Ni/Pd-catalyzed Suzuki-Miyaura cross-coupling of alcohols and aldehydes and C-N cross-coupling of nitro and amines via domino redox reactions: base-free, hydride acceptor-free.

Domino oxidation-Suzuki-Miyaura cross-coupling of benzyl alcohols with phenylboronic acid and domino reduction-C-N cross-coupling of the nitro compounds with aryl halides were carried out using a strong Ni/Pd bimetallic redox catalyst. The catalyst bearing a copolymer with two Ni/Pd coordinated metals in porphyrin (derived from demetalated chlorophyll b) and salen-type ligands, and pyridine moiety as a base functionality all immobilized on magnetite NPs was synthesised and characterized. The domino oxidation cross-coupling reaction was accomplished under molecular O2 in the absence of any hydride acceptor or/and base. Also, the domino reduction C-N cross-coupling reaction was performed in the presence of NaBH4 without the need for any base and co-reductant. This multifunctional catalyst gave moderate to good yields for both coupling reactions with high chemoselectivity. A wide investigation was conducted to determine its mechanism and chemoselectivity.

Cadmium adsorption using novel MnFe2O4-TiO2-UIO-66 magnetic nanoparticles and condition optimization using a response surface methodology.

In this study, magnetic nanocomposites (UIO-66-MnFe2O4-TiO2) were synthesized based on the metal-organic framework. To investigate the synthesized adsorbent structure, XRD, SEM, FT-IR, BET, and VSM techniques were used, and also an EDX test was applied after adsorption of Cd(ii). The synthesized nanocomposite was used for Cd(ii) adsorption. The effects of four parameters such as the amount of adsorbent (0.05 to 0.25 g), pH (1 to 9), adsorption time (24 to 120 minutes), initial amount of metal ion (100 to 900 mg), at five levels (-2 to +2) were evaluated during the experiment based on the Response Surface Methodology (RSM) using Central Composite Design (CCD) and then, the optimal levels were determined. The F-value and P-value of the fitted second order model were obtained as 6039.62 and 0.0001, respectively. Optimization of the values was also performed for variables and, initial concentration of metal, pH, adsorption time and amount of adsorbent were obtained as 5.2 mg l-1, 5, 63 minutes, and 0.18 g, respectively as optimum conditions. For optimal conditions, the maximum adsorbance was equal to 98%. Investigation of kinetic and isotherm adsorption showed that a second-order kinetic model and a Langmuir isotherm cover the Cd(ii) adsorption data well. It was also revealed that the adsorbent was removed from the environment by an external magnetic field.

An efficient and recyclable nanocatalyst for the green and rapid synthesis of biologically active polysubstituted pyrroles and 1,2,4,5-tetrasubstituted imidazole derivatives.

An effective process for the green and rapid synthesis of biologically active polysubstituted pyrroles and 1,2,4,5-tetrasubstituted imidazoles derivatives using Cu@imine/Fe3O4 MNPs catalyst under solvent-free conditions is explained. This catalyst showed high reactivity for the synthesis of a set of different derivatives of polysubstituted pyrroles and 1,2,4,5-tetrasubstituted imidazole derivatives under appropriate reaction conditions and short times. Moreover, the catalyst was also recycled and reused for six runs with no considerable reduction in reactivity and yields. Compared to the reported procedures, this method consistently demonstrates the advantages of low catalyst loading, short reaction times, easy separation and purification of the products, high yields, and high recoverability and recoverability of the catalyst.