrium Radioisotopes/standardsABSTRACT
The problem of evaluating discrepant data has been addressed by several authors over the previous 20 yr. More recently some attention has been given to the use of the median, which is expected to have better statistical 'robustness'. The various evaluation techniques should converge towards the 'true' value as the number of data in a data set increases, and the 'robustness' of each evaluation technique can then be tested by the rate at which that technique converges. Several evaluation techniques have been applied to discrepant data sets, and the results are shown to converge as the size of the data set grows. The discrepant data sets used as examples are the measured half-lives of 90Sr and 137Cs. Differences in the behaviour of the evaluation techniques are discussed, as applied to these data sets. The half-lives deduced from this study are: 90Sr 10,551+/-14 days; 137Cs 10,981+/-11 days.
