ABSTRACT
Graphene is an excellent choice for heating applications due to its high thermal conductivity and is considered an interesting candidate for application in flexible heaters. The major challenge, though, is the costly and chemical-intensive pathways to produce graphene on a large scale. Laser ablation of polymeric substrates is a relatively recent technique for a facile, single-step, chemical-free fabrication of graphene, referred to as laser-induced graphene (LIG). This work demonstrates the fabrication of patterned LIG-based flexible heaters and their response to radio frequency (RF) electromagnetic waves. Polymeric substrates were scribed with laser patterns in both raster and vector modes and subjected to RF electromagnetic fields to test their heating response. We confirmed different graphene morphologies of the lased patterns through various materials characterization methods. The maximum steady-state temperature observed for the LIG heater was approximately 500 °C. Unprecedented heating rates, as high as 502 °C/s, were observed when LIG heaters were exposed to RF fields at 200 MHz frequency and 4.6 W power. Mechanical and thermal stability tests for the best heater were also performed showing a stable thermal response for 1000 bending cycles and 20 cycles of the heating test for 8.5 h, respectively. Our work suggests that LIG heaters produced in vector mode lasing outperformed those lased in raster mode which can be attributed to the improved graphene quality for RF absorbance.
ABSTRACT
Laser-induced graphene (LIG) materials have great potential in water treatment applications. Herein, we report the fabrication of a mechanically robust electroconductive LIG membrane with tailored separation properties for ultrafiltration (UF) applications. These LIG membranes are facilely fabricated by directly lasing poly(ether sulfone) (PES) membrane support. Control PES membranes were fabricated through a nonsolvent-induced phase separation (NIPS) technique. A major finding was that when PES UF membranes were treated with glycerol, the membrane porous structure remained almost unchanged upon drying, which also assisted with protecting the membrane's nanoscale features after lasing. Compared to the control PES membrane, the membrane fabricated with 8% laser power on the bottom layer of PES (PES (B)-LIG-HP) demonstrated 4 times higher flux (865 LMH) and 90.9% bovine serum albumin (BSA) rejection. Moreover, LIG membranes were found to be highly hydrophilic and exhibited excellent mechanical and chemical stability. Owing to their excellent permeance and separation efficiency, these highly robust electroconductive LIG membranes have a great potential to be used for designing functional membranes.
