ABSTRACT
Coastal ecosystems are receiving environments for micropollutants due to high levels of associated anthropogenic activities. Effluent discharges from wastewater treatment plants are a significant source of micropollutants to coastal environments. Wastewater effluents, seawater, sediments, and green-lipped mussels (Perna canaliculus) in Lyttelton Harbour (Te Whakaraupo), Christchurch, New Zealand, were analysed for a suite of personal care products and steroid hormones during a 1-year period. In wastewater effluents, the concentration of methyl paraben (mParaben), ethyl paraben (eParaben), propyl paraben (pParaben), butyl paraben (bParaben), 4-t-octylphenol (OP), 4-methylbenzylidene camphor (4-MBC), benzophenone-3 (BP-3), benzophenone-1 (BP-1), triclosan, methyl triclosan (mTric), Bisphenol A (BPA), Estrone (E1), 17ß-estradiol (E2), 17α-ethinyl estradiol (EE2), and Estriol (E3) ranged from < 0.6 to 429 ng L-1 and was dominated by OP, 4-MBC, BP-3, triclosan, BP-1, and BPA. In seawater, 4-MBC, BP-3, BPA, and E1 were the most frequently detected contaminants (< 0.2-9.4 ng L-1). Coastal sediment samples contained mParaben, OP, 4-MBC, BP-3, BP-1, BPA, OMC, and E1 (< 0.2-11 ng g-1 d.w.), and mParaben, OP, and BP-3 were found to bioaccumulate (3.8-21.3 ng g-1 d.w.) in green lipped mussels.
