Soret coefficients of the ternary mixture 1,2,3,4-tetrahydronaphthalene + isobutylbenzene + n-dodecane.

In this work, the transport coefficients of the ternary mixtures of the diffusion coefficient measurements in ternary mixtures 1 project were determined. The analyzed ternary mixtures are formed by 1,2,3,4-tetrahydronaphthalene, isobutylbenzene, and dodecane (nC12) at different compositions. In all cases, the analysis was carried out at 25 °C. The thermodiffusion coefficients were measured by a new thermogravitational column, and the molecular diffusion coefficients were determined by the sliding symmetric tubes technique. Finally, the Soret coefficients were ascertained from the measurements of the thermodiffusion and molecular diffusion coefficients. In addition, two new quantitative correlations which enable the prediction of the thermodiffusion and Soret coefficients of a ternary mixture are presented. The comparison between the experimental and the predicted data shows a good agreement. The presented results help to complete the lack of experimental data in ternary mixtures. In addition, this work improves the fundamental understanding of multicomponent mixtures.

Contribution to the benchmark for ternary mixtures: Determination of Soret coefficients by the thermogravitational and the sliding symmetric tubes techniques.

This work is part of an international project for the research on the transport properties in ternary mixtures. Six different teams have analysed the same mixture by independent techniques in order to compare the results and validate the techniques. This work is the contribution of the team of Mondragon Unibertsitatea for ground conditions measurements. This team has measured the thermodiffusion coefficients by the thermogravitational techniques and the molecular diffusion coefficients by the Sliding Symmetric Tubes technique. The Soret coefficients have been determined by the combination of the thermodiffusion and molecular diffusion coefficients. The mixture chosen for the study is the one formed by 1,2,3,4-tetrahydronaphtalene, isobutylbenzene and n-dodecane at mass fraction of 80% of THN, 10% of IBB and 10% of n C12, and at 25°C. The good agreement between the results of the different teams shows the validity of the techniques used in this work.