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Chem Commun (Camb)
; 58(92): 12855-12858, 2022 Nov 17.
Article
in English
| MEDLINE
| ID: mdl-36317533
ABSTRACT
Theory and solution NMR indicate that all-syn 1,3,5-trifluorocyclohexane 5 adopts the expected tri-equatorial conformation, however in the solid state the more polar triaxial conformation is observed. This and the favoured conformations of substituted (Me, OMe, NH(CO)Me, NHBoc) derivatives of 5 are investigated to explore triaxial C-F preferences.
